A Gas-Phase Study of the Preferential Solvation of Mn2+ in Mixed Water/Methanol Clusters

Journal of the American Society for Mass Spectrometry

Volumn 19, Issue 4, 2008, Pages 520-530

  Duncombe, Bridgette J ^a   Rydén, Jens O S ^b   Puškar, Ljilijana ^b   Cox, Hazel ^b   Stace, Anthony J ^a  

^a UNIVERSITY OF NOTTINGHAM   (United Kingdom)

^b UNIVERSITY OF SUSSEX   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

METHANOL; MOLECULAR ORBITALS; POSITIVE IONS; SOLVATION; WATER;

METAL DICATION; METHANOL CLUSTERS; UNIMOLECULAR FRAGMENTATION;

MANGANESE;

MANGANESE; METHANOL; WATER;

ARTICLE; CALCULATION; FRAGMENTATION REACTION; GAS; KINETICS; SOLVATION;

EID: 41049083875     PISSN: 10440305     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jasms.2007.12.004     Document Type: Article

References (29)

1. Kebarle P. Ion Thermochemistry and Solvation from Gas-Phase Ion Equilibria. Annu. Rev. Phys. Chem 28 (1977) 445-476
2. Keesee R.G., and Castleman Jr. A.W. Thermochemical Data on Gas-Phase Ion-Molecule Association and Clustering Reactions. J. Phys. Chem. Ref. Data 15 (1986) 1011-1071
3. Stace A.J. Metal Ion Solvation in the Gas Phase: The Quest for Higher Oxidation States. J. Phys. Chem. A 106 (2002) 7993-8005
4. 2+. Int. J. Mass Spectrom. Ion Processes 102 (1990) 251-267
5. 2+ Gas-Phase Ion Chemistry. J. Chem. Phys 92 (1990) 5900-5906
6. 2+ Clusters: The First Evidence of Aqueous Cu(II) in the Gas Phase. J. Am. Chem. Soc 119 (1997) 10239-10240
7. n (n = 6-8), Obtained by Blackbody Infrared Radiative Dissociation. J. Am. Chem. Soc 120 (1998) 5842-5843
8. n, n = 5-7, M = Mg, Ca, Sr, and Ba. J. Am. Chem. Soc 121 (1999) 8898-8906
9. Wright R.R., Walker N.R., Firth S., and Stace A.J. The Coordination and Chemistry of Stable Cu(II) Complexes in the Gas Phase. J. Phys. Chem. A 105 (2001) 54-64
10. Nielsen S.B., Masella M., and Kebarle P. Competitive Gas-Phase Solvation of Alkali Metal Ions by Water and Methanol. J. Phys. Chem. A 103 (1999) 9891-9898
11. Vaden T.D., and Lisy J.M. Investigation of Competing Interactions in Alkali Metal Ion-Acetone-Water Clusters. Chem. Phys. Lett 408 (2005) 54-58
12. Vaden T.D., and Lisy J.M. Competing Noncovalent Interactions in Alkali Metal Ion-Acetonitrile-Water Clusters. J. Phys. Chem. A 109 (2005) 3880-3886
13. Marcus Y. Introduction to Liquid State Chemistry (1977), Wiley, London 164
14. Day T.J.F., and Patey G.N. Ion Solvation Dynamics in Binary Mixtures. J. Chem. Phys 106 (1997) 2782-2791
15. Day T.J.F., and Patey G.N. Ion Solvation Dynamics in Water-Methanol and Water Dimethylsulfoxide Mixtures. J. Chem. Phys 110 (1999) 10937-10944
16. 2+ Solvation in Aqueous Ammonia Solution by Means of Monte Carlo Method Including Three-Body Correction Terms. J. Chem. Phys 112 (2000) 4212-4215
17. 2 in 18.6% Aqueous Ammonia Solution. Chem. Phys 291 (2003) 153-159
18. Pavelka M., and Burda J.V. Theoretical Description of Copper Cu(I)/Cu(II) Complexes in Mixed Ammine-Aqua Environment. DFT and ab Initio Quantum Chemical Study. Chem. Phys 312 (2005) 193-204
19. Stace A.J., and Shukla A.K. Preferential Solvation of Hydrogen Ions in Mixed Clusters of Water with Methanol and Ethanol. J. Am. Chem. Soc 104 (1982) 5314-5318
20. Stace A.J., and Moore C. Solvation of Hydrogen Ions in Mixed Clusters of Water and Alcohol. J. Am. Chem. Soc 105 (1983) 1814-1819
21. Stace A.J. Preferential Solvation of Hydrogen Ions in Mixed Water-Amine Ion Clusters. J. Am. Chem. Soc 106 (1984) 2306-2314
22. Walker N.R., Wright R., and Stace A.J. Stable Gas Phase Complexes of Silver(II). J. Am. Chem. Soc 121 (1999) 4837-4844
23. Cooks R.G., Beynon J.H., Caprioli R.M., and Lester G.R. Metastable Ions (1973), Elsevier, Amsterdam 42
24. 2+ Complexes: Electron Capture Versus Charge Separation. J. Phys. Chem. A 110 (2006) 8423-8432
25. Frisch M.J., Trucks G.W., Schlegel H.B., Scuseria G.E., Robb M.A., Cheeseman J.R., Zakrzewski V.G., Montgomery J.A., Stratmann R.E., Burant J.C., Dapprich S., Millam J.M., Daniels A.D., Kudin K.N., Strain M.C., Farkas O., Tomasi J., Barone V., Cossi M., Cammi R., Mennucci B., Pomelli C., Adamo C., Clifford S., Ochterski J., Petersson G.A., Ayala P.Y., Cui Q., Morokuma K., Malick D.K., Rabuck A.D., Raghavachari K., Foresman J.B., Cioslowski J., Ortiz J.V., Stefanov B.B., Liu G., Liashenko A., Piskorz P., Komaromi I., Gomperts R., Martin R.L., Fox D.J., Keith T., Al-Laham M.A., Peng C.Y., Nanayakkara A., Gonzalez C., Challacombe M., Gill P.M.W., Johnson B.G., Chen W., Wong M.W., Andres J.L., Head-Gordon M., Replogle E.S., and Pople J.A. Gaussian 03 (1998), Gaussian, Inc, Pittsburgh. PA
26. 2+ complexes: Theory and Experiment. J. Am. Chem. Soc 125 (2003) 233-242
27. Rotzinger F.P. Performance of Molecular Orbital Methods and Density Functional Theory in the Computation of Geometries and Energies of Metal Aqua Ions. J. Phys. Chem. B 109 (2005) 1510-1527
28. Wu B. Gas-Phase Studies of Multiply Charged Metal-Ligand Complexes, Ph.D. Thesis (2007), The University of Nottingham
29. Ishii K., Itoh A., and Okuno K. Electron-Capture Cross-Sections of Multiply Charged Slow Ions of Carbon, Nitrogen, and Oxygen in He. Phys. Rev. A 70 (2004) 042716