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42049102546
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The stereochemical outcomes can be rationalized by the cyclization of the intermediate 7 and its analogues via a chair-like cyclic transition structure in which all substituents on the ring occupy the equatorial positions. See Refs. 3c and 4b.
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The stereochemical outcomes can be rationalized by the cyclization of the intermediate 7 and its analogues via a chair-like cyclic transition structure in which all substituents on the ring occupy the equatorial positions. See Refs. 3c and 4b.
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13
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0000372120
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2(L)-AgOTf catalyst system: Y. Kataoka, O. Matsumoto, K. Tani, Organometallics 1996, 15, 5246;
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14
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1642281558
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0000591830
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II-catalyzed alkene migration: J. F. Harrod, A. J. Chalk, J. Am. Chem. Soc. 1964, 86, 1776;
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II-catalyzed alkene migration: J. F. Harrod, A. J. Chalk, J. Am. Chem. Soc. 1964, 86, 1776;
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