Hexafluoro complex of rutherfordium in mixed HF/HNO3 solutions

Radiochimica Acta

Volumn 96, Issue 3, 2008, Pages 125-134

  Toyoshima, A ^a,b   Haba, H ^c   Tsukada, K ^a   Asai, M ^a   Akiyama, K ^d   Goto, S ^e   Ishii, Y ^a   Nishinaka, I ^a   Sato, T K ^a   Nagame, Y ^a   Sato, W ^b   Tani, Y ^b   Hasegawa, H ^b   Matsuo, K ^b   Saika, D ^b   Kitamoto, Y ^b   Shinohara, A ^b   Ito, M ^e   Saito, J ^e   Kudo, H ^e   Yokoyama, A ^f   Sakama, M ^g   Sueki, K ^h   Oura, Y ^d   Nakahara, H ^d   Schadel M ⁱ   Bruchle W ⁱ   Kratz, J V ^j   more..

^a JAPAN ATOMIC ENERGY AGENCY   (Japan)

^b OSAKA UNIVERSITY   (Japan)

^c RIKEN Nishina Center for Accelerated Based Science   (Japan)

^d TOKYO METROPOLITAN UNIVERSITY   (Japan)

^e NIIGATA UNIVERSITY   (Japan)

^f KANAZAWA UNIVERSITY   (Japan)

^g UNIVERSITY OF TOKUSHIMA   (Japan)

^h UNIVERSITY OF TSUKUBA   (Japan)

ⁱ GSI HELMHOLTZZENTRUM FÜR SCHWERIONENFORSCHUNG GMBH   (Germany)

^j JOHANNES GUTENBERG UNIVERSITY   (Germany)

more..

Author keywords

Anion exchange chromatography; Atom at a time chemistry; Hafnium (Hf); Hexafluoro complex; Rutherfordium (Rf); Zirconium (Zr)

Indexed keywords

EID: 41149087705     PISSN: 00338230     EISSN: None     Source Type: Journal    
DOI: 10.1524/ract.2008.1474     Document Type: Article

References (44)

1. Hofmann, S., Münzenberg, G.: The discovery of the heaviest elements. Rev. Mod. Phys. 72, 733 (2000).
2. 48Ca fusion reactions. Phys. Rev. C 74, 044 602 (2006).
3. Greiner, W., Gupta, R. K. (eds.): Heavy Elements and Related New Phenomena. World Scientific, Singapore (1999).
4. Schädel, M. (ed.): The Chemistry of Superheavy Elements. Kluwer Academic Publishers, Dordrecht (2003).
5. Schädel, M.: Chemistry of Superheavy Elements. Angew. Chem. Int. Edit. 45, 368 (2006).
6. Silva, R., Harris, J., Nurmia, M., Eskola, K., Ghiorso, A.: Chemical separation of rutherfordium. Inorg. Nucl. Chem. Lett. 6, 871 (1970).
7. Zvára, I., Belov, V. Z., Chelnokov, L. P., Domanov, V. P., Hussonois, M., Korotkin, Yu. S., Schegolev, V. A., Shalayevsky, M. R.: Chemical separation of kurchatovium. Inorg. Nucl. Chem. Lett. 7, 1109 (1971).
8. Zvara, I., Belov, V. Z., Domanov, V. P., Shalaevskii, M. R.: Chemical isolation of nilsbohrium as ekatantalum in the form of the anhydrous bromide II. Experiments with a spontaneously fissioning isotope of nilsbohrium. Sov. Radiochem. 18, 328 (1976).
9. Gregorich, K. E., Henderson, R. A., Lee, D. M., Nurmia, M. J., Chasteler, R. M., Hall, H. L., Bennett, D. A., Gannett, C. M., Chadwick, R. B., Leyba, J. D., Hoffman, D. C., Herrmann, G.: Aqueous chemistry of element 105. Radiochim. Acta 43, 223 (1988).
10. Schädel, M., Brüchle, W., Dressler, R., Eichler, B., Gäggeler, H. W., Günther, R., Gregorich, K. E., Hoffman, D. C., Hübener, S., Jost, D. T., Kratz, J. V., Paulus, W., Schumann, D., Timokhin, S., Trautmann, N., Türler, A., Wirth, G., Yakuschev, A.: Chemical properties of element 106 (seaborgium). Nature 388, 55 (1997).
11. Eichler, R., Brüchle, W., Dressler, R., Düllmann, Ch. E., Eichler, B., Gäggeler, H. W., Gregorich, K. E., Hoffman, D. C., Hübener, S., Jost, D. T., Kirbach, U. W., Laue, C. A., Lavanchy, V. M., Nitsche, H., Patin, J. B., Piguet, D., Schädel, M., Shaughnessy, D. A., Strellis, D. A., Taut, S., Tobler, L., Tsyganov, Y. S., Türler, A., Vahle, A., Wilk, P. A., Yakushev, A. B.: Chemical characterization of bohrium (element 107). Nature 407, 63 (2000).
12. Düllmann, Ch. E., Brüchle, W., Dressler, R., Eberhardt, K., Eichler, B., Eichler, R., Gäggeler, H. W., Ginter, T. N., Glaus, F., Gregorich, K. E., Hoffman, D. C., Jäger, E., Jost, D. T., Kirbach, U. W., Lee, D. M., Nitsche, H., Patin, J. B., Pershina, V., Piguet, D., Qin, Z., Schädel, M., Schausten, B., Schimpf, E., Schött, H.-J., Soverna, S., Sudowe, R., Thörle, P., Timokhin, S. N., Trautmann, N., Türler, A., Vahle, A., Wirth, G., Yakushev, A. B., Zielinski, P. M.: Chemical investigation of hassium (element 108). Nature 418, 859 (2002).
13. Fricke, B., Greiner, W.: On the chemistry of superheavy elements around Z = 164. Phys. Lett. B 30, 317 (1969).
14. Fricke, B., Waber, J. T.: Theoretical predictions of the chemistry of superheavy elements. Continuation of the periodic table up to Z = 184. Actinides Rev. 1, 433 (1971).
15. Johnson, E., Fricke, B.: Prediction of some thermodynamic properties of selected compounds of element 104. J. Phys. Chem. 95, 7082 (1991).
16. Pershina, V. G.: Electronic structure and properties of the transactinides and their compounds. Chem. Rev. 96, 1977 (1996).
17. Schwerdtfeger, P., Seth, M.: Relativistic Effects of the Superheavy Elements. In: Encyclopedia of Computational Chemistry. (Schleyer, P. R., Schreiner, P. R., Allinger, N. L., Clark, T., Gasteiger, J., Kollman, P., Schaefer III, H. F., eds.), John Wiley and Sons, Chichester, (1998), p. 2480.
18. Guillaumont, R., Adloff, J. P., Peneloux, A.: Kinetic and thermodynamic aspects of tracer-scale and single atom chemistry. Radiochim. Acta 46, 169 (1989).
19. Guillaumont, R., Adloff, J. P., Peneloux, A., Delamoye, P.: Subtracer scale behaviour of radionuclides, application to actinide chemistry. Radiochim. Acta 54, 1 (1991).
20. 3 solutions. J. Nucl. Radiochem. Sci. 3, 143 (2002).
21. Kacher, C. D., Gregorich, K. E., Lee, D. M., Watanabe, Y., Kadkhodayan, B., Wierczinski, B., Lane, M. R., Sylwester, E. R., Keeney, D. A., Hendricks, M., Hoffman, D. C., Bilewicz, A.: Chemical studies of rutherfordium (element 104): Part III. Solvent extraction into triisooctylamine from HF solutions. Radiochim. Acta 75, 135 (1996).
22. Schumann, D., Nitsche, H., Taut, St., Jost, D. T., Gäggeler, H. W., Yakushev, A. B., Buklanov, G. V., Domanov, V. P., Lien, D. T., Kubica, B., Misiak, R., Szeglowski, Z.: Sorption behaviour of rutherfordium and thorium from HCl/Hf containing aqueous solution. J. Alloys Compd. 271-273, 307 (1998).
23. Strub, E, Kratz, J. V., Kronenberg, A., Nähler, A., Thörle, P., Zauner, S., Brüchle, W., Jäger, E., Schädel, M., Schausten, B., Schimpf, E., Zongwei, Li, Kirbach, U., Schumann, D., Jost, D., Türler, A., Asai, M., Nagame, Y., Sakama, M., Tsukada, K., Gäggeler, H. W., Glatz, J. P.: Fluoride complexation of rutherfordium (Rf, element 104). Radiochim. Acta 88, 265 (2000).
24. Haba, H., Tsukada, K., Asai, M., Toyoshima, A., Akiyama, K., Nishinaka, I., Hirata, M., Yaita, T., Ichikawa, S., Nagame, Y., Yasuda, K., Miyamoto, Y., Kaneko, T., Goto, S., Ono, S., Hirai, T., Kudo, H., Shigekawa, M., Shinohara, A., Oura, Y., Nakahara, H., Sueki, K., Kikunaga, H., Kinoshita, N., Tsuruga, N., Yokoyama, A., Sakama, M., Enomoto, S., Schädel, M., Brüchle, W., Kratz, J. V.: Fluoride complexation of element 104, rutherfordium. J. Am. Chem. Soc. 126, 5219 (2004).
25. 3. Radiochim. Acta 92, 379 (2004).
26. Kadkhodayan, B., Türler, A., Gregorich, K. E., Baisden, P. A., Czerwinski, K. R., Eichler, B., Gäggeler, H. W., Hamilton, T. M., Jost, D. T., Kacher, C. D., Kovacs, A., Kreek, S. A., Lane, M. R., Mohar, M. F., Neu, M. P., Stoyer, N. J., Sylwester, E. R., Lee, D. M., Nurmia, M. J., Seaborg, G. T., Hoffman, D. C.: On-line gas chromatographic studies of chlorides on rutherfordium and homologs Zr and Hf. Radiochim. Acta 72, 169 (1996).
27. Firestone, R. B., Shirley, V. S.: Table of Isotopes. John Wiley and Sons, Inc., New York (1996), 8th edn.
28. 19F ions. J. Nucl. Radiochem. Sci. 3, 85 (2002).
29. Nagame, Y., Tsukada, K., Asai, M., Toyoshima, A., Akiyama, K., Ishii, Y., Kaneko-Sato, T., Hirata, M., Nishinaka, I., Ichikawa, S., Haba, H., Enomoto, S., Matsuo, K., Saika, D., Kitamoto, Y., Hasegawa, H., Tani, Y., Sato, W., Shinohara, A., Ito, M., Saito, J., Goto, S., Kudo, H., Kikunaga, H., Yokoyama, A., Sueki, K., Oura, Y., Nakahara, H., Sakama, M., Schädel, M., Brüchle, W., Kratz, J. V.: Chemical studies on rutherfordium (Rf) at JAERI. Radiochim. Acta 93, 519 (2005).
30. Schädel, M., Brüchle, W., Jäger, E., Schimpf, E., Kratz, J. V., Scherer, U. W., Zimmermann, H. P.: ARCA II - a new apparatus for fast, repetitive HPLC separations. Radiochim. Acta 48, 171 (1989).
31. Plaisance, M., Guillaumont, R.: Fluoro- et chlorofluoro-complexes de protactinium pentavalent. Radiochim. Acta 12, 32 (1969).
32. Glückauf, E.: Theory of chromatography. Part 9. The "theoretical plate" concept in column separations. Trans. Faraday Soc. 51, 34 (1955).
33. 253Fm. Phys. Rev. Lett. 95, 102 502 (2005).
34. Toyoshima, A., Tsukada, K, Haba, H., Asai, M., Goto, S., Akiyama, K., Nishinaka, I., Ichikawa, S., Nagame, Y., Shinohara, A.: Anion exchange behavior of nobelium. J. Radioanal. Nucl. Chem. 255, 485 (2003).
35. Toyoshima, A., Haba, H., Tsukada, K., Asai, M., Akiyama, K., Nishinaka, I., Nagame, Y., Saika, D., Matsuo, K., Sato, W., Shinohara, A., Ishizu, H., Ito, M., Saito, J., Goto, S., Kudo, H., Kikunaga, H., Kinoshita, N., Kato, C., Yokoyama, A., Sueki, K.: Elution curve of rutherfordium (Rf) in anion-exchange chromatography with hydrofluoric acid solution. J. Nucl. Raciochem. Sci. 5, 45 (2004).
36. Brüchle, W.: Confidence intervals for experiments with background and small numbers of events. Radiochim. Acta 91, 71 (2003).
37. Marinsky, J. A. (ed.): Ion Exchange. A Series of Advances. Vol. 1, Marcel Dekker, New York, (1966).
38. Bond, A. M., Hefter, G. T.: Critical Survey of Stability Constants and Related Thermodynamic Data of Fluoride Complexes in Aqueous Solution. Pergamon Press, Oxford (1980).
39. Norén, B.: The fluoride complexes of zirconium(iv). A potentiometric investigation. Acta Chem. Scand. 21, 2457 (1967).
40. Norén, B.: The fluoride complexes of hafnium(IV). I. A solvent extraction and potentiometric investigation. Acta Chem. Scand. 21, 2435 (1967).
41. Ahrland, S., Karipides, D., Norén, B.: The fluoride and sulphate complexes of zirconium(IV). Acta Chem. Scand. 17, 411 (1963).
42. Ahrland, S., Brandt, L.: The fluoride complexes of hafnium(IV). II. Determination of the stability constants by the cation exchange method. Acta Chem. Scand. 20, 328 (1966).
43. Pershina, V., Trubert, D., Naour, C. Le., Kratz, J. V.: Theoretical predictions of hydrolysis and complex formation of group-4 elements Zr, Hf and Rf in HF and HCl solutions. Radiochim. Acta 90, 869 (2002).
44. Wheaton, R. M., Bauman, W. C.: Properties of strongly basic anion exchange resins. Ind. Eng. Chem. 43, 1088 (1951).