Palladium-catalyzed dehydrogenative cis double phosphorylation of alkynes with H-phosphonate leading to (Z)-bisphosphoryl-1-alkenes

Journal of the American Chemical Society

Volumn 130, Issue 9, 2008, Pages 2752-2753

  Han, Li Biao ^a   Ono, Yutaka ^a   Shimada, Shigeru ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; ALKYNE DERIVATIVE; PALLADIUM; PHOSPHONIC ACID DERIVATIVE;

ARTICLE; CATALYSIS; CATALYST; COMPLEX FORMATION; DEHYDROGENATION; PHOSPHORYLATION; REACTION ANALYSIS;

ALKENES; ALKYNES; CATALYSIS; HYDROGENATION; MOLECULAR STRUCTURE; ORGANOPHOSPHORUS COMPOUNDS; PALLADIUM; PHOSPHONIC ACIDS; PHOSPHORYLATION; STEREOISOMERISM;

EID: 40949100432     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja7108272     Document Type: Article

References (20)

1. Part of this work was presented at the 87th Spring Meeting of the Chemical Society of Japan, 3D3-13, March 2007.
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3. For an analogy, the dehydrogenative double silylation is well recognized, (a) Tamao, K.; Miyake, N.; Kiso, Y.; Kumada, M. J. Am. Chem. Soc. 1975, 97, 5603.
4. 2P(O)H.
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10. 2) is a simple alkyl (aryl) group are not known, (a) Timofeeva, T. N.; Ignat'ev, V. M.; Ionin, B. I.; Petrov, A. A. Doklady Akade. Nauk SSSR 1969, 189, 1052; CAN 72:67041.
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17. 31P NMR spectra (see Supporting Information for details).
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19. Structures of complexes 8 and 9 were all unambiguously determined by X-ray crystallography (see Supporting Information for detailed data).
20. 1H NMR spectroscopy.