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Up to 90% of the total cobalt was reportedly converted to Co(III) by this method
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(b) Jones, G. H. J. Chem. Res., Miniprint 1981, 2801 . Up to 90% of the total cobalt was reportedly converted to Co(III) by this method.
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6] with methyl toluate was slow at 100°C.
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6] with methyl toluate was slow at 100°C.
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12
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42149159240
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Small amounts of other polyaromatic compounds such as dimethyl stilbenedicarboxylate, dimethyl methyldicarboxybenzophenone isomers, and bis(4-carbomethoxyphenyl)ethanone were also detected. The relatively low mass balance with respect to Co(III) could be partly due to the number of minor products produced during the oxidation.
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Small amounts of other polyaromatic compounds such as dimethyl stilbenedicarboxylate, dimethyl methyldicarboxybenzophenone isomers, and bis(4-carbomethoxyphenyl)ethanone were also detected. The relatively low mass balance with respect to Co(III) could be partly due to the number of minor products produced during the oxidation.
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Cvengrosova, A.1
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Kizlink, J.3
Pasternakova, T.4
Holotik, S.5
Ilavsky, J.6
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20
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42149097586
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4H], and cobaltic acetate (generated in situ by the addition of peracetic acid to a solution of cobaltous acetate) were measured at room temperature in a 96% acetic acid solution against a 3 M Ag/AgCl electrode. The solutions were 0.1 M in cobalt and the observed potentials were 1074, 1149, and 1255 mV, respectively.
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4H], and cobaltic acetate (generated in situ by the addition of peracetic acid to a solution of cobaltous acetate) were measured at room temperature in a 96% acetic acid solution against a 3 M Ag/AgCl electrode. The solutions were 0.1 M in cobalt and the observed potentials were 1074, 1149, and 1255 mV, respectively.
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22
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0037381094
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Beattie, J. K.; Klepetko, J. A.; Masters, A. F.; Turner, P. Polyhedron 2003, 22, 947.
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Turner, P.4
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