Halogen-magnesium exchange of m- and p-iodo or bromo-arenes bearing ortho-directing groups through ate complexes

Tetrahedron Letters

Volumn 45, Issue 34, 2004, Pages 6399-6402

  Xu, Jiayi ^a   Jain, Nareshkumar ^a   Sui, Zhihua ^a  

^a LLC1000 Rte 202 Raritan N ^*  (United States)

Author keywords

Ate complexes; Magnesium halogen exchange; ortho Directing groups; Phenols; Phenoxy alcohols

Indexed keywords

HALOGEN; INDOLE DERIVATIVE; MAGNESIUM; POLYCYCLIC AROMATIC HYDROCARBON DERIVATIVE;

ALKYLATION; ARTICLE; CHEMICAL REACTION; HALOGENATION; IODINATION; METALLATION;

EID: 4143134216     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2004.07.005     Document Type: Article

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45. 2, 1:1 hexanes-EtOAc) yielded 11 as a colorless oil (275 mg, 81%)
46. 4. Concentration and purification by chromatography provided compound 10 (122 mg, 0.56 mmol, 82%)