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Volumn 14, Issue 4, 2008, Pages 1164-1168

Huge deuterated effect on permittivity in a metal-organic framework

Author keywords

Dielectric response; Ferroelectricity; Isotope effects; Metal organic frameworks; Zinc

Indexed keywords

CARBOXYLIC ACIDS; COORDINATION REACTIONS; FERROELECTRICITY; HEAT TREATMENT; ISOTOPES; ZINC;

EID: 38949150414     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200701044     Document Type: Article
Times cited : (46)

References (48)
  • 37
    • 38949124104 scopus 로고    scopus 로고
    • Crystal data for 1: C20H2KBr2NO 7Zn, M, 619.62, monoclinic, P2j; a, 9.5711(8, b, 12.0486(10, c= 11.1972(9) Å α, γ, 90, β= 98.4(2)°; V, 1277.39(18) Å Z, 2; ρcald, 1.611 mgm-5; R1, 0.0499, wR2, 0.0982; μ, 4.126 mm1; S, 1.015; Flack value, 0.032(13, Crystal data for 2: C20H22D 6Br2NO7Zn, M, 625.66, monoclinic, P2 1; a, 9.5650(9, b, 12.0392(11, c, 11.1973(10) Å α, γ, 90, β, 98.44(2)°; V, 1275.5(2) Å3; Z, 2; ρcald, 1.629mgm-3; R1, 0.0543, wR 2, 0.1072; μ, 4.133 mm-1; S, 1.056; Flack value, 0.025(17, The structures were solved with direct methods using the program SHELXTL Sheldrick. 1997, ref, 13, All non-hydrogen atoms were located from the trial
    • -1; S = 1.056; Flack value = 0.025(17); The structures were solved with direct methods using the program SHELXTL (Sheldrick. 1997, ref. [13]). All non-hydrogen atoms were located from the trial structure and refined anisotropically with SHELXTL by using the full-matrix least-squares procedure. The hydrogen atom positions were fixed geometrically at calculated distances and allowed to ride on the parent carbon atoms. The final difference Fourier map was found to be featureless. CCDC 606407 (1) and 606408 (2) contain the supplementary crystallography data for this paper. These data can be obtained free of charge from The Cambridge Crystallography Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
  • 46
    • 38949185389 scopus 로고    scopus 로고
    • Sheldrick, G. M. (1997). SHELXTL V5.1 Software, Bruker AXS, Madison, Wisconsin, USA.
    • Sheldrick, G. M. (1997). SHELXTL V5.1 Software, Bruker AXS, Madison, Wisconsin, USA.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.