Investigation of the dynamic stereochemistry of dimesityl-2,4,6- trimethoxyphenylmethane by complete lineshape analysis and 2D EXSY NMR spectroscopy

Magnetic Resonance in Chemistry

Volumn 46, Issue 4, 2008, Pages 362-369

  Denkova, Pavletta ^a,b   Vassilev, Nikolay ^a   Van Lokeren, Luk ^b   Willem, Rudolph ^b  

^a INSTITUTE OF ORGANIC CHEMISTRY   (Bulgaria)

^b VRIJE UNIVERSITEIT BRUSSEL   (Belgium)

Author keywords

2D EXSY; 1H NMR; Activation parameters; Complete lineshape analysis; Dynamic NMR; Linear prediction; Modes of rearrangement; Organic propellers; Reference deconvolution; Residual diastereotopism

Indexed keywords

ACTIVATION ANALYSIS; CHEMICAL ACTIVATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROPELLERS; RATE CONSTANTS; TEMPERATURE DISTRIBUTION;

1H NMR; 2D EXSY; ACTIVATION PARAMETER; COMPLETE LINESHAPE ANALYSE; DECONVOLUTIONS; DYNAMIC NMR; LINE SHAPE ANALYSIS; LINEAR PREDICTION; MODE OF REARRANGEMENT; ORGANIC PROPELLER; ORGANICS; REFERENCE DECONVOLUTION; RESIDUAL DIASTEREOTOPISM;

STEREOSELECTIVITY;

BENZENE DERIVATIVE; DIMESITYL 2,4,6 TRIMETHOXYPHENYLMETHANE; DIMESITYL-2,4,6-TRIMETHOXYPHENYLMETHANE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL MODEL; COMPUTER SIMULATION; CONFORMATION; METHODOLOGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM THEORY; STANDARD; STEREOISOMERISM; TEMPERATURE;

BENZENE DERIVATIVES; COMPUTER SIMULATION; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; MOLECULAR CONFORMATION; QUANTUM THEORY; REFERENCE STANDARDS; STEREOISOMERISM; TEMPERATURE;

EID: 42049103943     PISSN: 07491581     EISSN: 1097458X     Source Type: Journal    
DOI: 10.1002/mrc.2183     Document Type: Article

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