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Volumn 47, Issue 6, 2008, Pages 2190-2195

Factors affecting the selectivity of the oxidation of methyl p-toluate by cobalt(III)

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EID: 42149158925     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic701634b     Document Type: Article
Times cited : (4)

References (27)
  • 10
    • 0002899824 scopus 로고
    • Up to 90% of the total cobalt was reportedly converted to Co(III) by this method
    • (b) Jones, G. H. J. Chem. Res., Miniprint 1981, 2801 . Up to 90% of the total cobalt was reportedly converted to Co(III) by this method.
    • (1981) J. Chem. Res., Miniprint , pp. 2801
    • Jones, G.H.1
  • 11
    • 0000029443 scopus 로고    scopus 로고
    • 6] with methyl toluate was slow at 100°C.
    • 6] with methyl toluate was slow at 100°C.
  • 12
    • 42149159240 scopus 로고    scopus 로고
    • Small amounts of other polyaromatic compounds such as dimethyl stilbenedicarboxylate, dimethyl methyldicarboxybenzophenone isomers, and bis(4-carbomethoxyphenyl)ethanone were also detected. The relatively low mass balance with respect to Co(III) could be partly due to the number of minor products produced during the oxidation.
    • Small amounts of other polyaromatic compounds such as dimethyl stilbenedicarboxylate, dimethyl methyldicarboxybenzophenone isomers, and bis(4-carbomethoxyphenyl)ethanone were also detected. The relatively low mass balance with respect to Co(III) could be partly due to the number of minor products produced during the oxidation.
  • 20
    • 42149097586 scopus 로고    scopus 로고
    • 4H], and cobaltic acetate (generated in situ by the addition of peracetic acid to a solution of cobaltous acetate) were measured at room temperature in a 96% acetic acid solution against a 3 M Ag/AgCl electrode. The solutions were 0.1 M in cobalt and the observed potentials were 1074, 1149, and 1255 mV, respectively.
    • 4H], and cobaltic acetate (generated in situ by the addition of peracetic acid to a solution of cobaltous acetate) were measured at room temperature in a 96% acetic acid solution against a 3 M Ag/AgCl electrode. The solutions were 0.1 M in cobalt and the observed potentials were 1074, 1149, and 1255 mV, respectively.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.