Hydrogen/deuterium exchange in the reactions of methyl cation with methane

International Journal of Mass Spectrometry and Ion Processes

Volumn 167-168, Issue , 1997, Pages 587-594

  Lee, Hack Sung ^a   Bierbaum, Veronica M ^a   DePuy, Charles H ^a  

^a UNIVERSITY OF COLORADO   (United States)

Author keywords

FA SIFT; H D exchange; Isotope effects; Methyl cation; Statistical distributions

Indexed keywords

EID: 4243954062     PISSN: 01681176     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0168-1176(97)00103-1     Document Type: Article

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16. Since vibrational frequency depends on the reduced mass of two dissociating moieties, the relative frequencies become 1:0.83:0.73. This is remarkably close to our fit 1:0.82:0.75.
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