Characterization and performance of a ZnO-ZnCr2O4/CeO2-ZrO2 monolithic catalyst for methanol auto-thermal reforming process

International Journal of Hydrogen Energy

Volumn 33, Issue 6, 2008, Pages 1643-1651

  Liu, Na ^a,b   Yuan, Zhongshan ^a   Wang, Shudong ^a   Zhang, Chunxi ^a   Wang, Shujuan ^a   Li, Deyi ^a  

^a DALIAN INSTITUTE OF CHEMICAL PHYSICS   (China)

^b UNIVERSITY OF CHINESE ACADEMY OF SCIENCES   (China)

Author keywords

CeO2 ZrO2; Hydrogen; Methanol auto thermal reforming; Monolithic catalysts; ZnCr2 O4; ZnO

Indexed keywords

METHANOL; REFORMING REACTIONS; ZINC OXIDE;

METHANOL AUTO-THERMAL REFORMING; MONOLITHIC CATALYSTS;

CATALYSTS;

EID: 40849102390     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2007.12.058     Document Type: Article

References (42)

1. Lattner J.R., and Harold M.P. Comparison of methanol-based fuel processors for PEM fuel cell systems. Appl Catal B-Environ 56 1-2 (2005) 149-169
2. Ahmed S., and Krumpelt M. Hydrogen from hydrocarbon fuels for fuel cells. Int J Hydrogen Energy 26 4 (2001) 291-301
3. Lindström B., Agrell J., and Pettersoon L.J. Combined methanol reforming for hydrogen generation over monolithic catalysts. Chem Eng J 93 1 (2003) 91-101
4. Cubeiro M.L., and Fierro J.L.G. Partial oxidation of methanol over supported palladium catalysts. Appl Catal A-Gen 168 2 (1998) 307-322
5. Geissler K., Newson E., Vogel F., Truong T., Hottinger P., and Wokaun A. Autothermal methanol reforming for hydrogen production in fuel cell applications. Phys Chem Chem Phys 3 3 (2001) 289-293
6. Lyubovsky M., and Roychoudhury S. Novel catalytic reactor for oxidative reforming of methanol. Appl Catal B 54 4 (2004) 203-215
7. Raimondi F., Schnyder B., Kötz R., Schelldorfer R., Jung T., Wambach J., et al. Structural changes of model Cu/ZnO catalysts during exposure to methanol reforming conditions. Surf Sci 532-5 (2003) 383-389
8. Reitz T.L., Ahmed S., Krumpelt M., Kumar R., and Kung H.H. Characterization of CuO/ZnO under oxidizing conditions for the oxidative methanol reforming reaction. J Mol Catal A-Chem 162 1-2 (2000) 275-285
9. 3 catalyst. Appl Catal B-Environ 38 4 (2002) 259-269
10. Velu S., Suzuki K., Okazaki M., Kapoor M.P., Osaki T., and Ohashi F. Oxidative steam reforming of methanol over CuZnAl(Zr)-oxide catalysts for the selective production of hydrogen for fuel cells: catalyst characterization and performance evaluation. J Catal 194 2 (2000) 373-384
11. 2 over nonreduced Zr-containing CuO/ZnO catalysts. J Catal 223 2 (2004) 340-351
12. 2-promoter on catalytic performance of CuZnAlO catalysts for production of hydrogen by steam reforming of methanol. Int J Hydrogen Energy 29 15 (2004) 1617-1621
13. Lindström B., Pettersson L.J., and Govind M.P. Activity and characterization of Cu/Zn, Cu/Cr and Cu/Zr on γ-alumina for methanol reforming for fuel cell vehicles. Appl Catal A-Gen 234 1-2 (2002) 111-125
14. 2 catalysts. Catal Commun 5 5 (2004) 231-235
15. Y catalysts prepared by deposition-precipitation, co precipitation, and complexation-combustion methods. J Catal 228 1 (2004) 206-217
16. 2. Appl Catal B-Environ 57 3 (2005) 201-209
17. Liu S., Takahashi K., Uematsu K., and Ayabe M. Hydrogen production by oxidative methanol reforming on Pd/ZnO catalyst: effects of the addition of a third metal component. Appl Catal A-Gen 277 1-2 (2004) 265-270
18. Liu S., Takahashi K., Uematsu K., and Ayabe M. Hydrogen production by oxidative methanol reforming on Pd/ZnO. Appl Catal A-Gen 283 12 (2005) 125-135
19. Cao C., Xia G., Holladay J., Jones E., and Wang Y. Kinetic studies of methanol steam reforming over Pd/ZnO catalyst using a microchannel reactor. Appl Catal A-Gen 262 1 (2004) 19-29
20. Qi A., Hong X., Wang S., Fu G., and Wu D. Study on catalysts for methanol oxidation reforming. Mod Chem Ind China 7 (2000) 37-39
21. 2 solid-solutions as highly efficient oxygen exchangers: dependence of the reduction behavior and the oxygen storage capacity on the structural-properties. J Catal 151 1 (1995) 168-177
22. 2 mixed oxides. Comparison of the citrate and sol-gel preparation methods. Chem Mater 15 2 (2003) 395-403
23. 2-containing materials. Catal Rev-Sci Eng 38 4 (1996) 439-520
24. 2 mixed oxides. J Mater Chem 15 6 (2005) 633-648
25. González-Velasco J.R., Gutiérrez-Ortiz M.A., Marc J., Botas J.A., González-Marcos M.P., and Blanchard G. Effects of redox thermal treatments and feedstream composition on the activity of Ce/Zr mixed oxides for TWC applications. Appl Catal B-Environ 25 1 (2000) 19-29
26. 2 mixed oxides by coprecipitation: role of preparation conditions. Appl Catal B-Environ 58 3-4 (2005) 203-210
27. Wang S, Liu N, Yuan Z, Wang S, Zhang C, Fu G. Application and preparation method of a methanol auto-thermal reforming catalyst for hydrogen production. Chinese Patent: CN200410031348.3;2004.
28. Liu N., Wang S., Yuan Z., Zhang C., Wang S., Li D., et al. Methanol autothermal reforming for hydrogen generation over monolithic catalyst. J Chem Ind Eng China 55 Suppl (2004) 90-94
29. 2 mixed oxide solid solution catalysts prepared via urea hydrolysis. Appl Catal A-Gen 234 12 (2002) 221-233
30. 2 mixed oxides. J Catal 187 1 (1999) 177-185
31. Bozo C., Gaillard F., and Guilhaume N. Characterisation of ceria-zirconia solid solutions after hydrothermal ageing. Appl Catal A-Gen 220 1-2 (2001) 69-77
32. 2 system. Appl Catal B-Environ 16 2 (1998) 105-117
33. 2 mixed oxides. J Alloys Compd 395 12 (2005) 135-140
34. Damyanova S., Perez C.A., Schmal M., and Bueno J.M.C. Characterization of ceria-coated alumina carrier. Appl Catal A-Gen 234 1-2 (2002) 271-282
35. 2 solid solutions upon sintering at high temperatures. Catal Lett 33 12 (1995) 193-200
36. 4/Pd catalyst. J Catal 111 1 (1988) 199-209
37. Pan L., and Wang S. Methanol steam reforming in a compact plate-fin reformer for fuel-cell systems. Int J Hydrogen Energy 30 9 (2005) 973-979
38. Wang S., and Wang S. Energy analysis and optimization of methanol generating hydrogen system for PEMFC. Int J Hydrogen Energy 31 12 (2006) 1747-1755
39. Wang S.N., Hong X.L., Wang S.D., and Wu D.Y. Analysis of independent reactions in kinetic model of methanol steam reforming process. J Fuel Chem Technol China 29 2 (2001) 174-176
40. 2 monolithic catalyst in oxidative steam reforming of methanol. Fuel Process Technol 88 1 (2007) 65-71
41. 3 catalyst in a monolithic reactor. Catal Today 125 12 (2007) 97-102
42. Yan X., Wang S., Li X., Hou M., Yuan Z., Li D., et al. A 75-kW methanol reforming fuel cell system. J Power Sources 162 2 (2006) 1265-1269