Kinetic study and modeling of peroxypropionic acid synthesis from propionic acid and hydrogen peroxide using homogeneous catalysts

Industrial and Engineering Chemistry Research

Volumn 47, Issue 3, 2008, Pages 656-664

  Leveneur, Sébastien ^a,b   Salmi, Tapio ^a   Murzin, Dmitry Yu ^a   Estel, Lionel ^b   Wärnå, Johan ^a   Musakka, Niko ^a  

^a ÅBO AKADEMI UNIVERSITY   (Finland)

^b Laboratoire de Sécurité des Procédés Chimiques LSPC INSA Rouen Avenue de l'Université   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CONCENTRATION (PROCESS); ELECTROLYTES; HYDROGEN PEROXIDE; REACTION KINETICS; REGRESSION ANALYSIS; SULFURIC ACID;

HOMOGENEOUS CATALYSTS; PEROXYPROPIONIC ACID; PROPIONIC ACID;

ORGANIC ACIDS;

CONCENTRATION (PROCESS); ELECTROLYTES; HYDROGEN PEROXIDE; ORGANIC ACIDS; REACTION KINETICS; REGRESSION ANALYSIS; SULFURIC ACID;

EID: 39449125903     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie070670e     Document Type: Article

References (12)

1. D'Ans, J.; Frey, W. Untersuchungen über die Bildung von Persäuren aus Organischen Säuren und Hydroperoxyd. Z. Anorg. Chem. 1914, 84, 145.
2. Swern, D. Organic Peroxides; Wiley-Interscience: New York, 1970.
3. Greenspan, F. P.; MacKellar, D. G. Analysis of Aliphatic Peracids. Anal. Chem. 1948, 20, 1061.
4. Prescher, G. Process for the Preparation of Perpropionic Acid Solutions. U.S. Patent 4,088,679, 1978.
5. Dul'neva, L. V.; Moskvin, A. V. Kinetics of Formation of Peroxyacetic Acid. Russ. J. Gen. Chem. 2005, 75, 1125.
6. Mohammed, F. O.; Pines, D.; Dreyer, J.; Pines, E.; Nibbering, E. T. J. Sequential Proton Transfer Through Water Bridges in Acid-Base Reactions. Science 2005, 310, 83.
7. Knopf, D. A.; Luo, B. P.; Krieger, U. K.; Koop, T. Thermodynamic Dissociation Constant of the Bisulfate Ion from Raman and Ion Interaction Modeling Studies of Aqueous Sulfuric Acid at Low Temperatures. J. Phys. Chem. A 2003, 107, 4322.
8. Sue, K.; Ouchi, F.; Minami, K.; Arai, K. Determination of Carboxylic Acid Dissociation Constants to 350°C at 23MPa by Potentiometric pH Measurements. J. Chem. Eng. Data. 2004, 49, 1359.
9. Ogata, Y.; Sawaki, Y. Kinetics of the Acid-Catalysed Formation of Aliphatic Peracids from Hydrogen Peroxide and Aliphatic Acids in Dioxin. Tetrahedron 1965, 21, 3381.
10. Haario, H. MODEST-User's Guide; Profmath Oy: Helsinki 1994.
11. Lide, D. R. CRC Handbook of Chemistry and Physics, 75th edition; CRC Press: Boca Raton, FL, 1995.
12. Havel, S.; Greschner, J. Explosion Properties of Peroxyacetic Acid. I. Thermodynamic Calculation of the Explosion Characteristics of Peroxyacetic Acid. Chem. Prum. 1966, 16, 73.