Diffusion of a highly charged supramolecular assembly: Direct observation of ion association in water

Inorganic Chemistry

Volumn 47, Issue 5, 2008, Pages 1411-1413

  Pluth, Michael D ^a   Tiedemann, Bryan E F ^a   Van Halbeek, Herman ^a   Nunlist, Rudi ^a   Raymond, Kenneth N ^a  

^a NONE

Author keywords

[No Author keywords available]

Indexed keywords

EID: 41849128172     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic7020885     Document Type: Article

References (35)

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30. Different interactions with varying alkali cations have been previously observed with 1. For example, see ref 6e.
31. Aggregation at high KCl concentrations is unlikely due to the high charge of 1.
32. + is negligible.
33. Pluth, M. D.; Bergman, R. G.; Raymond, K. N. J. Am. Chem. Soc. 2007, 129, 11459-11467.
34. Although added KCl could change the viscosity of the solution and thereby the diffusion coefficients, only a slight increase (< 5%) in the diffusion coefficient of 1 was observed in the course of the titration.
35. Sgarlata, C.; Tiedemann, B. E. F.; Arena, G.; Raymond, K. N., to be submitted for publication.