Kinetics of sulfite oxidation in wet desulfurization with catalyst of organic acid

Chemical Engineering Journal

Volumn 136, Issue 2-3, 2008, Pages 221-226

  Wang, Lidong ^a   Zhao, Yi ^a  

^a NORTH CHINA ELECTRIC POWER UNIVERSITY   (China)

Author keywords

Catalyze; Kinetics; Oxidation; Peracetic acid; Sulfite; Wet desulfurization

Indexed keywords

ACTIVATION ENERGY; CATALYST ACTIVITY; DESULFURIZATION; OXIDATION; PH; REACTION KINETICS;

SODIUM SULFITE CATALYZED; SULFITE OXIDATION; WET DESULFURIZATION;

ORGANIC ACIDS;

ACTIVATION ENERGY; CATALYST ACTIVITY; DESULFURIZATION; ORGANIC ACIDS; OXIDATION; PH; REACTION KINETICS;

EID: 38649122025     PISSN: 13858947     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cej.2007.04.004     Document Type: Article

References (17)

1. Lancia A., Musmarra D., and Pepe F. Uncatalyzed heterogeneous oxidation of calcium bisulfite. Chem. Eng. Sci. 51 (1996) 3889-3896
2. Zhong Q. Study on uncatalyzed calcium sulfite oxidation kinetics. J. Nanjing Univ. Sci. Technol. 24 (2000) 172-176 (in Chinese)
3. Du Q., Wu S.H., and Zhu Q.Y. Non-catalytic oxidation kinetics of calcium sulfite in wet limestone-gypsum FGD process. J. Chem. Ind. Eng. 54 (2003) 1490-1493 (in Chinese)
4. Delplancq E., Casti P., and Vanderschuren J. Kinetics of oxidation of calcium sulphite slurries in aerated stirred tank reactors. Chem. Eng. Res. Des. 70 (1992) 291-295
5. Zhao Y., Wang L.D., and Wang X.M. Study on the macroscopical uncatalyzed oxidation kinetics of desulfurization residual product-calcium sulfite. Proc. Chin. Soc. Electr. Eng. 25 (2005) 116-120 (in Chinese)
6. Abdullah A.S., and Zaidi S.M.J. Kinetics of catalytic oxidation of aqueous sodium sulfite. React. Kinet. Catal. Lett. 64 (1998) 343-349
7. 2- oxidation by manganese ions. Kinet. Catal. 43 (2002) 249-260
8. Hjuler K., and Johansen K.D. Wet oxidation of residual product from spray absorption of sulphur dioxide. Chem. Eng. Sci. 49 (1994) 4515-4521
9. Du Q., Wu S.H., and Zhu Q.Y. Mn-catalyzed oxidation kinetics of calcium sulfite in wet FGD process. J. Harbin Inst. Technol. 36 (2004) 391-394 (in Chinese)
10. Barron C.H., and O'Hern H.A. Reaction kinetics of sodium sulfite oxidation by the rapid-mixing method. Chem. Eng. Sci. 21 (1966) 397-404
11. Bronlkowska W.P., Bronlkowskl T., and Ulejczyk M. Mechanism and kinetics of autoxidation of calcium sulfite slurries. Environ. Sci. Technol. 26 (1992) 1976-1981
12. Lente G., and Fabian I. Kinetics and mechanism of the oxidation of sulfur by iron at metal ion excess. J. Chem. Soc. Dalton. Trans. 5 (2002) 778-784
13. Vorbach M., Marr R., and Siebenhofer M. Catalytic oxidation of sulfite/bisulfite in a falling-film absorption column. Proceedings of the Third International Symposium on Reaction Kinetics and the Development and Operation of Catalytic Processes. Oostende, April 22-25 (2001) 575
14. Semler G.K., Marr R., and Siebenhofer M. Experimental investigation and modeling of catalytically supported sulfite /bisulfite oxidation with oxygen. Chem. Eng. Technol. 27 (2004) 630-633
15. Zhao Y., Wang L.D., and Wang X.M. Experimental study on effect of inhibitors on macroscopical oxidation kinetics of calcium sulfite. J. Environ. Sci. 17 (2005) 483-487
16. Xiang Y.Z., and Xia D.H. Decreasing olefin content in gasoline by hydrogen peroxide-organic acid. J. Univ. Pet. 29 (2005) 119-121 (in Chinese)
17. 3 system. Acta Chim. Sinica 58 (2000) 759-765 (in Chinese)