Methods for studying reaction kinetics in gas chromatography, exemplified by using the 1-chloro-2,2-dimethylaziridine interconversion reaction

Journal of Chromatography A

Volumn 1186, Issue 1-2, 2008, Pages 144-160

  Krupcik J ^a   Mydlova J ^a   Majek P ^a   Simon P ^a   Armstrong, D W ^b  

^a SLOVAK UNIVERSITY OF TECHNOLOGY   (Slovakia)

^b UNIVERSITY OF TEXAS AT ARLINGTON   (United States)

Author keywords

1 Chloro 2,2 dimethylaziridine enantiomers; Arrhenius and Eyring equations; Gas chromatography; Reaction kinetics

Indexed keywords

ARRHENIUS PLOTS; CHEMICAL ACTIVATION; GAS CHROMATOGRAPHY; GAUSSIAN DISTRIBUTION; STOCHASTIC MODELS; THERMODYNAMIC PROPERTIES;

DIMETHYLAZIRIDINE ENANTIOMERS; DYNAMIC GAS CHROMATOGRAPHY; EYRING EQUATIONS;

ENANTIOMERS;

1 CHLORO 2,2 DIMETHYLAZIRIDINE; AZIRIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ACCURACY; ANALYTIC METHOD; ANALYTICAL PARAMETERS; CALCULATION; CAPILLARY GAS CHROMATOGRAPHY; CHEMICAL REACTION; CHEMICAL REACTION KINETICS; CHIRALITY; COLUMN CHROMATOGRAPHY; COMPUTER ANALYSIS; CONCENTRATION (PARAMETERS); DENSITY FUNCTIONAL THEORY; ELUTION; ENANTIOMER; ENANTIOSELECTIVITY; ENERGY; GAS CHROMATOGRAPHY; NORMAL DISTRIBUTION; PRIORITY JOURNAL; PROBABILITY; REACTION ANALYSIS; REVIEW; SEPARATION TECHNIQUE; SIMULATION; STATISTICAL ANALYSIS; TEMPERATURE; THEORETICAL STUDY; THERMODYNAMICS;

EID: 40649128956     PISSN: 00219673     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.chroma.2008.01.028     Document Type: Review

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