Molecular structure and properties of cellulose acetate chemically modified with caprolactone

European Polymer Journal

Volumn 44, Issue 2, 2008, Pages 357-365

  Számel, György ^a,b   Domján, Attila ^b   Klébert, Szilvia ^a,b   Pukánszky, Béla ^a,b  

^a BUDAPEST UNIVERSITY OF TECHNOLOGY AND ECONOMICS   (Hungary)

^b CHEMICAL RESEARCH CENTER   (Hungary)

Author keywords

Caprolactone; Cellulose acetate; Grafting; Mechanical properties; Molecular structure; Plasticization

Indexed keywords

CHEMICAL MODIFICATION; DYNAMIC MECHANICAL ANALYSIS; GRAFTING (CHEMICAL); HOMOPOLYMERIZATION; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

CAPROLACTONE; PLASTICIZATION;

CELLULOSE DERIVATIVES;

CELLULOSE ACETATE; CELLULOSE DERIVATIVES; COPOLYMERIZATION; MOLECULAR STRUCTURE;

EID: 38549153200     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2007.11.006     Document Type: Article

References (30)

1. Mohanty A.K., Misra M., and Hinrichsen G. Biofibres, biodegradable polymers and biocomposites: an overview. Macromol Mater Eng 276/277 1 (2000) 1-24
2. Bledzki A.K., and Gassan J. Composites reinforced with cellulose based fibres. Prog Polym Sci 24 2 (1999) 221-274
3. Zhang M.Q., Rong M.Z., and Lu X. Fully biodegradable natural fiber composites from renewable resources: all-plant fiber composites. Compos Sci Technol 65 15/16 (2005) 2514-2525
4. Schroeter J., and Felix F. Melting cellulose. Cellulose 12 2 (2005) 159-165
5. Heinze T., and Liebert T. Unconventional methods in cellulose functionalization. Prog Polym Sci 26 9 (2001) 1689-1762
6. Pereira R., Campana Filho S.P., and Curvelo A.A.S. Benzylated pulps from sugar cane bagasse. Cellulose 4 1 (1997) 21-31
7. Joly N., Granet R., Branland P., Verneuil B., and Krausz P. New methods for acylation of pure and sawdust-extracted cellulose by fatty acid derivatives - thermal and mechanical analyses of cellulose-based plastic films. J Appl Polym Sci 97 3 (2005) 1266-1278
8. Frisoni G., Baiardo M., and Scandola M. Natural cellulose fibers: heterogeneous acetylation kinetics and biodegradation behavior. Biomacromolecules 2 2 (2001) 476-482
9. Nishio Y. Material functionalization of cellulose and related polysaccharides via diverse microcompositions. Adv Polym Sci 205 1 (2006) 97-151
10. Hon D.N.S., and Ou N.H. Thermoplasticization of wood. I. Benzylation of wood. J Polym Sci Polym Chem 27 12 (1989) 2457-2482
11. Ma X.F., Yu J.G., and Kennedy J.F. Studies on the properties of natural fibers-reinforced thermoplastic starch composites. Carbohydr Polym 62 1 (2005) 19-24
12. Gomes M.E., Ribeiro A.S., Malafaya P.B., Reis R.L., and Cunha A.M. A new approach based on injection moulding to produce biodegradable starch-based polymeric scaffolds: morphology, mechanical and degradation behaviour. Biomaterials 22 9 (2001) 883-889
13. Mayumi A., Kitaoka T., and Wariishi H. Partial substitution of cellulose by ring-opening esterification of cyclic esters in a homogeneous system. J Appl Polym Sci 102 5 (2006) 4358-4364
14. Lee S.H., and Shiraishi N. Plasticization of cellulose diacetate by reaction with maleic anhydride, glycerol, and citrate esters during melt processing. J Appl Polym Sci 81 1 (2001) 243-250
15. Yoshioka M., Hagiwara N., and Shiraishi N. Thermoplasticization of cellulose acetates by grafting of cyclic esters. Cellulose 6 3 (1999) 193-212
16. Hatakeyama H., Yoshida T., and Hatakeyama T. The effect of side chain association on thermal and viscoelastic properties cellulose acetate based polycaprolactones. J Therm Anal Calorim 59 1/2 (2000) 157-168
17. Guruprasad K.H., and Shashidhara G.M. Grafting, blending, and biodegradability of cellulose acetate. J Appl Polym Sci 91 3 (2004) 1716-1723
18. Warth H., Mülhaupt R., and Schätzle J. Thermoplastic cellulose acetate and cellulose acetate compounds prepared by reactive processing. J Appl Polym Sci 64 2 (1997) 231-242
19. Teramoto Y., Ama S., Higeshiro T., and Nishio Y. Cellulose acetate-graft-poly(hydroxyalkanoate)s: synthesis and dependence of the thermal properties on copolymer composition. Macromol Chem Phys 205 14 (2004) 1904-1915
20. Teramoto Y., Yoshioka M., Shiraishi N., and Nishio Y. Plasticization of cellulose diacetate by graft copolymerization of ε-caprolactone and lactic acid. J Appl Polym Sci 84 14 (2002) 2621-2628
21. Teramoto Y., and Nishio Y. Cellulose diacetate-graft-poly(lactic acid)s: synthesis of wide-ranging compositions and their thermal and mechanical properties. Polymer 44 9 (2003) 2701-2709
22. Simon J., Müller H.P., Koch R., and Müller V. Thermoplastic and biodegradable polymers of cellulose. Polym Degrad Stabil 59 1-3 (1998) 107-115
23. Vidéki B., Klébert S., and Pukánszky B. Grafting of caprolactone to cellulose acetate by reactive processing. Eur Polym J 41 8 (2005) 1699-1707
24. Buchanan C.M., Hyatt J.A., and Lowman D.W. Two-dimensional NMR of polysaccharides: spectral assignments of cellulose triesters. Macromolecules 20 11 (1987) 2750-2754
25. Flugge L.A., Blank J.T., and Petillo P.A. Isolation, modification, and NMR assignments of a series of cellulose oligomers. J Am Chem Soc 121 31 (1999) 7228-7238
26. Lee S.J., Altaner C., Puls J., and Saake B. Determination of the substituent distribution along cellulose acetate chains as revealed by enzymatic and chemical methods. Carbohydr Polym 54 3 (2003) 353-362
27. Shi R., and Burt H.M. Synthesis and characterization of amphiphilic hydroxypropylcellulose-graft-poly(ε-caprolactone). J Appl Polym Sci 89 3 (2003) 718-727
28. Heinze T., and Liebert T. Chemical characteristics of cellulose acetate. Macromol Symp 208 1 (2004) 167-237
29. Számel Gy, Klébert Sz, Sajó I, Pukánszky B. Thermal analysis of cellulose acetate modified with caprolactone. J Therm Anal Calorim, 2008;91. doi:10.1007/s10973-007-8684-5.
30. Vidéki B., Klébert S., and Pukánszky B. External and internal plasticization of cellulose acetate with caprolactone: structure and properties. J Polym Sci Polym Phys 45 8 (2007) 873-883