Preparation of alkyl nitrates, nitrites, and thiocyanates from alcohols utilizing trichloroisocyanuric acid with triphenylphosphine

Synthetic Communications

Volumn 34, Issue 14, 2004, Pages 2507-2511

  Hiegel, Gene A ^a   Nguyen, Jeremiah ^a   Zhou, Yan ^a  

^a CALIFORNIA STATE UNIVERSITY   (United States)

Author keywords

Alcohols; Alkyl nitrates; Alkyl nitrites; Alkyl thiocyanates; Preparation; Substitution; Synthesis; Trichloroisocyanuric acid; Triphenylphosphine

Indexed keywords

2 OCTANOL; ACETONITRILE; ALCOHOL DERIVATIVE; ALKYL GROUP; BENZYL ALCOHOL; CYANURIC ACID; CYCLOHEXANOL; NITRIC ACID DERIVATIVE; NITRITE; NONANOL; OCTANOL; SILVER DERIVATIVE; SILVER NITRATE; SILVER NITRITE; SYMCLOSENE; THIOCYANATE SODIUM; THIOCYANIC ACID DERIVATIVE; TRIPHENYLPHOSPHINE; UNCLASSIFIED DRUG;

ARTICLE; GAS CHROMATOGRAPHY; INFRARED SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; SUBSTITUTION REACTION; SYNTHESIS;

EID: 3843057831     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1081/SCC-200025580     Document Type: Article

References (5)

1. Hiegel, G.A.; Ramirez, J.; Barr, R.K. Chlorine substitution reactions using trichloroisocyanuric acid with triphenylphosphine. Synth. Commun. 1999, 29 (8), 1415-1419.
2. Hiegel, G.A.; Rubino, M. Conversion of alcohols into alkyl chlorides using trichloroisocyanuric acid with triphenylphosphine. Synth. Commun. 2002, 32 (17), 2691-2694.
3. Pattison, E.; Brown, G. Organic nitrates as synthetic reagents - preparations of nitrates and some representative reactions. Can. J. Chem. 1956, 34, 879-884.
4. Noyes, W.A. n-Butyl nitrite. In Organic Syntheses; Wiley: New York, 1943; Collect. Vol. II, 108-109.
5. Conley, R.T. Infrared Spectroscopy; Allyn and Bacon: Boston, 1966; 117.