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24644495007
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note
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For representative examples of successful modifications of phosphite ligands for asymmetric catalysis, see refs. 2a,b,i and j.
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24
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39
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24644508224
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note
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The catalysts were prepared in situ during 16 h. In general, hydrogenated or polymerized products of styrene were not observed.
-
-
-
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40
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0034618483
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M. Diéguez, O. Pàmies, A. Ruiz, S. Castillón and C. Claver, Chem. Commun., 2000, 1607.
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41
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24644524901
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note
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Ligands 3d and 4d gave 52% (R) and 90% (S) ee at 20°C, respectively.
-
-
-
-
42
-
-
0034249672
-
-
Calculated from the HP-NMR data using the typical value of the cis and trans phophorus-proton coupling constants as in ref. 2f and P. W. N. M. van Leeuwen, P. C. J. Kamer, J. N. H. Reek and P. Dierkes, Chem. Rev., 2000, 100, 2741.
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43
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0001346731
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Recent mechanistic studies suggest that the enantioselectivity is determined during the insertion of the olefin into the Rh-H bond, see for example: (a) D. Gleich, R. Schmid and W. A. Herrmann, Organometallics, 1998, 17, 2141;
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24644522359
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4.
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47
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K. Selvakumar, M. Valentini, P. S. Pregosin and A. Albinati, Organometallics, 1999, 18, 4591.
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49
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24644505591
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note
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2 and the corresponding ligand and a catalytic amount of KOAc.
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52
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2042438523
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