A general polymerization method using hydroalkoxylation and hydrocarboxylation reactions catalyzed by triflic acid

Macromolecules

Volumn 41, Issue 3, 2008, Pages 524-526

  Mathers, Robert T ^a   LeBlond, Carl ^b   Damodaran, Krishnan ^c   Kushner, Douglas I ^a   Schram, Valerie A ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

^b INDIANA UNIVERSITY OF PENNSYLVANIA   (United States)

^c UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROCARBOXYLATION REACTIONS; TRIFLIC ACID (TFOH); WEIGHT-AVERAGE MOLECULAR WEIGHT;

CARBOXYLATION; CATALYST ACTIVITY; DECOMPOSITION; POLYMERIZATION; REACTION RATES; THERMODYNAMIC STABILITY;

SULFURIC ACID;

EID: 39749117441     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma7022183     Document Type: Article

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25. In addition to the possible exo and endo sequences, the microstructure for the polymerization of 5-norbornene-2-carboxylic acid also contains 2,5- and 2,6-linkages. The estimated ratio of 2,5-exo/exo and 2,6-exo/exo:2,5-endo/exo and 2,5-exo/endo:2,6-endo/exo and 2,6-exo/endo:2,6-endo/endo and 2,5-endo/endo was 1.0:0.95:0.3:0.04. See Supporting Information for more details.
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