A Novel Approach to Evaluate the Extent and the Effect of Cross-Contribution to the Intensity of Ions Designating the Analyte and the Internal Standard in Quantitative GC-MS Analysis

Journal of the American Society for Mass Spectrometry

Volumn 19, Issue 4, 2008, Pages 598-608

  Chen, Bud Gen ^a   Chang, Chiung Dan ^b   Wang, Chia Ting ^c   Chen, Yi Jun ^d   Chang, Wei Tun ^e   Wang, Sheng Meng ^e   Liu, Ray H ^a  

^a FOOYIN UNIVERSITY   (Taiwan)

^b Chiayi Yang Ming Hospital   (Taiwan)

^c CHENG CHING GENERAL HOSPITAL   (Taiwan)

^d CHANG BING SHOW CHWAN MEMORIAL HOSPITAL   (Taiwan)

^e CENTRAL POLICE UNIVERSITY   (Taiwan)

Author keywords

[No Author keywords available]

Indexed keywords

CALIBRATION; GAS CHROMATOGRAPHY; STANDARDS;

CALIBRATION RANGE; CROSS-CONTRIBUTION (CC); QUANTITATION DATA;

MASS SPECTROMETRY;

ION;

ACCURACY; ARTICLE; CALIBRATION; CONCENTRATION (PARAMETERS); MASS FRAGMENTOGRAPHY; QUANTITATIVE ANALYSIS; STANDARD;

3,4-METHYLENEDIOXYAMPHETAMINE; CALIBRATION; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; HYDROMORPHONE; IONS; REFERENCE STANDARDS; REPRODUCIBILITY OF RESULTS;

EID: 41149111811     PISSN: 10440305     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jasms.2008.01.004     Document Type: Article

References (14)

1. U.S. Department of Health and Human Services. Mandatory Guidelines for Federal Workplace Drug Testing Programs. Fed. Reg. 53 (1988) 11970-11989
2. Holland J.F., Sweeley C.C., Thrush R.E., Teets R.E., and Bieber M.A. Anal. Chem. 45 (1973) 308-314
3. Garland W.A., and Barbalas M.P. Applications to Analytical Chemistry: An Evaluation of Stable Isotopes in Mass Spectral Drug Assays. J. Clin. Pharmacol. 26 (1986) 412-418
4. Pickup J.F., and McPherson K. Theoretical Considerations in Stable Isotope Dilution Mass Spectrometry for Organic Analysis. Anal. Chem. 48 (1976) 1885-1890
5. Thorne G.C., Gaskell S.J., and Payne P.A. Approaches to the Improvement of Quantitative Precision in Selected Ion Monitoring: High Resolution Applications. Biomed. Mass Spectrom. 11 (1984) 415-420
6. Bush E.D., and Trager W.F. Analysis of Linear Approaches to Quantitative Stable Isotope Methodology in Mass Spectrometry. Biomed. Mass Spectrom. 8 (1981) 211-218
7. Barbalas M.P., and Garland W.A. A Computer Program for the Deconvolution of Mass Spectral Peak Abundance Data from Experiments Using Stable Isotopes. J. Pharm. Sci. 80 (1991) 922-927
8. Duncan M.W., Gale P.J., and Yergey A.L. The Principles of Quantitative Mass Spectrometry (2006), Rockpool Productions, Denver, CO 97
9. Liu R.H., Foster G.F., Cone E.J., and Kuma S.D. Selecting an Appropriate Isotopic Internal Standard for Gas Chromatography/Mass Spectrometry Analysis of Drugs of Abuse-Pentobarbital Example. J. Forensic Sci. 40 (1995) 983-989
10. Chang W.-T., Lin D.-L., and Liu R.H. Isotopic Analogs as Internal Standards for Quantitative Analyses by GC/MS-Evaluation of Cross-Contribution to Ions Designated for the Analyte and the Isotopic Internal Standard. Forensic Sci. Int. 121 (2001) 174-182
11. Liu R.H., Lin T.-L., Chang W.-T., Liu C., Tsay W.-I., Li J.-H., and Kuo T.-L. Isotopically Labeled Analogues for Drug Quantitation. Anal. Chem. 74 (2002) 618A-626A
12. Whiting T.C., Liu R.H., Chang W.-T., and Bodapati M.R. Isotopic Analogs as Internal Standards for Quantitative Analyses of Drugs/Metabolites by GC/MS-Nonlinear Calibration Approaches. J. Anal. Toxicol. 25 (2001) 179-189
13. Wang S.-M., Chye S.-M., Liu R.H., Lewis R.J., Canfield D.V., and Roberts J. Mass Spectrometric Data of Commonly Abused Amphetamines and Their Derivatives-Cross Contributions of Ion Intensity Between the Analytes and Their Isotopically Labeled Analogs. Forensic Sci. Rev. 17 (2005) 67-166
14. Liu R.H., Baugh L.D., Allen E.E., Salud S.C., Fentress J.C., Chadha H., and Walia A.S. Isotopic Analogue as the Internal Standard for Quantitative Determination of Benzoylecgonine: Concerns with Isotopic Purity and Concentration Level. J. Forensic Sci. 34 (1989) 986-990