메뉴 건너뛰기




Volumn 37, Issue 2, 2008, Pages 182-183

[5]Rotaxanes composed of α-cyclodextrin and Pd or Pt complexes with alkylbipyridinium ligands

Author keywords

[No Author keywords available]

Indexed keywords


EID: 40449139646     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2008.182     Document Type: Article
Times cited : (19)

References (28)
  • 2
    • 0003542983 scopus 로고    scopus 로고
    • ed. by J.-P. Sauvage, C. Dietrich-Buchecker, Wiley-VCH, Weinheim
    • b) Molecular Catenanes, Rotaxanes and Knots, ed. by J.-P. Sauvage, C. Dietrich-Buchecker, Wiley-VCH, Weinheim, 1999.
    • (1999) Molecular Catenanes, Rotaxanes and Knots
  • 14
    • 33746924101 scopus 로고    scopus 로고
    • Examples of [3]rotaxanes: a H. Yamaguchi, T. Oshikiri, A. Harada, J. Phys.: Condens. Matter 2006, 18, S1809.
    • Examples of [3]rotaxanes: a) H. Yamaguchi, T. Oshikiri, A. Harada, J. Phys.: Condens. Matter 2006, 18, S1809.
  • 25
    • 40449141036 scopus 로고    scopus 로고
    • Data of 2: 1HNMR (300MHz, D2O, rt, δ 1.02-1.59 (14H, CH2-axle, 1.70-2.04 (br, 2H, NCH2CH 2, 3.29-3.82 (80H, CH-α-CD, CH2-α-CD, OCH2-axle, OMe, 4.86 (br, 12H, CH-α-CD, 5.94 (s, 2H, ortho-C6H3, 6.04 (s, 1H, para-C 6H3, 7.73 (br, 2H, C10H8N 2, 8.22 (d, 2H, J, 5 Hz, 8.58 (br, 2H, C10H 8N2, 8.80 (d, 2H, C10H8N 2, J, 5Hz, The signal of NCH2 hydrogens was overlapped with the signal of HDO (δ 4.63, IR (KBr, rt, v 3000-3700 (O-H, 1206 (C-O-C) cm-1. Anal. Calcd for C100H 157N2O63Cl·OH2O, C, 47.31; H, 6.71; N, 1.10; Cl, 1.40, Found: C, 47.25; H, 6.59; N, 1.23; Cl, 1.31
    • 2O): C, 47.31; H, 6.71; N, 1.10; Cl, 1.40%. Found: C, 47.25; H, 6.59; N, 1.23; Cl, 1.31%.
  • 26
    • 40449102816 scopus 로고    scopus 로고
    • Data of 3: 1HNMR (400MHz, D2O, rt, δ 1.07-1.53 (28H, CH2-axle, 1.96 (br, 4H, NCH2CH 2, 2.77 (s, 4H, CH2NH2, 3.34-3.85 (160H, CH-α-CD, CH2-α-CD, OCH2-Axle, OCH 3, 4.52 (br, NCH2, 4H, 4.88 (br, 24H, CH-α-CD, 5.98 (s, 4H, ortho-C6H3, 6.08 (s, 2H, para-C6H3, 7.91 (br, 4H, C10H 8N2, 8.21 (br, 4H, C10H8N 2, 8.85 (8H, C10H8N2, Signals of OH and NH2 hydrogens were not observed. 13C{1H} NMR (100 MHz, D2O, rt, δ 28.1 (CH2, 29.0 (CH 2, 31.2 (CH2, 31.7 (CH2, 32.0 (CH 2, 32.8 (2C, CH2, 33.0 (CH2, 48.7 (en, 57.4 (OCH3, 61.4 CH2
    • 2O): C, 44.17; H, 6.50; N, 2.55%. Found: C, 44.17; H, 6.30; N, 2.19%.
  • 27
    • 40449088321 scopus 로고    scopus 로고
    • Data of 4: 1HNMR (300MHz, D2O, rt, δ 1.22-1.41 (24H, CH2-axle, 1.49 (br, 4H, OCH2CH 2, 1.95 (br, 4H, NCH2CH2, 2.69 (s, 4H, CH2NH2, 3.28-3.86 (160H, CH-α-CD, CH 2-α-CD, OCH2-axle, OCH3, 4.88 (d, 24H, CH-α-CD, J, 5Hz, 5.98 (s, 4H, ortho-C6H 3, 6.10 (s, 2H, para-C6H3, 7.90 (d, 4H, C10H8N2, J, 5Hz, 8.24 (d, 4H, C10H8N2, J, 7Hz, 8.87 (8H, C 10H8N2, The signal of NCH2 hydrogens was overlapped with the signal of HDO (δ 4.63, Signals of OH and NH2 hydrogens were not observed. 13C{1H}NMR (100 MHz, D2O, rt, δ 28.1 (CH2, 29.1 (CH 2, 31.2 CH2
    • 3). 3-(Trimethylsilyl)-1- propanesulfonic acid, sodium salt was used as external standard.
  • 28
    • 40449090480 scopus 로고    scopus 로고
    • NOESY measurement of rotaxane 3 and 4 did not provide any further information to discuss head-to-head (or head-to-tail) arrangement of two CDs in a ligand.
    • NOESY measurement of rotaxane 3 and 4 did not provide any further information to discuss head-to-head (or head-to-tail) arrangement of two CDs in a ligand.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.