LA-ICP-MS study of apatite- and K feldspar-hosted primary carbonatite melt inclusions in clinopyroxenite xenoliths from lamprophyres, Hungary: Implications for significance of carbonatite melts in the Earth's mantle

Geochimica et Cosmochimica Acta

Volumn 72, Issue 7, 2008, Pages 1864-1886

  Guzmics, Tibor ^a   Zajacz, Zoltán ^a,b   Kodolányi, János ^a,c   Halter, Werner ^b   Szabó, Csaba ^a  

^a EÖTVÖS LORÁND UNIVERSITY   (Hungary)

^b ETH ZURICH   (Switzerland)

^c UNIVERSITY OF BERN   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

APATITE; CARBONATITE; CHEMICAL COMPOSITION; EXPERIMENTAL STUDY; FELDSPAR; FLUID INCLUSION; INDUCTIVELY COUPLED PLASMA METHOD; LAMPROPHYRE; MANTLE CHEMISTRY; METASOMATISM; PARTITIONING; SEPARATION; UPPER MANTLE; XENOLITH;

BAKONY MOUNTAINS; CENTRAL EUROPE; EURASIA; EUROPE; HUNGARY; TRANSDANUBIAN MOUNTAINS;

EID: 40949099422     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.gca.2008.01.024     Document Type: Article

References (63)

1. Baker M.B., and Wyllie P.J. High pressure apatite solubility in carbonate-rich liquids: implications for mantle metasomatism. Geochim. Cosmochim. Acta 56 (1992) 3409-3422
2. Blundy J., and Dalton J. Experimental comparison of trace element partitioning between clinopyroxene and melt in carbonate and silicate systems, and implication for mantle metasomatism. Contrib. Mineral Petrol. 139 (2000) 356-371
3. Blundy J.D., and Wood B.J. Prediction of crystal-melt partition coefficients from elastic moduli. Nature 372 (1994) 452-454
4. Coltorti M., Bonadiman C., Hinton R.W., Siena F., and Upton B.G.J. Carbonatite metasomatism of the oceanic upper mantle: evidence from clinopyroxenes and glasses in ultramafic xenoliths of Grande Comore, Indian Ocean. J. Petrol. 40 (1999) 133-165
5. Chakhmouradian A.R. High-field strength elements in carbonatitic rocks: geochemistry, crystal chemistry and significance for constraining the sources of carbonatites. Chem. Geol. 235 (2006) 138-160
6. 2 from 3 to 7 GPa. Contrib. Mineral Petrol. 131 (1998) 123-135
7. Dalton J.A., and Wood B.J. The composition of primary carbonate melts and their evolution through wall rock reaction in the mantle. Earth Planet. Sci. Lett. 119 (1993) 511-525
8. Danyushevsky L.V., McNeil A.W., and Sobolev A.V. Experimental and petrological studies of melt inclusions in phenocrysts from mantle-derived magmas: an overview of techniques, advantages and complications. Chem. Geol. 183 (2002) 5-24
9. Doroshkevich A.G., Wall F., and Ripp G.S. Calcite-bearing dolomite carbonatite dykes from Veseloe, North Transbaikalia, Russia and possible Cr-rich mantle xenoliths. Min. Pet. 90 (2006) 19-49
10. 2 system. Am. J. Sci. 278 (1978) 305-343
11. Fleet M.E., and Pan Y. Site preference of rare earth elements in fluorapatite. Am. Min. 80 (1995) 329-335
12. 2O-bearing phosphate fluoride melts and the role of volatile components. Geochim. Cosmochim. Acta 61 (1997) 4745-4760
13. Foley S.F., Barth M.G., and Jenner G.A. Rutile/melt partition coefficients for trace elements and an assessment of the influence on rutile on trace element characteristics of the subduction zone magmas. Geochim. Cosmochim. Acta. 64 (2000) 933-938
14. Green T.H., Adam J., and Sie S.H. Trace element partitioning between silicate minerals and carbonatite at 25 kbar and application to mantle metasomatism. Mineral. Petrol. 46 (1992) 179-184
15. Green T.H., and Pearson N.J. An experimental study of Nb and Ta partitioning between Ti-rich minerals and silicate liquids at high pressure and temperature. Geochim. Cosmochim. Acta 51 (1987) 55-62
16. Green D.H., and Wallace M.E. Mantle metasomatism by ephemeral carbonatite melts. Nature 336 (1988) 459-462
17. Goldschmidt V.M. The principles of the distribution of chemical elements in minerals and rocks. J Chem. Soc. Lond. 140 (1937) 655-673
18. Guzmics T., Kodolányi J., Kovács I., Bali E., Zajacz Z., Halter W. and Szabó C. 2007a. Primary carbonatite melt inclusions in apatite and in K feldspar from clinopyroxene-rich mantle xenoliths from Hungarian lamprophyres: implications for generation and evolution of carbonatite melts in the Earth's mantle. ECROFI-XIX. Bern, Switzerland. p. 78 (abstr.).
19. Guzmics T., Zajacz Z., Szabó Cs. and Halter W. 2007b. Apatite- and K feldspar-hosted primary carbonatite melt inclusions from mantle xenoliths, Hungary. Goldschmidt, Cologne, Germany. #A366 (abstr.).
20. Guzmics T., Zajacz Z., Szabó Cs. and Halter W. 2007c. LA-ICPMS study of clinopyroxene-apatite-K feldspar-phlogopite metasomatic mantle xenoliths from Hungarian lamprophyres and their primary carbonatite melt inclusions: implications for carbonatite melt metasomatism in the Earth's upper mantle. EMAW, Ferrara, Italy. (unpaged) (abstr.).
21. Halter W.E., Pettke T., Heinrich C.A., and Rothen-Rutishauser B. Major to trace element analysis of melt inclusions by laser-ablation ICP-MS: methods of quantification. Chem. Geol. 183 (2002) 63-86
22. Hammouda T. High-pressure melting of carbonated eclogite and experimental constraints on carbon recycling and storage in the mantle. Earth Planet. Sci. Lett. 214 (2003) 357-368
23. Hauri E.H., Shimizu N., Dieu J.J., and Hart S.R. Evidence for hotspot-related carbonatite metasomatism in the oceanic upper mantle. Nature 365 (1993) 221-227
24. Hoernle K., Tilton G., Le Bas M.J., Duggen S., and Garbe-Schönberg D. Geochemistry of oceanic carbonatites compared with continental carbonatites: mantle recycling of oceanic crustal carbonate. Contrib. Mineral Petrol. 142 (2002) 520-542
25. Hou Z., Tian S., Yuan Z., Xie Y., Yin S.,Yi L., Fei H. and Yang Z. The Himalayan collision zone carbonatites in western Sichuan, SW China: Petrogenesis, mantle source and tectonic implication. Earth Planet. Sci. Lett. 244, 234-250.
26. Hunter R.H., and McKenzie D. The equilibrium geometry of carbonate melts in rocks of mantle composition. Earth Planet. Sci. Lett. 92 (1989) 347-356
27. Klemme S., and Dalpé C. Trace-element partitioning between apatite and carbonatite melt. Am. Min. 88 (2003) 639-646
28. Klemme S., van der Laan S.R., Foley S.F., and Günther D. Experimentally determined trace and minor element partitioning between clinopyroxene and carbonatite melt under upper mantle conditions. Earth Planet. Sci. Lett. 133 (1995) 439-448
29. Kogarko L.N., Krigman L.D., Petrova Y.N., and Solovova I.P. Phase equilibra in the fluorapatite-nepheline-diopside system and origin oh the Khibny apatite deposits. Trans. from Geokhimiya 1 (1977) 42-55
30. 2 at 2.7 GPa. Contrib. Mineral Petrol. 138 (2000) 199-213
31. Lee W.J., and Wyllie P.J. Liquid immiscibility between nephelinite and carbonatite from 1.0-2.5 GPa compared with mantle compositions. Contrib. Mineral Petrol. 127 (1997) 1-16
32. 2. J. Petrol. 39 (1998) 495-517
33. 2 at 1 GPa, metasomatic wehrlites and primary carbonatite magmas. Contrib. Mineral Petrol. 138 (2000) 214-228
34. Nag K., Arima M., and Gupta A.K. Experimental study of the joins forsterite-diopside-leucite and forsterite-leucite-åkermanite up to 2.3 GPa [P(H2O) = P(Total)] and variable temperatures: its petrological significance. Lithos 98 (2007) 177-194
35. Nichols G.T., Wyllie P.J., and Stern C.R. Subduction zone melting of pelagic sediments constrained by melting experiments. Nature 371 (2002) 785-788
36. Onuma N., Higuchi H., Wakita H., and Nagasawa H. Trace element partition between two pyroxenes and the host lava. Earth Planet. Sci. Lett. 5 (1968) 47-51
37. Prowatke S., and Klemme S. Trace element partitioning between apatite and silicate melts. Geochim. Cosmochim. Acta 70 (2006) 4513-4527
38. Purton J.A., Allan N.L., Blundy J.D., and Wasserman E.A. Isovalent trace element partitioning between minerals and melts-a computer simulation study. Geochim. Cosmochim. Acta 60 (1996) 4977-4987
39. Roedder E. (1984): Fluid Inclusions. In Reviews in mineralogy (ed. P. H. Ribbe). Mineralogical Society of America Series, vol. 12, Chelsea, p. 646.
40. Roedder E. Silicate liquid immiscibility in magmas. In: Yoder H.S. (Ed). The evolution of the igneous rocks (1987), Princeton University Press, Princeton 15-58
41. Rudnick R.L., Barth M., Horn I., and McDonough W.F. Rutile-bearing refractory eclogites: missing link between continents and depleted mantle. Science 287 (2000) 278-281
42. Rudnick R.L., McDonough W.F., and Chappell B.W. Carbonatite metasomatism in the northern Tanzanian mantle-petrographic and geochemical characteristics. Earth Planet. Sci. Lett. 114 (1993) 463-475
43. Ryabchikov I.D., and Hamilton D.L. Interaction of carbonate-phosphate melts with mantle peridotites at 20-35 kbar. S. Afr. Geol. 96 3 (1993) 143-148
44. Safonov O.G., Perchuk L.L., and Litvin Y.A. Melting relations in the chloride-carbonate-silicate systems at high-pressure and the model for formation of alkalic diamond-forming liquids in the upper mantle. Earth. Planet. Sci. Lett. 253 (2007) 112-128
45. Sha L.-K., and Chappell B.W. Apatite chemical composition, determined by electron microprobe and laser ablation inductively coupled plasma mass spectrometry, as a probe into granite petrogenesis. Geochim. Cosmochim. Acta 63 (1999) 3861-3881
46. Shannon R.D. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Cryst A32 (1976) 751-767
47. Sun S.S., and McDonough W.F. Chemical and isotopic systematics of oceanic basalts; implications for mantle composition and processes. In: Saunders A.D., and Norry M.J. (Eds). Magmatism in the ocean basins (1989), Geological Society of London, London 313-345
48. Sweeney R.J. Carbonatite melt composition in the Earth's mantle. Earth Planet. Sci. Lett. 128 (1994) 259-270
49. Sweeney R.J., Prozesky V., and Przybylowicz W. Selected trace and minor element partitioning between peridotite minerals and carbonatite melts at 18-46 kb pressure. Geochim. Cosmochim. Acta 59 (1995) 3671-3683
50. Szabó Cs. Xenoliths from cretaceous lamprophyres of Alcsútdoboz-2 borehole, Transdanubian Central Mountains, Hungary. Acta Min. Petrograph. 27 (1985) 39-50
51. Szabó C., Kubovics I., and Molnár Z. Alkaline lamprophyre and related dyke rocks in NE Transdanubia, Hungary: the Alcsútdoboz-2 (AD-2) borehole. Mineral Petrol 47 (1993) 127-148
52. Thibault Y., Edgar A.D., and Lloyd F.E. Experimental investigation of melts from a carbonated phlogopite lherzolite: implications for metasomatism in the continental lithospheric mantle. Am. Min 77 (1992) 784-794
53. Thomsen T. B. and Schmidt M. W., in press. Melting of carbonaceous pelites at 2.5-5.0 GPa, silicate-carbonatite liquid immiscibility, and potassium-carbon metasomatism of the mantle. Earth Planet. Sci. Lett. doi:10.1016/j.epsl.2007.11.027.
54. Wallace M.E., and Green D.H. An experimental determination of primary carbonatite magma composition. Nature 335 (1988) 343-346
55. Veksler I.V., Petibon C., Jenner G.A., Dorfman A.M., and Dingwell D.B. Trace element partitioning in immiscible silicate-carbonate liquid systems: an initial experimental study using a centrifuge autoclave. J. Petrol. 39 (1998) 2095-2104
56. Van Westrenen W., Allan N.L., Blundy J.D., Purton J.A., and Wood B.J. Atomistic simulation of trace element incorporation into garnets-comparison with experimental garnet-melt partitioning data. Geochim. Cosmochim. Acta 64 (2000) 1629-1639
57. Watson E.B., Brenan J.M., and Baker D.R. Distribution of fluids in the continental mantle. In: Menzies M.A. (Ed). Continental Mantle (1990), Clarendon Press, Oxford 111-125
58. Woolley A.R., and Kempe D.R.C. Carbonatites: nomenclature, average chemical compositions, and trace element distribution. In: Bell K. (Ed). Carbonatites: genesis and evolution (1989), Unwin Hyman, London 1-14
59. 2 at mantle pressures with geophysical and petrological applications. Contrib. Mineral Petrol. 54 (1976) 79-107
60. Yaxley G.M., and Brey G.P. Phase relations of carbonate-bearing eclogite assemblages from 2.5 to 5.5 GPa: implications for petrogenesis of carbonatites. Contrib. Mineral Petrol. 146 (2004) 606-619
61. Yaxley G.M., Crawford A.J., and Green D.H. Evidence for carbonatite metasomatism in spinel peridotite xenoliths from western Victoria, Australia. Earth Planet. Sci. Lett. 107 (1991) 305-317
62. Yaxley G.M., Green D.H., and Kamenetsky V. Carbonatite metasomatism in the southeastern Australian lithosphere. J. Petrol. 39 (1998) 1917-1930
63. Zajacz Z., and Halter W. LA-ICPMS analyses of silicate melt inclusions in co-precipitated minerals: quantification, data analysis and mineral/melt partitioning. Geochim. Cosmochim. Acta 71 (2007) 1021-1040