Synthesis, characterization, and catalytic activity of a well-defined rhodium siloxide complex immobilized on silica

Angewandte Chemie - International Edition

Volumn 47, Issue 3, 2008, Pages 541-544

  Marciniec, Bogdan ^a   Szubert, Karol ^a   Potrzebowski, Marek J ^b   Kownacki, Ireneusz ^a   Łȩszczak, Kinga ^a  

^a ADAM MICKIEWICZ UNIVERSITY   (Poland)

^b CENTRE OF MOLECULAR AND MACROMOLECULAR STUDIES   (Poland)

Author keywords

Heterogeneous catalysis; Hydrosilylation; Rhodium; Supported catalysts

Indexed keywords

HYDROSILYLATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RHODIUM COMPOUNDS; SOLID STATE REACTIONS; SYNTHESIS (CHEMICAL);

RHODIUM SILOXIDE; SUPPORTED CATALYSTS;

CATALYST ACTIVITY;

EID: 40949130417     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200704362     Document Type: Article

References (33)

1. a) B. Marciniec, H. Maciejewski, Coord. Chem. Rev. 2001, 223, 301;
2. b) "Late Transition Metal (Co, Rh, Ir)-siloxide Complexes - Synthesis, Structure and Application to Catalysis": B. Marciniec, I. Kownacki, M. Kubicki, P. Krzyżanowski, E. Walczuk, P. Błaż ejewska-Chadyniak in Perspectives in Organometallic Chemistry (Eds.: C. G. Screttas, B. R. Steele), Royal Society of Chemistry, Cambridge, 2003, p. 253.
3. Tailored Metal Catalysts (Ed.: Y. Iwasawa), Reidel, Boston, 1986.
4. F. J. Feher, J. Am. Chem. Soc. 1986, 108, 3850.
5. F. J. Feher, R. L. Blanski, J. Am. Chem. Soc. 1992, 114, 5886.
6. F. J. Feher, T. L. Tajima, J. Am. Chem. Soc. 1994, 116, 2145.
7. A. Choplin, B. Coutant, C. Dubuisson, P. Leyrit, C. McGill, F. Quignard, R. Teissier in Stud. Surf. Sci. Catal. Heterogeneous Catalysis and Fine Chemicals IV (Eds.: H. U. Blaser, A. Baiker, R. Prins), Elsevier, Amsterdam, 1997, p. 353.
8. L. D. Ornelos, A. Choplin, J. M. Basset, L. Y. Hsu, S. Shore, Nouv. J. Chim. 1985, 9, 155.
9. M. Chabanas, A. Baudouin, C. Coperet, J. M. Basset, J. Am. Chem. Soc. 2001, 123, 2062.
10. a) F. Blanc, C. Coperet, J. Thivolle-Cazat, J. M. Basset, A. Lesage, L. Emsley, A. Sinha, R. R. Schrock, Angew. Chem. 2006, 118, 1238;
11. Angew. Chem. Int. Ed. 2006, 45, 1216;
12. b) F. Blanc, J. Thivolle-Cazat, J. M. Basset, C. Coperet, A. S. Hock, Z. J. Tonzetich, R. R. Schrock, J. Am. Chem. Soc. 2007, 129, 1044.
13. a) B. Marciniec, Silicon Chem. 2002, 1, 155;
14. b) "Hydrosilylation and Related Reactions of Silicon Compounds": B. Marciniec in Applied Homogeneous Catalysis with Organometallic Compounds, Vol. 1, 2nd ed. (Eds.: B. Cornils, W. A. Herrmann), Wiley-VCH, Weinheim, 2002, p. 491.
15. a) B. Marciniec, E. Walczuk-Guściora, P. Błażejewska- Chadyniak, J. Mol. Catal. A 2000, 160, 165;
16. b) B. Marciniec, E. Walczuk-Guściora, C. Pietraszuk, Organometallics 2001, 20, 3423.
17. E. Mieczyńska, A. M. Trzeciak, J. J. Ziółkowski, I. Kownacki, B. Marciniec, J. Mol. Catal. A 2005, 237, 246.
18. a) C. Nozaki, C. G. Lugmair, A. T. Bell, T. D. Tilley, J. Am. Chem. Soc. 2002, 124, 13194;
19. b) A. W. Holland, G. Li, A. M. Shahin, G. J. Long, A. T. Bell, T. D. Tilley, J. Catal. 2005, 235, 150.
20. a) R. L. Brutchey, I. J. Drake, A. T. Bell, T. D. Tilley, Chem. Commun. 2005, 3736;
21. b) K. L. Fujdala, I. J. Drake, A. T. Bell, T. D. Tilley, J. Am. Chem. Soc. 2004, 126, 10864.
22. a) S. L. Scott, P. Dufour, C. C. Santini, J. M. Basset, Inorg. Chem. 1996, 35, 869;
23. b) S. L. Scott, M. Szpakowicz, A. Mills, C. C. Santini, J. Am. Chem. Soc. 1998, 120, 1883;
24. c) S. L. Scott, A. Mills, C. Chao, J. M. Basset, N. Millot, C. C. Santini, J. Mol. Catal. A 2003, 204-205, 457.
25. a) M. D. Ward, J. Schwartz, J. Am. Chem. Soc. 1981, 103, 5253;
26. b) N. Kitajima, J. Schwartz, J. Am. Chem. Soc. 1984, 106, 2220.
27. B. Marciniec, P. Krzyżanowski, J. Organomet. Chem. 1995, 493, 261.
28. C. Okkerse in Physical and Chemical Aspects of Adsorbents and Catalysts (Ed.: B. G. Linsen), Academic Press, London, 1970, p. 258.
29. B. Marciniec, P. Krzyżanowski, E. Walczuk-Guściora, W. Duczmal, J. Mol. Catal. A 1999, 144, 263.
30. Polish Patent Application P-368485, 2004.
31. B. Marciniec, E. Walczuk, P. Błażejewska-Chadyniak, D. Chadyniak, M. Kujawa-Welten, S. Krompiec in Organosilicon Chemistry V - from Molecules to Materials, Wiley-VCH, Weinheim, 2003.
32. A. Lesage, L. Duma, D. Sakellariou, L. Emsley, J. Am. Chem. Soc. 2001, 123, 5747.
33. F. Blanc, C. Coperet, J. Thivolle-Cazat, J. M. Basset, A. Lesage, L. Emsley, A. Sinha, R. R. Schrock, Inorg. Chem. 2006, 45, 9587.