Insight into phosphine effects on the homogeneous hydrogenation of avermectins to ivermectin catalyzed by in-situ formed rhodium complexes

Reaction Kinetics and Catalysis Letters

Volumn 93, Issue 1, 2008, Pages 165-173

  Zgolicz, Patricia D ^a   Cabrera, María I ^a   Grau, Ricardo J ^a  

^a Instituto de Desarrollo Tecnologico para la Industria Quimica   (Argentina)

Author keywords

Avermectin; Homogeneous hydrogenation; Ivermectin; Phosphine; Rhodium

Indexed keywords

CATALYST ACTIVITY; HYDROGENATION; LIGANDS; SUBSTITUTION REACTIONS;

ARYLPHOSPHINES; ELECTRON-DONOR CAPACITY;

RHODIUM COMPOUNDS;

EID: 40349100707     PISSN: 01331736     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11144-008-5256-z     Document Type: Article

References (22)

1. J.C. Chabala, N. Westfiel, M.H. Fisher, N. Bridgewater: U.S. Patent 4,199,569 (1980), to Merck & Co.
2. W.C. Campbell, M.H. Fisher, E.O. Stapley, G. Albers-Schöberg, T.A. Jacob: Science, 221, 823 (1983).
3. W.L. Shoop, H. Mrozik, M.H. Fisher: Vet. Parasitol., 59, 139 (1995).
4. E.W. Cupp, M.J. Bernardo, A.E. Kiszewski, R.C. Collins, H.R. Taylor, M.A. Aziz, B.M. Greene: Science, 231, 740 (1986).
5. W.C. Campbell: Annu. Rev. Microbiol., 45, 445 (1991).
6. H.B. Dull: Ann. Trop. Med. Parasitol., 92,(suppl) S67 (1998).
7. R.D. Pearson, in: G.L Mandell, J.E. Bennet, R. Dolin (Eds.). Principles and Practice of Infectious Diseases, pp. 205, 5th ed. Philadelphia: Churchill Livingstone, 2000.
8. J. Victoria: J. Dermatol. Pediatr. Lat, 1, 61 (2003).
9. C.A. Guzzo. C.M. Clineschmidt, G. Schorn, J.M. Reynolds: U.S. Patent 7,064,108 (2006), to Merck & Co.
10. J.C. Chabala, N. Westfiel, M.H. Fisher, N. Bridgewater: U.S. Patent 4,199,569 (1980), to Merck & Co.
11. D. Arlt, G. Bonse, F. Reisewitz: U.S. Patent 5,656,748 (1997) to Bayer.
12. L. Sogli, E. Siviero, A. Rossi, D. Terrasan, E. Bernasconi, P. Terreros, F. Salto: WO 9838201 (1998), to Antibioticos Spa.
13. D. Arlt, G. Bonse: U.S. Patent 6,072,052 (2000), to Bayer.
14. P.D. Zgolicz, M.I. Cabrera, R.J. Grau: Applied Catal. A: General, 283, 99 (2005).
15. M.I. Cabrera, P.D. Zgolicz, R.J. Grau: Applied Catal. A: General (2007), in press.
16. M.I. Cabrera, P.D. Zgolicz, R.J. Grau: React. Kinet. Catal. Lett. (2007), submitted.
17. R.J. Grau, A.E. Cassano, M.A. Baltanás: Ind. Eng. Chem. Res., 26, 18 (1987).
18. J. Tiburcio, S. Bernés, H. Torrens: Polyhedron, 25, 1549 (2006).
19. H.H. Jaffé: Chem. Rev., 53, 191 (1953).
20. T.A. Mastryukova, M.I. Kabachnik: Russ. Chem. Rev. (Engl. Transl.), 38, 795 (1969).
21. P.R. Wells: Chem Rev., 63, 171 (1963).
22. J. March: Organic Chemistry. Reactions, Mechanisms and Structure, pp. 278, 4th Ed., J. Wiley & Sons, New York 1992.