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This process has also been alternatively described as concurrent tandem catalysis (ref 6a, tandem orthogonal catalysis (ref 6b, or cooperative sequential multicatalysis ref 6c
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This process has also been alternatively described as concurrent tandem catalysis (ref 6a), tandem orthogonal catalysis (ref 6b), or cooperative sequential multicatalysis (ref 6c).
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25
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The Tsuji-Trost reaction and related carbon-carbon formation reaction
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3, and 5 mol % of Grubbs' catalyst second generation or Hoveyda-Grubbs' catalyst. These conditions allow a limited (57%) conversion of the tandem isomerization/RCM. See: (a) Braddock, D. C.; Wildsmith, A. J. Tetrahedron Lett. 2001, 42, 3239- 3242.
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3, and 5 mol % of Grubbs' catalyst second generation or Hoveyda-Grubbs' catalyst. These conditions allow a limited (57%) conversion of the tandem isomerization/RCM. See: (a) Braddock, D. C.; Wildsmith, A. J. Tetrahedron Lett. 2001, 42, 3239- 3242.
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30
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35248813310
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A reverse one-pot sequence, Ru-catalyzed cross metathesis/Pd-catalyzed allylic carbonate reduction has been recently reported by Comins et al. In this sequence, the second catalytic system is added after completion of the first step, yielding a product in 65-85% yield. Comins, D. L.; Dinsmore, J. M.; Marks, L. R. Chem. Commun. 2007, 4170-4171.
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A reverse one-pot sequence, Ru-catalyzed cross metathesis/Pd-catalyzed allylic carbonate reduction has been recently reported by Comins et al. In this sequence, the second catalytic system is added after completion of the first step, yielding a product in 65-85% yield. Comins, D. L.; Dinsmore, J. M.; Marks, L. R. Chem. Commun. 2007, 4170-4171.
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Ruthenium-catalyzed allylic alkylation is a well-known process see
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Ruthenium-catalyzed allylic alkylation is a well-known process see: Trost, B. M.; Toste, F. D.; Pinkerton, A. B. Chem. Rev. 2001, 101, 2067-2096.
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