Silver and copper polyynides: A study with HPLC, FT-IR and XPS spectroscopy

Fullerenes Nanotubes and Carbon Nanostructures

Volumn 16, Issue 2, 2008, Pages 126-141

  Cataldo, Franco ^a,d   Compagnini, Giuseppe ^b   Scandurra, Antonino ^c   Strazzulla, Gianni ^d  

^a Actinium Chemical Research   (Italy)

^b UNIVERSITY OF CATANIA   (Italy)

^c Laboratorio Superfici e Interfasi SUPERLAB   (Italy)

^d INAF OSSERVATORIO ASTROFISICO DI CATANIA   (Italy)

Author keywords

Chemical structure; HPLC, FT IR spectroscopy; Metal polyynides; Polyynes; XPS spectroscopy

Indexed keywords

COUPLING AGENTS; FOURIER TRANSFORM INFRARED SPECTROSCOPY; HYDROLYSIS; X RAY PHOTOELECTRON SPECTROSCOPY;

ACID HYDROLYSIS; CHEMICAL STRUCTURES; METAL POLYYNIDES;

ACETYLATION;

EID: 40549128696     PISSN: 1536383X     EISSN: 15364046     Source Type: Journal    
DOI: 10.1080/15363830801888024     Document Type: Article

References (22)

1. Cataldo, F. (1998) Structural relationship between dicopper diacetylide and dicopper acetylide. Eur. J. Solid State Inorg. Chem., 35: 281-291.
2. Cataldo, F. (1998) From dicopper diacetilyde to carbyne. Eur. J. Solid State Inorg. Chem., 35: 293-304.
3. Cataldo, F. (1999) From dicopper acetylide to carbyne. Polym. Int., 48: 15-22.
4. Cataldo, F. (1998) Spectroscopical characterization of carbonaceous matter prepared through Glaser coupling reaction route. Carbon, 37: 161-163.
5. Cataldo, F. and Capitani, D. (1999) Preparation and characterization of carbonaceous matter rich in diamond-like carbon and carbyne. Mater. Chem. Phys., 59: 225-231.
6. Cataldo, F. (2001) Raman scattering investigation of carbynoid and diamond-like carbon. Fullerene Sci. Technol., 9: 153-160.
7. Cataldo, F. (2004) Synthesis of polyynes in a submerged electric arc. Carbon, 42: 129-142.
8. Cataldo, F. (2004) Submerged electric arc between graphite electrodes: a one-pot tool for the synthesis of long chain polyynes in solution. Tetrahedron Lett., 45: 141-144.
9. Cataldo, F. (2004) Polyynes and cyanopolyynes synthesis from the submerged electric arc: about the role played by the electrode and solvents in polyynes formation. Tetrahedron, 60: 4265-4274.
10. Cataldo, F. (2005) Polyynes: Synthesis, Properties and Applications; Taylor & Francis Publishing House, CRC Press: Boca Raton, FL.
11. Cataldo, F., Ursini, O., and Angelini, G. (2007) Kinetics of the polyynes formation with the submerged carbon arc. J. Electroanal. Chem., 602: 82-90.
12. Cataldo, F. and Casari, C.S. (2007) Synthesis, structure and thermal properties of copper and silver polyynides and acetylides. J. Inorg. Organomet Polym. Mater., 17:641-651.
13. Cataldo, F. (2005) The simplest approach to prepare solutions of polyynes in hydrocarbons. Tetrahedron Lett, 46: 3665-3667.
14. Cataldo, F. (2005) A new method synthesizing polyynes in solution. Carbon, 43: 2792-2800.
15. (a) Cotton, F.A. and Wilkinson, G. (1988) Advanced Inorganic Chemistry, 5th edn.; John Wiley & Sons: New York;
16. (b) Cotton, F.A. and Wilkinson, G. (1962) Advanced Inorganic Chemistry, a Comprehensive Text, 1st edn.; John Wiley & Sons: New York.
17. Avram, M. and Mateescu, G.D. (1972) Infrared Spectroscopy Applications in Organic Chemistry; Wiley-Interscience: New York, pp. 196-200.
18. (a) Bauer, H., Faust, J., Frobose, R., Fussel, J., Kruerke, U., Kunz, M., and Somer, H.M. (1987) Gmellin Handbook of Inorganic Chemistry, 8th edn.; Cu Organocopper Compounds Part 4, System Number 60, Springer-Verlag: Berlin;
19. (b) Gmellins Handbuch der Anorganischen Chemie, Kupfer; Teil B, Lieferung 2, System-Nummer 60, 1961, Verlag Chemie: Weinheim.
20. Lucotti, A., Tomasini, M., Del Zoppo, M., Castiglioni, C., Zerbi, G., Cataldo, F., Casari, C.S., Li Bassi, A., Russo, V., Bogana, M., and Bottani, C.E. (2006) Raman and SERS investigation of isolated sp-carbon chains. Chem. Phys. Lett., 417: 78-82.
21. Casari, C.S., Russo, V., Li Bassi, A., Bottani, C.E., Cataldo, F., Lucotti, A., Tomasini, M., Del Zoppo, M., Castiglioni, C., and Zerbi, G. (2007) Stabilization of linear carbon structures in solid Ag nanoparticles assembly. Appl. Phys. Lett., 90: 13111-13113.
22. Briggs, D. and Seah, M.P. (1990) Practical Surface Analysis, 2nd edn.; John Wiley & Sons: Chichester, Vol. 1.