Kinetics of the anionic ring opening polymerization of cyclosiloxanes initiated with a superbase

Journal of Inorganic and Organometallic Polymers and Materials

Volumn 14, Issue 2, 2004, Pages 85-99

  Grzelka, Agnieszka ^a   Chojnowski, Julian ^a   Fortuniak, Witold ^a   Taylor, Richard G ^b   Hupfield, Peter C ^b  

^a CENTRE OF MOLECULAR AND MACROMOLECULAR STUDIES   (Poland)

^b DOW CORNING LTD   (United Kingdom)

Author keywords

Anionic polymerization; Cyclosiloxanes; Octamethylcyclotetrasiloxane; Phosphazene base; Polysiloxanes; Ring opening polymerization

Indexed keywords

MONOMER; OLIGOMER; POLYSILOXANE; SILOXANE; TOLUENE;

ANION TRANSPORT; ARTICLE; CYCLIZATION; ENERGY TRANSFER; ENERGY YIELD; KINETICS; OLIGOMERIZATION; REACTION ANALYSIS; RING OPENING; RING OPENING METATHESIS POLYMERIZATION;

EID: 3843055005     PISSN: 15741443     EISSN: 15741451     Source Type: Journal    
DOI: 10.1023/b:joip.0000028088.53201.f7     Document Type: Article

References (18)

1. B. Hardman and A. Torkelson, in Encyclopedia of Polymer Science and Engineering, 2nd ed., H. F. Mark, N. M. Bikales, C. G. Overberger, and G. Menges, eds. (J. Wiley and Sons, New York, 1989), Vol. 15, p. 204.
2. H. H. Moretto, M. Schulze, and G. Wagner, in Ulmanns Encyclopedia of Industrial Chemistry, 5th ed. (Weinheim, 1993), Vol. A24, p. 57.
3. J. Chojnowski and M. Cypryk, in Silicon Containing Polymers, R. Jones, W. Ando, and J. Chojnowski, eds. (Kluwer Acad. Publ., Dordrecht, 2000), Chapt. 1, p. 3.
4. J. Chojnowski, J. Inorg. Organometal. Polym. 1, 299 (1991).
5. R. Schwesinger and H. Schlemper, Angew. Chem., Int. Ed. Engl. 26, 1167 (1987).
6. R. Schwesinger et al., Liebigs Ann. (1996) 1055.
7. A. Molenberg and M. Möller, Macromol. Chem. Rapid Commun. 16, 449 (1995).
8. B. Ebwein, A. Molenberg, and M. Möller, Macromol. Symp. 107, 331 (1996).
9. M. E. van Dyke, and S. J. Clarson, J. Inorg. Organometal. Polym. 8, 111 (1998).
10. P. C. Hupfield and R. G. Taylor, J. Inorg Organometal. Polym. 9, 17 (1999).
11. A. Grzelka, J. Chojnowski, M. Cypryk, W. Fortuniak, P. C. Hupfield, and R. G. Taylor, J. Organometal. Chem. 660, 14 (2002).
12. A. Molenberg and M. Möller, Macromol. Chem. Phys. 198, 717 (1997).
13. D. Bougard, C. Bremard, R. D. Jueger, and Y. Lemmouchi, Phosphorus Sulfur Silicon 79, 147 (1993).
14. R. Link and R. Schwesinger, Angew. Chem. Int. Ed. Engl. 31, 850 (1992).
15. Y. A. Yuzhelevskii, E. B. Dmokhovskaya, A. L. Klebanskii, and N. N. Kozlova, Vysokomol. Soedin. A11, 432 (1969).
16. M. G. Voronkov, V. P. Mileshkevitch, and Y. A. Yuzhelevskii, The Siloxane Bond (Consultant Bureau, New York, 1978).
17. Z. Laita and M. Jelinek, Vysokomol. Soedin. 4, 1793 (1962).
18. M. Mazurek and J. Chojnowski, Makromol. Chem. 178, 1005 (1977).