Surfactant-free synthesis of amphiphilic copolymer of poly(styrene-co-acrylamide) in aqueous emulsion with the assistance of ultrasound

Polymers for Advanced Technologies

Volumn 19, Issue 3, 2008, Pages 221-228

  Yan, Lifeng ^a   Ji, Jing ^a   Xie, Dinghai ^a   Li, Wan ^a   Zhang, Guangzhao ^a  

^a UNIVERSITY OF SCIENCE AND TECHNOLOGY OF CHINA   (China)

Author keywords

Amphiphilic copolymer; Emulsion; Surfactant free; Ultrasound

Indexed keywords

DIFFERENTIAL SCANNING CALORIMETRY; EMULSIONS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROPHILICITY; HYDROPHOBICITY; LIGHT SCATTERING; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYACRYLATES; SIZE EXCLUSION CHROMATOGRAPHY; SURFACE ACTIVE AGENTS;

AMPHIPHILICITY; HYDROPHILIC MONOMER ACRYLAMIDE;

POLYSTYRENES;

DIFFERENTIAL SCANNING CALORIMETRY; EMULSIONS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROPHILICITY; HYDROPHOBICITY; LIGHT SCATTERING; MONOMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; POLYACRYLATES; POLYSTYRENES; SIZE EXCLUSION CHROMATOGRAPHY; SURFACE ACTIVE AGENTS;

COPOLYMER; EMULSION; HYDROPHILIC PROPERTY; MONOMER; SURFACE-ACTIVE AGENT;

EID: 42149181293     PISSN: 10427147     EISSN: 10991581     Source Type: Journal    
DOI: 10.1002/pat.1000     Document Type: Article

References (27)

1. Alexandridis P. Poly(ethylene oxide) poly(propylene oxide) block copolymer surfactants. Curr. Opin. Colloid Interface Sci. 1997; 2: 478.
2. Soo PL, Eisenberg A. Preparation of block copolymer vesicles in solution. J. Polym. Sci.: Part B: Polym. Phys. 2004; 42: 923.
3. Srinivasulu B, Rao PR, Sundaram EV. Synthesis and characterization of ethyl-methacrylate acrylamide copolymers. J. Appl. Polym. Sci. 1991; 43: 1521.
4. Sanayei RA, Odriscoll KF, Klumperman B. Pulzed-laser compolymerization of styrene and maleri-anhydride. Macromolecules 1994; 37: 5577.
5. Willert M, Landfester K. Amphiphilic copolymers from miniemulsified systems. Macromole. Chem. Phys. 2002; 203: 825.
6. Napoli N, Tirelli N, Kilcher G, Hubbell JA. New synthetic methodologies for amphiphilic multiblock copolymers of ethylene glycol and propylene sulfide. Macromolecules 2001; 34: 8913.
7. Narumi A, Matsuda T, Kaga H. Synthesis of amphiphilic triblock copolymer of polystyrene and poly(4-vinylbenzyl glucoside) via TEMPO-mediated living radical polymerization. Polymer 2002; 43: 4835.
8. Lovell PA, El-Aasser MS. Emulsion Polymerization and Emulsion Polymer. Wiley: New York, 1997.
9. Burguiere C, Chassenieux C, Charleux B. Characterization of aqueous micellar solutions of amphiphilic block copolymers of poly(acrylic acid) and polystyrene prepared via ATRP. Toward the control of the number of particles in emulsion polymerization. Polymer 2003; 44: 509.
10. Montoya-Goni A, Sherrington DC, Schoonbrood HAS, Asua JM. Reactive surfactants in heterophase polymerization. XXIV. Emulsion polymerization of styrene with maleate- and succinate-containing cationic surfactants. Polymer 1999; 40: 1359.
11. Mason TJ, Cintas, P. Sonochemistry. In Handbook of Green Chemistry and Technology, Clarke J, Macquarrie D (eds). Blackwell: Oxford, 2002; 372-396.
12. Wadhawan JD, Marken F, Compton RG. Biphasic sonoelectrosynthesis. A review. Pure. Appl. Chem. 2001; 73: 1947.
13. Yan L, Wu H, Zhu Q. Emulsifier-free ultrasonic emulsion copolymerization of styrene with acrylic acid in water. Green Chem. 2004; 6: 99-103.
14. Yin N, Chen K. Ultrasonically initiated emulsifier-free emulsion copolymerization of n-butyl acrylate and acrylamide. Part I: polymerization mechanism. Polymer 2004; 45: 3587.
15. Wang C, Tao Z, Yang W, Fu S. Synthesis and photoconductivity study of C60-containing styrene/acrylamide copolymers. Macromol. Rapid Commun. 2001; 21: 98.
16. Zhang L, Zeng Z, Chen Y, Wu C, Gao J. Photoinitiated copolymerization of acrylamide and styrene in oil-in-water microemulsion. J. Appl. Polym. Sci. 1997; 66: 2543.
17. Ma G, Sone H, Omi S. Preparation of uniform-sized polystyrene-polyacrylamide composite microspheres from a W/O/W emulsion by membrane emulsification technique and subsequent suspension polymerization. Macromolecules 2004; 37: 2954.
18. Zimm BH. J. Chem. Phys. 1948; 16: 1099.
19. Chu B. Laser Light Scattering (2nd edn). Academic Press: New York, 1991.
20. Berne B, Pecora R. Dynamic Light Scattering. Plenum Press: New York, 1976.
21. Bradley MA, Grieser F. Emulsion polymerization synthesis of cationic polymer latex in an ultrasonic field. J. Colloid Interface Sci. 2002; 251: 78-7884.
22. Bradley MA, Prescott SW, Schoonbrood HAS, Landfester K, Grieser F. Emulsion polymerization synthesis of cationic polymer latex in an ultrasonic field. Macromolecules 2005; 38: 6346-6351.
23. Zhang X, Liu W, Chen Y, Gong A, Chen C, Xi F. Self-condensing vinyl polymerization of acrylamide. Polym. Bull. 1999; 43: 29.
24. Antonietti M, Landfester K. Polyreactions in miniemulsion. Prog. Polym. Sci. 2002; 27: 689.
25. Mark JE (ed.). Polymer Data Handbook. Oxford University Press: Oxford, 1999.
26. Liu S, Sen A. Syntheses of syndiotactic-polystyrene-graft-poly (methyl methacrylate), syndiotactic-polystyrene-graft-poly (methyl acrylate), and syndiotactic-polystyrene-graft-atactic-polystyrene with defined structures by atom transfer radical polymerization. Macromolecules 2000; 33: 5106.
27. Zhang LA. Formation of crew-cut aggregates of various morphologies from amphiphilic block copolymers in solution. Eisenberg. Polym. Adv. Technol. 1998; 9: 677.