Kinetics of natural oxidant demand by permanganate in aquifer solids

Journal of Contaminant Hydrology

Volumn 96, Issue 1-4, 2008, Pages 187-194

  Urynowicz, Michael A ^a   Balu, Balamurali ^b   Udayasankar, Umamaheshwari ^a  

^a UNIVERSITY OF WYOMING   (United States)

^b Georgia Institute of Technology   (United States)

Author keywords

Kinetics; Natural oxidant demand; Permanganate

Indexed keywords

FIRST-ORDER KINETIC MODEL; NATURAL OXIDANT DEMAND; PERMANGANATE;

AQUIFERS; BIOLOGICAL MATERIALS; MANGANESE COMPOUNDS; MATHEMATICAL MODELS; ORGANIC CARBON; REACTION KINETICS; SEPARATION;

OXIDANTS;

MANGANESE DERIVATIVE; NATURAL ORGANIC MATTER; ORGANIC CARBON; OXIDIZING AGENT; PERMANGANATE; UNCLASSIFIED DRUG;

AQUIFERS; BIOLOGICAL MATERIALS; MANGANESE COMPOUNDS; MATHEMATICAL MODELS; ORGANIC CARBON; OXIDANTS; REACTION KINETICS; SEPARATION;

AQUIFER; KINETICS; ORGANIC CARBON; OXIDANT; OXIDATION;

AQUIFER; ARTICLE; CHEMICAL REACTION; COMPOSITE MATERIAL; DISPERSION; KINETICS; OXIDATION; PERMEABILITY; PRIORITY JOURNAL;

CARBON; KINETICS; MANGANESE COMPOUNDS; MODELS, CHEMICAL; OXIDANTS; OXIDES;

EID: 38749115388     PISSN: 01697722     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jconhyd.2007.11.001     Document Type: Article

References (26)

1. Barcelona M.J., and Holm T.R. Oxidation-reduction capacities of aquifer solids. Environ. Sci. Technol. 25 (1991) 1565-1572
2. Dresher E., Gavasker A.R., Sass B.M., Cumming L.J., Dresher M.J., and Williamson T.K.J. Batch and column testing to evaluate chemical oxidation of DNAPL source zones. Proc. from the 1st Intern. Conf. on Remediation of Chlorinated and Recalcitrant Compounds (1998), Battelle, Monterey, CA
3. Hatcher P.G., Dennis S.M., and Maciel G.E. Aromaticity of humic substances. Soil Sci. Soc. 45 (1981) 1089-1094
4. Hønning J., Broholm M.M., and Larsen T.H. Oxidation kinetics and consumption of potassium permanganate in moraine clay. 3rd Intern. Conf. on Oxidation and Reduction Technologies for In-Situ Treatment of Soil and Groundwater (ORT-3), San Diego, CA (2004)
5. Hønning J., Broholm M.M., and Bjerg P.L. Quantification of potassium permanganate consumption and PCE oxidation in subsurface materials. J. Contam. Hydrol. 90 (2007) 221-239
6. Huang K., Hoag G.A., Chheda P., Woody B.A., and Dobbs G.M. Soil oxidant demand during chemical oxidation of trichloroethylene by permanganate in soil media. Hazard. Ind. Waste 32 (2000) 617-626
7. In: Khan S.U., and Schnitzer M. (Eds). Soil Organic Matter (1978), Elsevier Scientific Publishing Company, New York 27-58
8. Malcolm, R.L. and MacCarthy, P. 1986. Limitations in the use of commercial humic acids. Water and Soil Research. Environ. Sci. Tech., 20, 904-911.
9. 4 oxidation. Wat. Res. 26 (1992) 1471-1478
10. Matsuda K., and Schnitzer M. The permanganate oxidation of humic acids extracted from acid soils. Soil Sci. 114 (1971) 185-193
11. Mumford K.G., Thomson N.R., and Allen-King R.M. Investigating the kinetic nature of natural oxidant demand during ISCO. Proc. from the 3rd International Conf. on Remediation of Chlorinated and Recalcitrant Compounds (2002), Batelle, Monterey, Ca
12. Mumford K.G., Thomson N.R., and Allen-King R.M. Bench-scale investigation of permanganate natural oxidant demand kinetics. Environ. Sci. Technol. 39 (2005) 2835-2840
13. Nelson D.W., and Sommers L.E. Total carbon, organic carbon, and organic matter. In: Page A.L., et al. (Ed). Methods of Soil Analysis, Part 2. 2nd ed. Agronomy vol. 9 (1982), Am. Soc. Of Agron., Inc, Madison, WI 961-1010
14. Plechanov N. Studies of molecular weight distributions of fulvic and humic acids by gel permeation chromatography. Examination of the solute molecular composition using RI, UV, fluorescence, and weight measurement as detection techniques. Org. Geochem. 5 (1983) 143-149
15. Sanchez-Monedero M.A., Cegarra J., Garcia D., and Roig A. Chemical composition and structure of humic acids during organic waste composting. Biodegradation 13 (2002) 361-371
16. Serra M.I.O., and Schnitzer M. The chemistry of humic and fulvic acids extracted from argentine soils - I. Analytical characteristics. Soil Biol. Biochem. 5 (1972) 281-286
17. Siegrist R.L., Lowe K.S., Murdoch L.C., Case T.L., and Pickering D.A. In situ oxidation by fracture emplaced reactive solids. J. Environ. Eng. 125 5 (1999) 429-440
18. Siegrist R.L., Urynowicz M.A., West O.R., Crimi M.L., and Lowe K.S. Principles and practices of in situ chemical oxidation using permanganate (2001), Battelle, Columbus, OH
19. Stevenson F.J. Humus chemistry (1982), John Wiley and Sons, New York
20. In: Aiken G.R., McKnight D.M., Wershaw R.L., and Macarthy P. (Eds). Humic Substances in Soil, Sediment, and Water (1985), John Wiley and Sons, New York
21. Struse A.M., Siegrist R.L., Dawson H.E., and Urynowicz M.A. Diffusive transport of permanganate during in situ oxidation. J. Environ. Eng. 128 4 (2002) 327-334
22. Stumm W., and Morgan J.J. Aquatic chemistry: Chemical equilibria and rates in natural waters (1996), John Wiley & Sons, New York
23. Underdown A.W., and Gamble D.S. Light scattering of polydisperse fulvic acids. Anal. Chem. 53 (1981) 2139-2140
24. USEPA field applications of in situ remediation technologies: Chemical oxidation. 1998. EPA542-R-98-008.
25. Walkley A., and Black I.A. An examination of the Degtjareff method for determining soil organic matter and a proposed modification of the chromic acid titration method. Soil Sci. 37 (1943) 29-38
26. Yan Y.E., and Schwartz F.W. Oxidative degradation and kinetics of chlorinated ethylenes by potassium permanganate. J. Contam. Hydrol. 37 (1999) 343-365