Low-temperature heat capacity of synthetic Fe- and Mg-cordierite: Thermodynamic properties and phase relations in the system FeO-Al2O3-SiO2-(H2O)

European Journal of Mineralogy

Volumn 20, Issue 1, 2008, Pages 47-62

  Dachs, Edgar ^a   Geiger, Charles A ^b  

^a UNIVERSITY OF SALZBURG   (Austria)

^b UNIVERSITY OF KIEL   (Germany)

Author keywords

Fe cordierite; Low temperature heat capacity; Mg cordierite; Standard entropy; Thermodynamic properties

Indexed keywords

ALUMINA; ALUMINUM OXIDE; BINARY ALLOYS; CALORIMETERS; CALORIMETRY; ENTROPY; IRON OXIDES; MAGNESIUM ALLOYS; SILICA; SILICON; SPECIFIC HEAT; TEMPERATURE; THERMODYNAMIC PROPERTIES;

ADIABATIC CALORIMETRY; ELECTRONIC CONTRIBUTIONS; EXPERIMENTAL PHASE EQUILIBRIA; HEAT PULSE CALORIMETRY; INCREASING TEMPERATURES; LOW TEMPERATURE HEAT CAPACITIES; STANDARD ENTROPY; THERMODYNAMIC CALCULATIONS;

SILICATE MINERALS;

CALORIMETRY; CORDIERITE; ENTHALPY; ENTROPY; HEAT CAPACITY; IRON; LATTICE DYNAMICS; LOW TEMPERATURE; MAGNESIUM; THERMODYNAMIC PROPERTY;

EID: 40949144888     PISSN: 09351221     EISSN: None     Source Type: Journal    
DOI: 10.1127/0935-1221/2008/0020-1785     Document Type: Article

References (47)

1. Aines, R.D. & Rossman, G.R. (1984): The high temperature behavior of water and carbon dioxide in cordierite and beryl. Am. Mineral., 69, 319-327.
2. Aranovich, L.Ya. & Podlesskii, K.K. (1983): The cordierite-garnet-sillimanite-quartz equilibrium: experiments and applications. in "Kinetics and equilibrium in mineral reactions", S.K. Saxena, ed., Springer-Verlag, New York, 173-198.
3. 2O on the structure of low-cordierite, a single crystal X-ray study. Proc. 13th IMA General Meeting, Varna, Bulgaria, 485-503.
4. 2. J. Petrol., 29, 445-522.
5. 2. Contrib. Mineral. Petrol., 126, 1-24.
6. 2: representation, estimation, and high temperature extrapolation. Contrib. Mineral. Petrol., 89, 168-183.
7. 2. J. Petrol., 27, 1143-1156.
8. Carey, J.W. (1993): The heat capacity of hydrous cordierite above 295 K. Phys. Chem. Minerals, 19, 578-583.
9. Carey, J.W. (1995): A thermodynamic formulation of hydrous cordierite. Contrib. Mineral. Petrol., 119, 155-165.
10. Chatterjee, N.D., Krüger, R., Haller, G., Olbricht, W. (1998): The Bayesian approach to an internally consistent thermodynamic database: theory, database, and generation of phase diagrams. Contrib. Mineral. Petrol., 133, 149-168.
11. Dachs, E, & Bertoldi, C. (2005): Precision and accuracy of the heat-pulse calorimetric technique: low-temperature heat capacities of milligram-sized synthetic mineral samples. Eur J. Mineral., 17, 251-261.
12. 12) garnet solid solutions: A low temperature calorimetric and a thermodynamic investigation. Am. Mineral., 91, 894-906.
13. 4)} solid solutions: An analysis of vibrational, magnetic and electronic contributions to the heat capacity and entropy of mixing. J. Chem. Thermodynamics, 39, 906-933.
14. Geiger, C.A. & Grams, M. (2003): Cordierite IV: Structural heterogeneity and energetics of natural Mg-Fe solid solutions. Contrib. Mineral. Petrol., 145, 752-764.
15. Geiger, C.A. & Kolesov, B.A. (2002): Microscopic-macroscopic relationships in silicates: Examples from IR and Raman spectroscopy and heat capacity measurements. in "Energy Modelling in Minerals", C.-M. Gramaccioli, ed., European Notes in Mineralogy vol. 4, Eötvös University Press, Budapest, 347-387.
16. Geiger, C.A. & Voigtländer, H. (2000): Heat capacity measurements on synthetic Mg- and Fe-cordierite. Contrib. Mineral. Petrol., 138, 46-50.
17. 2+. Am. Mineral., 85, 1255-1264.
18. Gibbs, G.V. (1966): The polymorphism in cordierite I: The crystal structure of low cordierite. Am. Mineral., 51, 1068-1087.
19. Goldman, D.S., Rossman, G.R., Dollase, W.A. (1977): Channel constituents in cordierite. Am. Mineral., 62, 1144-1157.
20. Gopal, E.S.R. (1966): Specific heats at low temperatures. Plenum Press, New York.
21. 2. Eur. J. Mineral., 9, 175-223.
22. Haar, L., Gallagher, J.S., Kell, G.S. (1984): NBS/NRC steam tables. Thermodynamic and transport properties and computer programs for vapor and liquid states of water in SI units. Hemisphere Publishing McGraw-Hill, New York.
23. Holdaway, M.J. & Lee, S.M. (1977): Fe-Mg cordierite stability in high-grade pelitic rocks based on experimental, theoretical, and natural observations. Contrib. Mineral. Petrol., 63, 175-198.
24. Holland, T.J.B. & Powell, R. (1998): An internally consistent thermodynamic data set for phases of petrological interest. J. Metamorphic Geol., 16, 309-343.
25. 2O. Am. Mineral., 85, 1265-1274.
26. Komada, N. & Westrum, E.F. (1997): Modeling lattice heat capacity contributions by a single-parametric phonon dispersion approach. J. Chem. Thermodynamics, 29, 311-336.
27. Lashley, J.C., Hundley, M.F., Migliori, A., Sarrao, J.L., Pagliuso, P.G., Darling, T.W., Jaime, M., Cooley, J.C., Hults, W.L., Morales, L., Thoma, D.J., Smith, J.L., Boerio-Goates, J., Woodfield, B.F., Stewart, G.R., Fisher, R.A., Phillips, N.E. (2003): Critical examination of heat capacity measurements made on a Quantum Design physical property measurement system. Cryogenics, 43, 369-378.
28. Malcherek, T., Domeneghetti, M.C., Tazzoli, V., Ottolini, L., McCammon, C., Carpenter, M.A. (2001): Structural properties of ferromagnesian cordierites. Am. Mineral., 86, 66-79.
29. 2O equilibrium: A geological thermometer, barometer and water fugacity indicator. Contrib. Mineral. Petrol., 77, 38-46.
30. H2o relations. Contrib. Mineral. Petrol., 116, 462-472.
31. Newton, R.C. (1972): An experimental determination of the high-pressure stability limits of magnesian cordierite under wet and dry conditions. J. Petrol., 80, 398-402.
32. Newton, R.C. & Wood, B.J. (1979): Thermodynamics of water in cordierite and some petrologic consequences of cordierite as a hydrous phase. Contrib. Mineral. Petrol., 68, 391-405.
33. Pankratz, L.B. & Kelley, K.K. (1963): High-temperature heat contents and entropies of akermanite, cordierite, gehlenite, and merwinite. U.S. Bureau of Mines, Report of Investigations, 6555, 1-7.
34. 18). Am. Mineral., 91, 35-38.
35. 2O molecule in selected hydrous micro and nanoporous silicates. Am. Mineral., 92, 388-396.
36. Pryce, M.W. (1973): Low-iron cordierite in phlogopite schist from White Well, Western Australia. Mineral. Mag., 39, 241-243.
37. Richardson, S.W. (1968): Staurolite stability in a part of the system Fe-Al-Si-O-H. J. Petrol., 9, 467-488.
38. 5 Pascals) pressure and at higher temperatures. Geological Survey Bulletin 2131, 461 p.
39. 2. Am. J. Sci., Bowen volume, 471-512.
40. 2. J. Petrol., 2, 324-406.
41. Shao, H., Liang, K.M., Zhou, F., Wang, G.L., Peng, F. (2004): Characterization of cordierite-based glass-ceramics produced from fly ash. J. Non-Cryst. Solids, 337 (2), 157-160.
42. 2O in magnesium and iron cordierite. Contrib. Mineral. Petrol., 124, 82-89.
43. Stanek, J. & Miskovsky, J. (1964): Iron-rich cordierite from the Dolni Bory pegmatite. Cas. Mineral. Geol., 9, 191-192 (in Czech).
44. Ulbrich, H.H. & Waldbaum, D.R. (1976): Structural and other contributions to the third-law entropies of silicates. Geochim. Cosmochim. Acta., 40, 1-24.
45. van Hinsberg, V.J., Vriend, S.P., Schumacher, J.C. (2005): A new method to calculate end-member thermodynamic properties of minerals from their constituent polyhedra II: heat capacity, compressibility and thermal expansion. J. Metamorphic Geol., 23, 681-693.
46. Weller, W.W. & Kelley, K.K. (1963): Low-temperature heat capacities and entropies at 298.15 °K of akermanite, cordierite, gehlenite, and merwinite. U.S. Bureau of Mines, Report of Investigations, 6343, 1-8.
47. 2O in bassanite, gypsum and cordierite investigated by high resolution incoherent inelastic neutron scattering. Phys. Chem. Minerals, 21, 539-545.