Stereoselective construction of the tricyclic core of neoliacinic acid

Journal of Organic Chemistry

Volumn 73, Issue 3, 2008, Pages 1040-1055

  Clark, J Stephen ^a   Baxter, Carl A ^b   Dossetter, Alexander G ^b   Poigny, Stéphane ^b   Castro, José L ^c,d   Whittingham, William G ^e  

^a UNIVERSITY OF GLASGOW   (United Kingdom)

^b UNIVERSITY OF NOTTINGHAM   (United Kingdom)

^c NEUROSCIENCE RESEARCH CENTRE   (United Kingdom)

^d GLAXOSMITHKLINE   (United Kingdom)

^e JEALOTT S HILL INTERNATIONAL RESEARCH CENTRE   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

LACTONE PORTION; NEOLIACINIC ACIDS;

BIOSYNTHESIS; ETHERS; PLANTS (BOTANY); REACTION KINETICS; STEREOSELECTIVITY;

CARBOXYLIC ACIDS;

CARBENOID; CARBOXYLIC ACID; EPOXIDE; LACTONE; NEOLIACINIC ACID; SESQUITERPENE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; DRUG STRUCTURE; DRUG SYNTHESIS; RING OPENING; STEREOCHEMISTRY;

AZO COMPOUNDS; BIOLOGICAL PRODUCTS; BROMIDES; CATALYSIS; CYCLIZATION; ESTERIFICATION; ETHER, ETHYL; HETEROCYCLIC COMPOUNDS, 3-RING; KETONES; LACTONES; MAGNETIC RESONANCE SPECTROSCOPY; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PROPANOLS; STEREOISOMERISM;

EID: 38849189399     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo702111u     Document Type: Article

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67. 4). The solvent was removed at water pump pressure on a rotary evaporator behind a blast screen. The solid m-chloroperbenzoic acid was used without recrystallization.