Ethanol steam reforming in a dense Pd-Ag membrane reactor: A modelling work. Comparison with the traditional system

International Journal of Hydrogen Energy

Volumn 33, Issue 2, 2008, Pages 644-651

  Gallucci, F ^a   De Falco, M ^b   Tosti, S ^c   Marrelli, L ^b   Basile, A ^a  

^a UNIVERSITY OF CALABRIA   (Italy)

^b SAPIENZA UNIVERSITY OF ROME   (Italy)

^c ENEA   (Italy)

Author keywords

Ethanol steam reforming; Hydrogen production; Membrane reactor; Modelling; Pd membranes

Indexed keywords

HYDROGEN PRODUCTION; MATHEMATICAL MODELS; REFORMING REACTIONS; STEAM;

ETHANOL STEAM REFORMING; MEMBRANE REACTORS; PD MEMBRANES;

ETHANOL;

EID: 38849153566     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2007.10.039     Document Type: Article

References (28)

1. de Wild P.J., and Verhaak M.J.F.M. Catalytic production of hydrogen from methanol. Catal Today 60 (2000) 3-10
2. Wiese W., Emonts B., and Peters R. Methanol steam reforming in a fuel cell drive system. J Power Source 84 (1999) 187-193
3. Breen J.P., Burch R., and Coleman H.M. Metal-catalysed steam reforming of ethanol in the production of hydrogen for fuel cell applications. Appl Catal B: Environ 39 (2002) 65-74
4. 3 catalyst. J Power Source 123 (2003) 10-16
5. Maggio G., Freni S., and Cavallaro S. Light alcohols/methane fuelled molten carbonate fuel cells: a comparative study. J Power Source 74 (1998) 17-23
6. Heinzel A., Vogel B., and Hubner P. Reforming of natural gas-hydrogen generation for small scale stationary fuel cell systems. J Power Source 105 (2002) 202-207
7. 2 production for fuel cells. Catal Today 77 (2002) 89-98
8. Lindstrom B., and Pettersson L.J. Hydrogen generation by steam reforming of methanol over copper-based catalysts for fuel cell applications. Int J Hydrogen Energy 26 (2001) 923-933
9. K Liguras D., Kondarides D.I., and Verykios X.E. Production of hydrogen for fuel cells by steam reforming of ethanol over supported noble metal catalysts. Appl Catal 43 (2003) 345-354
10. Freni S., Mondello N., Cavallaro S., Cacciola G., Pardon V.N., and Sobyanin V.A. Hydrogen production by steam reforming of ethanol: a two process. React Kinet Catal Lett 71 (2000) 143-152
11. 2 catalysts for steam reforming of ethanol. Appl Catal 246 (2003) 323-334
12. Llorca J., Homs N., Sales J., and de la Piscina P.R. Efficient production of hydrogen over supported cobalt catalysts from ethanol steam reforming. J Catal 209 (2002) 306-317
13. Haga F., Nakajima T., Yamashita K., and Mishima S. Effect of crystallite size on the catalysis of alumina-supported cobalt catalyst for steam reforming of ethanol. React Kinet Catal Lett 63 (1998) 253-259
14. 3 catalysts used for ethanol steam reforming. Catal Commun 5 (2004) 339-345
15. Shu J., Grandjean B.P.A., Van Neste A., and Kalaguine S. Catalytic palladium-based membrane reactors: a review. Can J Chem Eng 69 (1991) 1036-1060
16. Kikuchi E. Membrane reactor application to hydrogen production. Catal Today 56 (2000) 97-101
17. Armor J.N. Applications of catalytic inorganic membrane reactors to refinery products. J Membr Sci 147 (1998) 217-233
18. Paturzo L., Basile A., and Drioli E. High temperature membrane reactors and integrated membrane operations. Rev Chem Eng 18 6 (2002) 511-551
19. Tosti S., Basile A., Bettinali L., Borgognoni F., Chiaravalloti F., and Gallucci F. Long-term tests of Pd-Ag thin wall permeator tube. J Membr Sci 284 (2006) 393-397
20. Wieland S., Melin T., and Lamm A. Membrane reactors for hydrogen production. Chem Eng Sci 57 (2002) 1571-1576
21. Amandusson H., Ekedahl L.G., and Dannetun H. Alcohol dehydrogenation over Pd versus PdAg membranes. Appl Catal A: Gen 217 (2001) 157-164
22. Basile A., Gallucci F., and Paturzo L. A dense Pd/Ag membrane reactor for methanol steam reforming: experimental study. Catal Today 104 (2005) 244-250
23. Basile A., Gallucci F., and Paturzo L. Hydrogen production from methanol by oxidative steam reforming carried out in a membrane reactor. Catal Today 104 (2005) 251-259
24. Basile A., Tosti S., Capannelli G., Vitulli G., Iulianelli A., Gallucci F., et al. Co-current and counter-current modes for methanol steam reforming membrane reactor: experimental study. Catal Today 118 (2006) 237-245
25. Gallucci F., Basile A., Tosti S., Iulianelli A., and Drioli E. Methanol steam reforming and ethanol steam reforming in membrane reactors: an experimental study. Int J Hydrogen Energy 32 9 (2007) 1201-1210
26. Gallucci F., Paturzo L., and Basile A. Hydrogen recovery from methanol steam reforming in a dense membrane reactor: simulation study. Ind Eng Chem Res 43 (2004) 2420-2432
27. Gallucci F., and Basile A. Co-current and counter-current modes for methanol steam reforming membrane reactor. Int J Hydrogen Energy 31 (2006) 2243-2249
28. 3 catalyst. Chem Eng J 125 3 (2007) 139-147