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Volumn 47, Issue 3, 2008, Pages 766-768

Many faces of dipyrrins: From hydrogen-bonded networks to homo- and heteronuclear metallamacrocycles

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EID: 39749106003     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic701949k     Document Type: Article
Times cited : (67)

References (37)
  • 23
    • 39749131584 scopus 로고    scopus 로고
    • Salt 2: To a solution of 1 (0.08 g 0.32 mmol) in CH2Cl2 (20 mL) was added HOTf (28 μL, 0.32 mmol) in CH2Cl2 (20 mL, After stirring for 20 min at room temperature, the solvent was evaporated under reduced pressure to afford a dark residue in quantitative yield. Dark-red crystals were grown by slow diffusion of diethyl ether vapor into a CHCl3 solution of the compound. 1H NMR (300 MHz, acetone-d6, δ 7.00 (br s, 2H, 7.89 (d, J, 8.4 Hz, 2H, 8.06 (d, J, 8.5 Hz, 2H, 8.30 (br s, 2H, 13C NMR (75 MHz, CDCl3, δ 110.7, 116.0, 117.7, 119.7, 126.7, 129.3, 132.3, 132.6, 133.9, 143.9, 149.9. 19F NMR (280 MHz, acetone-d6, δ -79.3. IR (KBr/cm -1, νCN 2242, b) Complex 4: A 1.75 mM solution of 1 in benzene (0.5 mL) was combined with a 1.75 mM solution of AgBF4 in
    • 2: C, 42.00; H, 3.01; N, 8.64. Found: C, 39.92; H, 2.96; N, 8.33.
  • 24
    • 39749172323 scopus 로고    scopus 로고
    • Crystal data for 2 (C17H12F 3N3O3S, MW, 395.36, monoclinic, P21/c, a, 10.0624(6) Å, b, 10.3247(6) Å, c, 16.6996(9) Å, β, 91.463(2)°, V, 1734.2(2) Å3, Z, 4, Dcalc, 1.514, T, 173(2) K, μ, 0.241 mm-1, 15 368 reflns measd, 3972 unique refins (Rint, 0.0344, R, 0.0431 [I > 2σ(I, Rw, 0.1279 (for all data, b) Crystal data for 4 (C32H 22Ag2B2F8N6, MW, 879.92, triclinic, P1, a, 9.9210(6) Å, b, 10.0826(4) Å, c, 10.1108(4) Å, α, 118.576(2)°, β, 100.160(3)°, γ, 108.078(3)°, V, 777.79(6) Å3
    • 2 using SHELXL-97. The H atoms were introduced at calculated positions and not refined (riding model).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.