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Volumn 73, Issue 7, 2008, Pages 2768-2773

A concise synthesis of ent-cholesterol

Author keywords

[No Author keywords available]

Indexed keywords

METABOLISM; SYNTHESIS (CHEMICAL);

EID: 41649095760     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo702694g     Document Type: Article
Times cited : (19)

References (22)
  • 10
    • 41649092773 scopus 로고    scopus 로고
    • 4 reduction gave a primary alcohol. The optical purity of this alcohol could be assayed using HPLC analysis on a Chiracel OD-H column, eluting with 3% i-PrOH in hexanes. The optical purity of (S)-citronellol purchased from TCI was found to be ca. 60% ee, whereas the more expensive (S)-citronellol from Aldrich was found to be >97% ee.
    • 4 reduction gave a primary alcohol. The optical purity of this alcohol could be assayed using HPLC analysis on a Chiracel OD-H column, eluting with 3% i-PrOH in hexanes. The optical purity of (S)-citronellol purchased from TCI was found to be ca. 60% ee, whereas the more expensive (S)-citronellol from Aldrich was found to be >97% ee.
  • 18
    • 41649089389 scopus 로고    scopus 로고
    • 3 Their attempted conversion of acid 9 to the exo enone intermediate by treatment with formaldehyde and piperidine led to a complex mixture of products. In our hands the sequence was successful with very careful handling but was not easily scalable.
    • 3 Their attempted conversion of acid 9 to the exo enone intermediate by treatment with formaldehyde and piperidine led to a "complex mixture of products." In our hands the sequence was successful with very careful handling but was not easily scalable.
  • 22
    • 0016711144 scopus 로고    scopus 로고
    • Sauer, G.; Eder, U.; Haffer, G.; G.; Neef, G.; Wiechert, R. Angew. Chem., Int. Ed. 1975, 14, 413-414.
    • Sauer, G.; Eder, U.; Haffer, G.; G.; Neef, G.; Wiechert, R. Angew. Chem., Int. Ed. 1975, 14, 413-414.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.