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Volumn 130, Issue 12, 2008, Pages 3762-3763

TOF-2: A large 1D channel thorium organic framework

Author keywords

[No Author keywords available]

Indexed keywords

ORGANIC COMPOUND; THORIUM;

EID: 41149158568     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja800395q     Document Type: Article
Times cited : (123)

References (33)
  • 24
    • 84885427826 scopus 로고    scopus 로고
    • Th[C6H3(CO2)3F]·0. 3H2O was synthesized by combining N(CH3)4Cl (0.219 g, 2.00 × 10-3 mol, Th(NO3) 4·6H2O (0.588 g, 1.00 × 10-3 mol, 1,3,5-C6H3(CO2H)3 (0.078 g, 3.71 × 10-4 mol, HCON(CH3)2 (0.25 mL, water (5 mL, and HF(aq, 40, 0.14 g) in a Teflon lined stainless steel autoclave and heating to 140°C for 24 h, before being cooled to room temperature at a rate of 3°C h-1. The mother liquor was decanted from the products, which were then sonicated and washed with water. Light yellow needle crystals were recovered by filtration. A yield of 78, based on thorium) was observed. IR data cm-1, 3586, 2867, 1612, 1529, 1438, 1367, 1228, 1112, 936, 761, 624, 608, 544, 519. Elemental analysis. Calcd: C, 23.30; H, 0.78
    • -1): 3586, 2867, 1612, 1529, 1438, 1367, 1228, 1112, 936, 761, 624, 608, 544, 519. Elemental analysis. Calcd: C, 23.30; H, 0.78; Th, 50.07. Exptl: C, 23.66; H, 0.68; Th, 50.02.
  • 25
    • 84885423732 scopus 로고    scopus 로고
    • 2].
    • 2].
  • 31
    • 84885422759 scopus 로고    scopus 로고
    • 13C MAS NMR gave four resonances at 172.9 ppm, 172.1 ppm, 135.0 ppm, and 133.7 ppm which are assigned to the carbon atoms on the benzene ring. The carbonyl carbons were not observed, presumably due to its slow relaxation time.
    • 13C MAS NMR gave four resonances at 172.9 ppm, 172.1 ppm, 135.0 ppm, and 133.7 ppm which are assigned to the carbon atoms on the benzene ring. The carbonyl carbons were not observed, presumably due to its slow relaxation time.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.