Oxidation reaction of high molecular weight dicarboxylic acids in sub- and supercritical water

Journal of Supercritical Fluids

Volumn 44, Issue 3, 2008, Pages 331-340

  Jin, Fangming ^a,b   Cao, Jianxun ^b   Kishita, Atsushi ^b   Enomoto, Heiji ^b   Moriya, Takehiko ^c  

^a TONGJI UNIVERSITY   (China)

^b TOHOKU UNIVERSITY   (Japan)

^c TOHOKU ELECTRIC POWER CO INC   (Japan)

Author keywords

Biomass; Carboxylic acids; Oxidation pathways; Oxidative decarboxylation; Radical reaction

Indexed keywords

BIOMASS; FREE RADICAL POLYMERIZATION; HYDROGEN PEROXIDE; MOLECULAR WEIGHT; OXIDATION; SUPERCRITICAL FLUIDS;

DICARBOXYLIC ACIDS; OXIDATION PATHWAYS; OXIDATIVE DECARBOXYLATION; RADICAL REACTION;

CARBOXYLIC ACIDS;

EID: 40049098102     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2007.09.004     Document Type: Article

References (26)

1. Helling R.K., and Tester J.W. Oxidation of simple compounds and mixtures in supercritical water: carbon, monoxide, ammonia, and ethanol. Environ. Sci. Technol. 22 (1988) 1319
2. P.A. Webley, J.W. Tester, Fundamental kinetics and mechanistic pathway for oxidation reactions in supercritical water, SAE Technical Paper Series 881039, 1988, p. 1351.
3. Webley P.A., and Tester J.W. Fundamental kinetics of methane oxidation in supercritical water. Energy Fuels 5 (1991) 411
4. P.A. Webley, H.R. Holgate, D.M. Stevenson, J.W. Tester, Oxidation kinetics of model compounds of metabolic waste in supercritical water, SAE Technical Paper Series 901333, 1990, p. 928.
5. Thornton T.D., and Savage P.E. Phenol oxidation in supercritical water. J. Supercrit. Fluids 3 (1990) 240
6. Crain N., Tebbal S., Li L., and Gloyna E.F. Kinetics and reaction pathway of pyridine oxidation in supercritical water. Ind. Eng. Chem. Res. 32 (1993) 2259
7. Devlln H.R., and Harris I.J. Mechanism of the oxidation of aqueous phenol with dissolved oxygen. Ind. Eng. Chem. Fundam. 23 (1984) 387
8. 3- and CHO-substituted phenols. Ind. Eng. Chem. Res. 36 (1997) 1391
9. DiNaro J.L., Tester J.W., Howard J.B., and Swallow K.C. Experimental measurements of benzene oxidation in supercritical water. AIChE J. 46 (2000) 2274
10. Savage P.E., and Smith M.A. Kinetics of acetic acid oxidation in supercritical water. Environ. Sci. Technol. 9 (1995) 216
11. Meyer J.C., Marrone P.A., and Tester J.W. Acetic acid oxidation and hydrolysis in supercritical water. AIChE J. 41 (1995) 2108
12. D.S. Lee, Supercritical water oxidation of acetamide and acetic acid, PhD Dissertation, Civil Engineering Department, University of Texas, Austin, 1990.
13. Holgate H.R., Meyer J.C., and Tester J.W. Glucose hydrolysis and oxidation in supercritical water. AIChE J. 41 (1995) 637
14. 2 in supercritical water. J. Supercrit. Fluids 19 (2000) 251
15. Jin F., Kishita A., and Enomoto H. Oxidation of garbage in supercritical water. High Pressure Res. 20 (2001) 525
16. Jin F., Moriya T., and Enomoto H. Oxidation reaction of high molecular weight carboxylic acids in supercritical water. Environ. Sci. Technol. 37 (2003) 3220
17. Day D.C., Hudgins R.R., and Silveston P.L. Oxidation of propionic acid solutions. Can. J. Chem. Eng. 51 (1973) 733
18. Williams P.E.L., Silveston P.L., and Hudgins R.R. Oxidation of butyric acid solutions. Can. J. Chem. Eng. 53 (1975) 354
19. Emanuel N.M. The Oxidation of Hydrocarbons in the Liquid Phase. 1st ed. (1965), Pergamon, New York
20. Emanuel N.M. The Oxidation of Hydrocarbons in the Liquid Phase. 1st ed. (1967), Plenum, New York
21. Morrison R.T., and Boyd R.N. Organic Chemistry. 6th ed. (1992), Prentice-Hall, Inc., Englewood Cliffs p. 680
22. McCollom T.M., and Seewald J.S. Experimental study of the hydrothermal reactivity of organic acids and acid anions. II. Acetic acid, acetate, and valeric acid. Geochim. Cosmochim. Acta 67 (2003) 3645
23. Kharaka Y.K., Carothers W.W., and Rosenbauer R.J. Thermal decarboxylation of acetic acid: implications for origin of natural gas. Geochim. Cosmochim. Acta 47 (1983) 397
24. Negron-Mendoza A., Ramos S., and Albarran G. Enhance decarboxylation reaction of carboxylic acids in clay minerals. Radiat. Phys. Chem. 46 (1995) 565
25. Watanabe M., Inomata H., Smith Jr. R.L., and Arai K. Catalytic decarboxylation of acetic acid with zirconia catalyst in supercritical water. Appl. Catal. A: Gen. 219 (2001) 149
26. Krammer P., and Vogel H. Hydrolysis of esters in subcritical and supercritical water. J. Supercrit. Fluids 16 (2000) 189