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Volumn 47, Issue 3, 2008, Pages 775-777

A luminescent and magnetic cyano-bridged Tb3+-Mo5+ coordination polymer: Toward multifunctional materials

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EID: 39749127159     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic702192k     Document Type: Article
Times cited : (133)

References (53)
  • 7
    • 0034702246 scopus 로고    scopus 로고
    • (d) Barron, L. D. Nature 2000, 504, 895.
    • (2000) Nature , vol.504 , pp. 895
    • Barron, L.D.1
  • 44
    • 39749159065 scopus 로고    scopus 로고
    • 5Tb: C, 17.35; N, 20.25; Mo, 17.35; Tb, 28.75. Found: C, 17.61; N, 20.49; Mo, 17.01; Tb, 28.45.
    • 5Tb: C, 17.35; N, 20.25; Mo, 17.35; Tb, 28.75. Found: C, 17.61; N, 20.49; Mo, 17.01; Tb, 28.45.
  • 45
    • 39749159694 scopus 로고    scopus 로고
    • Crystal data for Tb(H2O)5[Mo(CN)8, C8H10MoN8O5Tb, M, 553.10, tetragonal, space group P4/nmm, Z, 2, a, 10.8912(2) Å, c, 7.1961-(2) Å, V, 853.59(3) Å3, μ(Mo Kα, 4.878 mm-1, Dc, 2.152 g cm-3. Independent reflections, 580 (Rint, 0.0305, Final R1, 0.0208 [I > 2σ(I, and wR2, 0.0560 all data, Data completeness to θ, 27.48°, 99.5, CCDC 660990
    • int = 0.0305). Final R1 = 0.0208 [I > 2σ(I)] and wR2 = 0.0560 (all data). Data completeness to θ = 27.48°, 99.5%. CCDC 660990.
  • 49
    • 39749200073 scopus 로고    scopus 로고
    • The photoluminescence spectra were recorded between 14 K and room temperature on a Fluorolog-3 model FL3-2T with a double excitation spectrometer and a single emission spectrometer (TRIAX 320) coupled to a R928 photomultiplier, using the front face acquisition mode. The excitation source was a 450 W xenon lamp. The lifetime measurements were acquired between 14 K and room temperature with the setup described for the luminescence spectra using a pulsed Xe-Hg lamp (6 μs pulse at half width and 20-30 μs tail).
    • The photoluminescence spectra were recorded between 14 K and room temperature on a Fluorolog-3 model FL3-2T with a double excitation spectrometer and a single emission spectrometer (TRIAX 320) coupled to a R928 photomultiplier, using the front face acquisition mode. The excitation source was a 450 W xenon lamp. The lifetime measurements were acquired between 14 K and room temperature with the setup described for the luminescence spectra using a pulsed Xe-Hg lamp (6 μs pulse at half width and 20-30 μs tail).
  • 52
    • 39749105272 scopus 로고    scopus 로고
    • Magnetic susceptibility data were collected with a Quantum Design MPMS-XL SQUID magnetometer. The data were corrected for the sample holder, and the diamagnetism contributions were calculated from Pascal's constants Theory and Applications of Molecular Paramagnetism; Boudreaux, E. A. L., Mulay, N., Eds.; John Wiley Sons: New York, 1976.
    • Magnetic susceptibility data were collected with a Quantum Design MPMS-XL SQUID magnetometer. The data were corrected for the sample holder, and the diamagnetism contributions were calculated from Pascal's constants (Theory and Applications of Molecular Paramagnetism; Boudreaux, E. A. L., Mulay, N., Eds.; John Wiley Sons: New York, 1976.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.