Importance of adsorption (hole-filling) mechanism for hydrophobic organic contaminants on an aquifer kerogen isolate

Environmental Science and Technology

Volumn 38, Issue 16, 2004, Pages 4340-4348

  Ran, Yong ^a   Xing, Baoshan ^b   Rao, P Suresh C ^c   Fu, Jiamo ^a  

^a GUANGZHOU INSTITUTE OF GEOCHEMISTRY   (China)

^b UNIVERSITY OF MASSACHUSETTS   (United States)

^c PURDUE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AQUIFERS; DEFORMATION; HYDROPHOBICITY; IMPURITIES; ISOTHERMS; KEROGEN; MATHEMATICAL MODELS; MOLECULES; ORGANIC COMPOUNDS; PARAMETER ESTIMATION;

AQUEOUS CONCENTRATIONS; HOLE-FILLING; ORGANIC CARBON; PARTITION COEFFICIENTS;

ADSORPTION;

1,2 DICHLOROBENZENE; 1,3,5 TRICHLOROBENZENE; NAPHTHALENE; ORGANIC CARBON; ORGANIC COMPOUND; PHENANTHRENE DERIVATIVE;

KEROGEN; ORGANIC COMPOUND; SORPTION;

ADSORPTION; AQUEOUS SOLUTION; AQUIFER; ARTICLE; CONCENTRATION (PARAMETERS); DESORPTION; DISPERSION; EQUILIBRIUM CONSTANT; HYDROPHOBICITY; HYSTERESIS; ISOTHERM; MOLECULAR SIZE; PARTITION COEFFICIENT; POROSITY; SOLUBILITY;

ADSORPTION; CARBON; ENVIRONMENTAL POLLUTANTS; GEOLOGIC SEDIMENTS; HYDROCARBONS; MODELS, THEORETICAL; SOLUBILITY;

EID: 4143116585     PISSN: 0013936X     EISSN: None     Source Type: Journal    
DOI: 10.1021/es035168+     Document Type: Article

References (50)

1. Chiou, C. T. Theoretical consideration of the partition uptake of nonionic organic compounds by soil organic matter. In Reactions and Movement of Organic Chemicals in Soil; Sawhney, B L., Brown, K., Eds.; Soil Sci. Soc. Am. Special Publ. No. 22: Madison, WI, 1989; pp 1-30.
2. Weber, W. J., Jr.; McGinley, P. M.; Katz, L. E. A distributed reactivity model for sorption by soils and sediments: 1. Conceptual basis and equilibrium assessments. Environ. Sci. Technol. 1992, 26, 1955-1962.
3. Weber, W. J., Jr.; LeBoeuf, E. J.; Young, T. M.; Huang, W. Contaminant interactions with geosorbent organic matter: Insights drawn from polymer sciences. Water Res. 2001, 35, 853-868.
4. Pignatello, J. J.; Xing, B. Mechanisms of slow sorption of organic chemicals to natural particles. Environ. Sci. Technol. 1996,30, 1-11.
5. Luthy, R. D.; Aiken, G. R.; Brusseau, M. L.; Cunningham, D. S.; Gschwend, P. M.; Pignatello, J. J.; Reinhard, M.; Traina, S. J.; Weber, W. I., Jr.; Westall, I. C. Sequestration of hydrophobic organic contaminants by geosorbents. Environ. Sci. Technol. 1997, 31, 3341-3347.
6. Brusseau, M. L.; Jessup, R. E.; Rao, P. S. C. Nonequilibrium sorption of organic chemicals: Elucidation of rate-limiting processes. Environ. Sci. Technol. 1991, 25, 134-142.
7. Weber, W. J., Jr.; Huang, W. A distributed reactivity model for sorption by soils and sediments: 4. Intraparticle heterogeneity and phase-distribution relationships under nonequilibrium conditions. Environ. Sci. Technol. 1996, 30, 881-888.
8. Durand, E. Kerogen: Insoluble Organic Matter from Sedimentary Rocks; Editions Technip: Paris, 1980.
9. Tissot, B. P.; Welte, D. H. Petroleum Formation and Occurrence; Springer-Verlag: New York, 1984.
10. Allen-King, R. M.; Albanese, C. L.; Martin, J. P.; Roeder, R. Organic carbon dominated trichloroethene sorption in a clay-rich glacial deposit. Ground Water 1997, 35, 124-130.
11. Ran, Y.; Xiao, B.; Huang, W.; Peng, P.; Liu, D.; Fu, J.; Sheng, G. Kerogen in aquifer material and its strong sorption for nonionic organic pollutants. J. Environ. Qual. 2003, 32, 1701-1709.
12. Ran, Y.; Xiao, B.; Fu, J.; Sheng, G. Sorption and desorption hysteresis of organic contaminants by kerogen in a sandy aquifer material. Chemosphere 2003, 50, 1365-1376.
13. McGinley, P. M.; Katz, L. E.; Weber, W. J., Jr. A distributed reactivity model for sorption by soils and sediments: 2. Multicomponent systems and competitive effects. Environ. Sci. Technol. 1993, 27, 1524-1531.
14. Carroll, K. M.; Harkness, M. R.; Bracco, A. A.; Balcarcel, R. R. Application of a permeat/polymer diffusional model to the desorption of polychlorinated biphenyls from Hudson River sediments. Environ. Sci. Technol. 1994, 28, 253-258.
15. Young, T. M.; Weber, W. J., Jr. A distributed reactivity model for sorption by soils and sediments: 3. Effects of diagenetic processes on sorption energetics. Environ. Sci. Technol. 1995, 29, 92-97.
16. Xing, B.; Pignatello, J. J.; Gigliotti, B. Competitive sorption between atrazine and other organic compounds in soils and model sorbents. Environ. Sci. Technol. 1996, 30, 2432-2440.
17. Xing, B.; Pignatello, J. J. Dual-mode sorption of low-polarity compounds in glassy poly(vinyl chloride) and soil organic matter. Environ. Sci. Technol. 1997, 31, 792-799.
18. Schnitzer, M.; Schulten, H.-R. Analysis of organic matter in soil extracts and whole soils by pyrolysis-mass spectrometry. Adv. Agron. 1995, 55, 167-217.
19. Wershaw, R. L. Model for humus in soils and sediments. Environ. Sci. Technol. 1993, 27, 814-816.
20. Huang, W.; Weber, W. J., Jr. A distributed reactivity model for sorption by soils and sediments. 10. Relationships between desorption, hysteresis, and the chemical characteristics of organic domains. Environ. Sci. Technol. 1997, 31, 2562-2569.
21. 2 on soil organic matter: Nature of porosity, surface area, and diffusion mechanisms. Environ. Sci. Technol. 1996, 30, 408-413.
22. Li, J.; Werth, C. J. Evaluating competitive sorption mechanisms of volatile organic compounds in soils and sediments using polymers and zeolites. Environ. Sci. Technol. 2001, 35, 568-574.
23. Braida, W. J.; Pignatello, J. J.; Lu, Y.; Ravikovitch, P. I.; Neimark, A. V.; Xing, B. Sorption hysteresis of benzene in charcoal particles. Environ. Sci. Technol. 2003, 37, 409-417.
24. Ran, Y.; Huang, W.; Rao, P. S. C.; Liu, D.; Sheng, G.; Fu, J. The roles of condensed organic matter in the nonlinear sorption of hydrophobic organic contaminants by a peat and sediments. J. Environ. Qual. 2002, 31, 1953-1962.
25. Xia, G.; Ball, W. P. Adsorption- partition uptake of nine low-polarity organic chemicals on a natural sorbent. Environ. Sci. Technol. 1999, 33, 262-269.
26. Kleineidam, S.; Schuth, C.; Grathwohl, P. Solubility-normalized combined adsorption-partitioning sorption isotherms for organic pollutants. Environ. Sci. Technol. 2002, 36, 4689-4697.
27. Dachs, J.; Eisenreich, S. J. Adsorption and partitioning of organic compounds onto/ into fractal sorbents. Langmuir 2001, 17, 2533-2537.
28. Dachs, J.; Bayona, J. M. Langmiur- derived model for diffusion- and reaction- limited adsorption of organic compounds on fractal aggregates. Environ. Sci. Technol. 1997, 31, 2754-2760.
29. Harris, L. A.; Yust, C. S. Transmission electron microscopy observations of porosity in coal. Fuel 1976, 55, 233-236.
30. Oberlin, A.; Boulmier, J. L. Electron microscopic study of kerogen microtexture: Selected criteria for determining the evolution path and evolution stage of kerogen. In Kerogen: Insoluble Organic Matter from Sedimentary Rock; Durand, B., Ed.; Editions Technip: Paris, 1980; pp 191-241.
31. Swanson, R. A.; Dutt, G. R. Chemical and physical processes that affect atrazine distribution in soil systems. Soil Sci. Soc. Am. Proc. 1973, 37, 872-876.
32. Bowman, B. T. Method of repeated additions for generating pesticide adsorption-desorption isotherm data. Can. J. Soil Sci. 1979, 59, 435-437.
33. Schwarzenbach, R. P.; Gschwend, P. M.; Imboden, D. M. Environmental Organic Chemistry; John Wiley & Sons: New York, 1993.
34. Carmo, A. M.; Hundal, L. S.; Thompson, M. L. Sorption of hydrophobic organic compounds by soil materials: Application of unit equivalent Freundlich coefficients. Environ. Sci. Technol. 2000, 34, 4363-4369.
35. Crittenden,J. C.; Sanongraj, S.; Bulloch, J. L.; Hand, D. W.; Rogers, T. N.; Speth, T. F.; Ulmer, W. Correlation of aqueous-phase adsorption isotherms. Environ. Sci. Technol. 1999, 33, 2926-2933.
36. Cousins, I. T.; Mackay, D. Gas-particle partitioning of organic compounds and its interpretation using relative solubilities. Environ. Sci. Technol. 2001, 35, 643-647.
37. Dachs, J.; Eisenreich, S. J. Adsorption onto aerosol soot carbon dominates gas-particle partitioning of polycyclic aromatic hydrocarbons. Environ. Sci. Technol. 2000, 34, 3690-3697.
38. Goss, K. U.; Schwarzenbach, R. P. Linear free energy relationships used to evaluate equilibrium partitioning of organic compounds. Environ. Sci. Technol. 2001, 35, 1-9.
39. Gustafsson, Ö.; Gschwend, P. M. Soot as a strong partition medium for polycyclic aromatic hydrocarbons in aquatic systems. In Molecular Markers in Environmental Geochemistry; Eganhous, R. P., Ed.; American Chemical Society: Washington, DC, 1997.
40. Dubinin, M. M. The potential theory of adsorption of gases and vapors for adsorbents with energetically nonuniform surfaces. Chem. Rev. 1960, 60, 235-241.
41. Means, J. C.; Wood, S. G.; Hassett, J. J.; Banwart, W. L. Sorption of polynuclear aromatic hydrocarbons by sediments and soils. Environ. Sci. Technol. 1980, 14, 1524-1529.
42. Chiou, C. T.; Porter, P. E.; Schmedding, D. W. Partition equilibria of nonionic organic compounds between soil organic matter and water. Environ. Sci. Technol. 1983, 17, 227-231.
43. Karickhoff, S. W. Semiempirical estimation of sorption of hydrophobic pollutants on natural sediments and soils. Chemosphere 1981, 10, 833-846.
44. Manes, M. Activated carbon adsorption fundamentals. In Encyclopedia of Environmental Analysis and Remediation; Meyer, R. A., Ed.; John Wiley & Sons: New York, 1998; pp 26-68.
45. Xia, G.; Pignatello, J. J. Detailed sorption isotherms of polar and apolar compounds in a high-organic soil. Environ. Sci. Technol. 2001, 35, 84-94.
46. Condon, J. B. Equivalency of Dubinin-Polanyi equations and the QM based sorption isotherm equation. A. Mathematical derivation. Microporous Mesoporous Mater. 2000, 38, 359-376.
47. Condon, J. B. Equivalency of Dubinin-Polanyi equations and the QM based sorption isotherm equation. B. Simulations of heterogeneous surfaces. Microporous Mesoporous Mater. 2000, 38, 377-383.
48. Weber, J. J., Jr.; Kim, S. H.; Johnson, M. D. Distribution reactivity model for sorption by soils and sediments. 15. High-concentration co-contaminant effects on phenanthrene sorption and desorption. Environ. Sci. Technol. 2002, 36, 3625-3634.
49. Huang, W.; Weber, W. J., Jr. A distributed reactivity model for sorption by soils and sediments. 11: Slow concentration-dependent sorption rates. Environ. Sci. Technol. 1998, 32, 3549-3555.
50. White, J. C.; Pignatello, J. J. Influence of bisolute competition on the desorption kinetics of polycyclic aromatic hydrocarbons in soil. Environ. Sci. Technol. 1999, 33, 4292-4298.