Triplet state dipole moments of aminobenzonitriles

Journal of Physical Chemistry A

Volumn 112, Issue 7, 2008, Pages 1359-1362

  Demeter, Attila ^a,b   Zachariasse, Klaas A ^a  

^a MAX PLANCK INSTITUTE FOR BIOPHYSICAL CHEMISTRY   (Germany)

^b CHEMICAL RESEARCH CENTER   (Hungary)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE; CHARGE TRANSFER; MAGNETIC MOMENTS; MICROWAVES; SOLVENTS;

AMINOBENZONITRILES; TRIPLET STATE DIPOLE MOMENTS;

ANILINE;

NITRILE; SOLVENT;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROCHEMISTRY; SPECTROSCOPY; TEMPERATURE; TIME;

ELECTROCHEMISTRY; MOLECULAR STRUCTURE; NITRILES; SOLVENTS; SPECTRUM ANALYSIS; TEMPERATURE; TIME FACTORS;

EID: 39849108947     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0747959     Document Type: Article

References (20)

1. Schuddeboom, W.; Jonker, S. A.; Warman, J. M.; Leinhos, U.; Kühnle, W.; Zachariasse, K. A. J. Phys. Chem. 1992, 96, 10809.
2. Köhler, G.; Grabner, G.; Rotkiewicz, K. Chem. Phys. 1993, 173, 275.
3. Ma, C.; Kwok, W. M.; Matoušek, P.; Parker, A. W.; Phillips, D.; Toner, W. T.; Towrie, M. J. Phys. Chem. A 2001, 105, 4648.
4. Ma, C.; Kwok, W. M.; Matousek, P.; Parker, A. W.; Phillips, D.; Toner, W. T.; Towrie, M. J. Photochem. Photobiol. A: Chem. 2001, 142, 177.
5. Xu, X.; Cao, Z.; Zhang, Q. J. Chem. Phys. 2005, 122, 194305.
6. Hashimoto, M.; Hamaguchi, H.-O. J. Phys. Chem. 1995, 99, 7875.
7. Chattopadhyay, N.; Serpa, C.; Arnaut, L. G.; Formosinho, S. J. Helv. Chim. Acta 2002, 85, 19.
8. The authors in ref 7 claim that they succeeded in freezing the molecular structure of the triplet state of DMABN during its submicrosecond lifetime (ref 6) by quickly immersing the DMABN solution into liquid nitrogen.
9. Visser, R. J.; Varma, C. A. G. O. J. Chem. Soc., Faraday Trans. 2 1980, 76, 453.
10. Druzhinin, S. I.; Demeter, A.; Galievsky, V. A.; Yoshihara, T.; Zachariasse, K. A. J. Phys. Chem. A 2003, 107, 8075.
11. Yoshizawa, T.; Iwaki, Y.; Osaka, N.; Nakabayashi, T.; Zachariasse, K. A.; Ohta, N. J. Phys. Chem. B 2004, 108, 19132.
12. Chattopadhyay, N.; Van der Auweraer, M.; De Schryver, F. C. Chem. Phys. Lett. 1997, 279, 303.
13. Suzuki, K.; Demeter, A.; Kühnle, W.; Tauer, E.; Zachariasse, K. A.; Tobita, S.; Shizuka, H. Phys. Chem. Chem. Phys. 2000, 2, 981.
14. Yoshihara, T.; Druzhinin, S. I.; Demeter, A.; Kocher, N.; Stalke, D.; Zachariasse, K. A. J. Phys. Chem. A 2005, 109, 1497.
15. Wintgens, V.; Valat, P.; Kossanyi, J.; Biczók, L.; Demeter, A.; Berces, T. J. Chem. Soc., Faraday Trans. 1994, 90, 411.
16. T(30) value: cyclohexane, 31.2; benzene, 34.5; 1,4-dioxane, 36.0. It follows from these data that 1,4-dioxane has the largest polarity of three solvents, between that of diethyl ether (34.6) and tetrahydrofuran (37.4). See ref 1 for a more detailed discussion, also based on the polarity dependence of the ICT emission maxima.
17. Ma, C.; Kwok, W. M.; Matousek, P.; Parker, A. W.; Phillips, D.; Toner, W. T.; Towrie, M. J. Phys. Chem. A 2002, 106, 3294.
18. Okamoto, H. J. Phys. Chem. A 2000, 104, 4182.
19. Okamoto, H.; Inishi, H.; Nakamura, Y.; Kohtani, S.; Nakagaki, R. J. Phys. Chem. A 2001, 105, 4182.
20. Zachariasse, K. A.; Grobys, M.; von der Haar, Th.; Hebecker, A.; Il'ichev, Yu. V.; Jiang, Y.-B.; Morawski, O.; Kühnle, W. J. Photochem. Photobiol. A: Chem. 1996, 102, 59.