Thermodynamics of salt lake system: Representation, experiments, and visualization

AIChE Journal

Volumn 54, Issue 3, 2008, Pages 706-727

  Kwok, Kui S ^a   Ng, Ka M ^a   Taboada, Maria E ^b   Cisternas, Luis A ^b  

^a HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

^b UNIVERSIDAD DE ANTOFAGASTA   (Chile)

Author keywords

Crystallization; High dimensional phase diagram; Process design; Salt lake system; Solid liquid equilibrium; Thermodynamic model development

Indexed keywords

CRYSTALLIZATION; LITHIUM COMPOUNDS; MATHEMATICAL MODELS; PROCESS DESIGN;

HIGH-DIMENSIONAL PHASE DIAGRAM; SALT LAKE SYSTEM; THERMODYNAMIC MODEL DEVELOPMENT;

WATER ANALYSIS;

CRYSTALLIZATION; LITHIUM COMPOUNDS; MATHEMATICAL MODELS; PROCESS DESIGN; WATER ANALYSIS;

EID: 42149188813     PISSN: 00011541     EISSN: 15475905     Source Type: Journal    
DOI: 10.1002/aic.11421     Document Type: Article

References (58)

1. Arnold DS, Fairchild JL, Nichols DA, Coe MD. Process for producing sodium carbonate from complex brines. US Pat No 4,291,002; 1981.
2. Mehta VC. Process for recovering lithium from salt brines. US Pat No. 4,723,962; 1988.
3. Jongema P. Process of the precipitation of sodium chloride. US Pat No 5,221,528; 1993.
4. Efraim I, Lampert S, Holdengraber C. Co-production of potassium sulfate, sodium sulfate, and sodium chloride. US Pat. No. 5,552,126; 1996.
5. Wilkomirsky I. Production of lithium carbonate from brines. U.S. Pat No 5,993,759; 1999.
6. Lukes J. Process for obtaining monohydrated lithium sulfate from natural brines. U.S. Pat No 6,547,836 B1; 2003.
7. Berry DA, Ng KM. Separation of quaternary conjugate salt systems by fractional crystallization. AIChE J. 1996;42:2162-2174.
8. Wibowo C, Ng KM. Unified approach for synthesizing crystallization-based separation processes. AIChE J. 2000;46:1400-1421.
9. Schroer JW, Ng KM. Simplify multicomponent crystallization. Chem Eng. 2001;108:46-53.
10. Cisternas LA. Optimal design of crystallization-based separation schemes. AIChE J. 1999;45:1477-1487.
11. Cisternas LA, Torres MA, Godoy MJ, Swaney RE. Design of separation schemes for fractional crystallization of metathetical salts. AIChE J. 2003;49:1731-1742.
12. Cisternas LA, Cueto J, Swaney R. Flowsheet synthesis of fractional crystallization processes with cake washing. Comput Chem Eng. 2004;28:613-623.
13. Cisternas LA, Vasquez CM, Swaney RE. On the design of crystallization-based separation processes: review and extension. AIChE J. 2006;52:1754-1769.
14. Zemaitis JF Jr, Clark DM, Rafal M, Scrivner NC. Handbook of Aqueous Electrolyte Thermodynamics: Theory and Application. New York: AIChE, 1986.
15. OLI Systems, Inc. Available at: http://www.olisystems.com/. Accessed December 20, 2006.
16. Wibowo C, O'Young L, Ng KM. Streamlining crystallization process design. Chem Eng Prog. 2004;100:30-39.
17. Ma PH, Wang ZC, Xu G, Song ZH. Comprehensive exploitation of Ei Salar de Atacama salt lake. J Salt Lake Sci. 1998;6:61-66.
18. Torres MA, Cisternas LA, Galleguillos HR, Vargas PE. Determination of the Pitzer parameters for the solid-liquid equilibrium. Ingeniería Química. 2005;28:54-64.
19. Sander B, Fredenslund A, Rasmussen P. Calculation of vapor-liquid equilibria in mixed solvent/salt systems using an extended UNIQUAC equation. Chem Eng Sci. 1986;41:1171-1183.
20. Sander B, Fredenslund A, Rasmussen P. Calculation of solid-liquid equilibria in aqueous solutions of nitrate salts using an extended UNIQUAC equation. Chem Eng Sci. 1986;41:1197-1202.
21. Samant KD, Ng KM. Representation of high-dimensional solidliquid phase diagrams for ionic systems. AIChE J. 2001;47:861-879.
22. Wibowo C, Ng KM. Visualization of high-dimensional phase diagrams of molecular and ionic mixtures. AIChE J. 2002;48:991-1000.
23. Wibowo C, Ng KM. Visualization of high-dimensional systems via geometric modeling with homogeneous coordinates. Ind. Eng. Chem. Res. 2002;41:2213-2225.
24. Silcock HL, editor. Solubilities of Inorganic and Organic Compounds, Vol. 3, Part 3, Oxford, England: Pergamon Press, 1979.
25. 2O Between 0°C and 100°C. Russ J Inorg Chem. 1960;5:92-96.
26. 2, and water, at 25°C. Can J Chem. 1958;36:1511-1517.
27. Yanko AP. Symposium: "Physico-chemical analysis." (Fizikokhimicheskii analiz.) Otd Akad Nauk SSSR Novosibirsk. 1963;141.
28. Blasdale WC. Equilibria in solutions containing mixtures of salts. I. The system water and the sulfates and chlorides of sodium and potassium. J Ind Eng Chem. 1918;10:344-347.
29. Yanat'eva OK. Izv Sektora Fiz-Khim Anal Akad Nauk SSSR. 1949;17:373.
30. Rustamov PG, Bergman AG. Zh Neorgan Khim. 1958;3:2184.
31. Kurnakov NS, Luk'yanova EI. Izv Akad Nauk SSSR Ser Khim. 1938;1:41-42.
32. Kurnakov NS, Shoikhet DN. Izv Sektora Fiz Khim Anal Akad Nauk SSSR. 1938;10:310.
33. Solov'eva EF. Tr Vses Nauch Issled Inst Gal. 1953;27:67.
34. Van't Hoff JH, Meyerhoffer W. Sitzungsber. Preuss Akad. 1898;37.
35. Blasdale WC. Equilibria in solutions containing mixtures of salts. II. The system water and the chlorides and sulfates of sodium and magnesium at 25°C. J Ind Eng Chem. 1920;12:164-167.
36. Takegami S. Mem Coll Sci Kyoto Imp Univ. 1921;4:317.
37. Kurnakov NS, Zemcuznyj SF. Z Anorg Allgem Chem. 1924;140:149.
38. Leimbach G, Pfeiffenberg A. Caliche. 1929; 11:64.
39. Kurnakov NS, Opykhtina MA. Izv Inst Fiz Khim Anal Akad Nauk SSSR. 1930;4:368-373.
40. Nikolaev VI, Burovaya EE. Izv Sektora Fiz Khim Anal Akad Nauk SSSR. 1938;10:248.
41. Rode T. Izv Sektora Fiz Khim Anal Anal Nauk SSSR. 1947;15:237.
42. Pel'sh AD. Tr Vses Nauch Issled Inst Gal. 1953;27:3.
43. Autenrieten H, Braun G. Kali und Steinsalz. 1960;3:15.
44. Autenrieten H, Braun G. Kali und Steinsalz. 1960;3:85.
45. Nývlt J. Solid-Liquid Phase Equilibria. Amsterdam, Netherlands: Elsevier Scientific, 1977.
46. Cohen-Adad R, Cohen-Adad MT. Solubility of solids in liquids. In: Hefter GT, Tomkins RPT, editors. The Experimental Determination of Solubilities. Wiley Series in Solution Chemistry, Vol. 6. Chichester, England: Wiley, 2003.
47. Mullin JW. Crystallization, 4th ed. Oxford, England: Butterworth Heinemann, 2001.
48. Druzhinin IG, Yanko AP. Dokl Akad Nauk SSSR. 1954;94:481.
49. Druzhinin IG, Yanko AP. Tr Inst Khim Akad Nauk Krig SSR. 1955;6:3.
50. 2O system. Russ J Inorg Chem. 1959;4:536-538.
51. Voskresenskaya NK, Yanat'eva OK. Izv Akad Nauk SSSR Ser Khim. 1937;1:97.
52. 2O system at 25°C. Russ J Inorg Chem. 1959;4:1301-1303.
53. Linke WF, Seidell A, editors. Solubilities of Inorganic and Metal Organic Compounds. Washington DC: American Chemical Society, 1965.
54. 2O ternary system at 25°C, 50°C, 90°C and 100°C. Russ J Inorg Chem. 1960;5:90-92.
55. 2O system. Russ J Inorg Chem 1959;4:864-868.
56. 2O System. Russ J Inorg Chem 1959;4:652-654.
57. 2O. Can J Chem. 1958;36:171-175.
58. Taboada ME, Cisternas LA, Cheng YS, Ng KM. Design of alternative purification processes for potassium sulfate. Ind Eng Chem Res 2005;44:5845-5851.