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Volumn 128, Issue 13, 2008, Pages

Adsorption geometry variation of 1,4-benzenedimethanethiol self-assembled monolayers on Au(111) grown from the vapor phase

Author keywords

[No Author keywords available]

Indexed keywords

BONDING; CHEMISORPTION; MOLECULAR ORIENTATION; PHOTOELECTRON SPECTROSCOPY; SELF ASSEMBLED MONOLAYERS; SURFACE REACTIONS; X RAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY;

EID: 41849127815     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.2876118     Document Type: Article
Times cited : (42)

References (47)
  • 26
    • 41849093898 scopus 로고
    • Atomic Calculation of Photoionization Cross-Sections and Asymmetry Parameters (Gordon and Breach Science, New York).
    • J. J. Yeh and I. Lindau, Atomic Calculation of Photoionization Cross-Sections and Asymmetry Parameters (Gordon and Breach Science, New York, 1993).
    • (1993)
    • Yeh, J.J.1    Lindau, I.2
  • 32
    • 0003105868 scopus 로고
    • in Advances in Quantum Chemistry, edited by P. O. Loewdin, (Academic, New York),.
    • J. C. Slater, in Advances in Quantum Chemistry, edited by, P. O. Loewdin, (Academic, New York, 1972), p. 1.
    • (1972) , pp. 1
    • Slater, J.C.1
  • 43
    • 41849087880 scopus 로고
    • NEXAFS Spectroscopy, Springer Series in Surface Science Vol 25 (Springer, Berlin).
    • J. Stöhr, NEXAFS Spectroscopy, Springer Series in Surface Science Vol 25 (Springer, Berlin, 1992).
    • (1992)
    • Stöhr, J.1
  • 47
    • 0038581625 scopus 로고    scopus 로고
    • The NEXAFS analysis does not consider here any possible molecular twist: in principle, the angle α of the π* resonance can be related to the tilt angle of the molecular major axis with respect to the surface normal and to the twist angle of the aromatic ring with respect to the plane formed by the surface normal and the molecular major axis [see, for instance, ()]. If the twist angle of the molecule is known, the tilt of the molecular major axis can be derived. In the present case, due to the superposition of different molecular arrangements and to the possible random disposition of the molecules or their domains at the surface, no assumptions valid for the entire sampled region can be made regarding the molecular twist angles.
    • The NEXAFS analysis does not consider here any possible molecular twist: in principle, the angle α of the π* resonance can be related to the tilt angle of the molecular major axis with respect to the surface normal and to the twist angle of the aromatic ring with respect to the plane formed by the surface normal and the molecular major axis [see, for instance, M. Zharnikov, A. Küller, A. Shaporenko, E. Schmidt, and W. Eck, Langmuir 19, 4682 (2003)]. If the twist angle of the molecule is known, the tilt of the molecular major axis can be derived. In the present case, due to the superposition of different molecular arrangements and to the possible random disposition of the molecules or their domains at the surface, no assumptions valid for the entire sampled region can be made regarding the molecular twist angles.
    • (2003) Langmuir , vol.19 , pp. 4682
    • Zharnikov, M.1    Küller, A.2    Shaporenko, A.3    Schmidt, E.4    Eck, W.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.