Transition metal complexes in organic synthesis, part 72: Iron-mediated diastereoselective spiroannelation of dimethyl aminomalonate to the 2-azaspiro[4.5]decane ring system

Synlett

Volumn , Issue 10, 2004, Pages 1769-1771

  Knölker, Hans Joachim ^a   Baum, Elke ^a   Kosub, Mike ^a  

^a DRESDEN UNIVERSITY OF TECHNOLOGY   (Germany)

Author keywords

Cyclizations; Diels Alder reactions; Diene complexes; Iron; Spiro compounds

Indexed keywords

2 AZASPIRO[4.5]DECANE; DECANE; DIMETHYL AMINOMALONATE; IRON; MALONIC ACID DERIVATIVE; TRANSITION ELEMENT; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL MODIFICATION; COMPLEX FORMATION; DIELS ALDER REACTION; ORGANIC CHEMISTRY; SPIROANNELATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 4143053591     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-829545     Document Type: Article

References (22)

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18. 11: C, 50.55; H, 3.89; N, 4.91; found: C, 50.39; H, 4.18; N, 4.86.
19. 2 = 0.1807. Details of the crystal structure investigation have been deposited at the Cambridge Crystallographic Data Centre (CCDC 233245).
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22. 2 = 0.1510. Details of the crystal structure investigation have been deposited at the Cambridge Crystallographic Data Centre (CCDC 233244).