Copper(II) bromide catalyzed novel preparation of propargylic ethers and sulfides by SN1-type substitution between propargylic alcohols and alcohols or thiols

Synthesis

Volumn , Issue 2, 2008, Pages 191-196

  Hui, Hao Hao ^a   Zhao, Qin ^a   Yang, Ming Yu ^a   She, De Bing ^a   Chen, Min ^a   Huang, Guo Sheng ^a  

^a LANZHOU UNIVERSITY   (China)

Author keywords

Alcohols; Etherification; Nucleophilic substitution; Propargylic ethers; Thiols

Indexed keywords

COPPER BROMIDE; ETHERIFICATION; NUCLEOPHILIC SUBSTITUTION; PRODUCT YIELDS; PROPARGYLIC ALCOHOLS; PROPARGYLIC ETHERS;

ALCOHOLS; COPPER COMPOUNDS; NUCLEOPHILES;

ETHERS;

(3 ISOPROPOXY 3 METHYLBUT 1 YN 1 YL)BENZENE; 1 (1 BENZYLOXY CYCLOHEXYL) 2 PHENYLETHYNE; 1 (1 CYCLOHEXYLSULFANYLCYCLOHEXYL) 2 PHENYLETHYNE; 1 (1 ETHOXYCYCLOHEXYL) 2 PHENYLETHYNE; 1 (1 ISOPROPOXYCYCLOHEXYL) 2 PHENYLETHYNE; 1 (2 ACETOXYPHENYL) 3 ETHOXY 3 METHYLBUT 1 YNE; 1 (2 CHLOROETHOXY) 1,1,3 TRIPHENYLPROP 1 YNE; 1 [1 (2 CHLOROETHOXY)CYCLOHEXYL] 2 PHENYLETHYNE; 1 [1 ETHYLSULFANYLCYCLOHEXYL] 2 PHENYLETHYNE; 3 BENZYLOXY 1,3,3 TRIPHENYLPROP 1 YNE; 3 BENZYLOXY 3 METHYL 1 PHENYLBUT 1 YNE; 3 CYCLOHEXYSULFANYL 3 METHYL 1 PHENYLBUT 1 YNE; 3 ETHOXY 3 METHYL 1 PHENYLBUT 1 YNE; 3 ETHYLSULFANYL 3 METHYL 1 PHENYLBUT 1 YNE; 3 METHYL 1 PHENYL 3 (2 SULFANYLETHOXY)BUT 1 YNE; [3 (2 CHLOROETHOXY) 3 METHYLBUT 1 YN 1 YL]BENZENE; ALCOHOL DERIVATIVE; CARBON; CUPRIC BROMIDE; CUPRIC ION; ETHER DERIVATIVE; SULFIDE; THIOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL BOND; CHEMICAL STRUCTURE; ETHERIFICATION; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOCHEMISTRY; SUBSTITUTION REACTION;

EID: 38849201034     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-990951     Document Type: Article

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