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3 carbon atom, has been confirmed by preliminary theoretical investigations currently in progress.
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3 carbon atom, has been confirmed by preliminary theoretical investigations currently in progress.
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34
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0346077150
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For examples of neutral iron methylenecyclohexadiene complexes, see: Howell, J. A. S, Thomas, M. J. Organometallics 1985, 4, 1054
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40
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40549137555
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Crystal data of 7 and 11. Data were recorded at room temperature on a Kappa-CCD Enraf-Nonius diffractometer with graphite- monochromated Mo Kα radiation (λ, 0.71073 Å) and the ai-scan technique. The structure was solved by direct methods and refined with full-matrix least-squares technique on F using the Crystals18 programs. Molecular structures were drawn with the program Cameron.19 Complex 7: C16H13MnO4S, M, 356.27; monoclinic, a, 6.7948(6) Å, b= 19.899(3) Å, c, 12.1956(15) Å U, 1613.3(3) Å3, T, 250 K, space group P21/n, Z, 4, 15 998 reflections measured, 4629 unique (Rint, 0.043, which were used in all calculations. The final wR(F2) was 0.054 all data, Complex 11: C16H12BF4MnO4S, M, 442.07; monoclinic
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2) was 0.053 (all data).
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