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3843145196
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2) values of 0.0714 and 0.1851 for 293 parameters and 3521 unique reflections with I ≥ 2σ(I) and 0.1041 and 0.2118 for all 4896 reflections. The CCDC reference number is 212568 for 1.
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Absorption and emission spectra were recorded by a Hitachi (U-3310) spectrophotometer and an Edinburgh (FS920) fluorimeter, respectively. A configuration of front-face excitation was used to measure the emission of the single crystal. Lifetime studies were performed by an Edinburgh FL 900 photon-counting system. For phosphorescence measurements, a Nd:YAG (355 nm, 8 ns, Continuum Surlite 11) pumped optical parametric oscillator was used as an excitation source. The resulting luminescence was then detected by an intensified charge coupled detector.
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28
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3843125491
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n. Detailed structural characterization is in progress and will be elaborated in a full paper.
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