Host (nanocavity of zeolite-Y)/guest (12- and 14-membered azamacrocyclic Ni(II) complexes) nanocatalyst: Synthesis, characterization and catalytic oxidation of cyclohexene with molecular oxygen

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Volumn 60, Issue 1-2, 2008, Pages 145-152

  Salavati Niasari, Masoud ^a   Abdolmohammadi, Shahrzad ^b  

^a UNIVERSITY OF KASHAN   (Iran)

^b UNIVERSITY OF TEHRAN   (Iran)

Author keywords

Azamacrocycle; Nanocatalyst; Nanopores; Nickel(II); Oxidation

Indexed keywords

EID: 38349187582     PISSN: 09230750     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10847-007-9363-7     Document Type: Article

References (36)

1. Somorjai, G.A., Borodko, Y.G.: Research in nanosciences - great opportunity for catalysis science. Catal. Lett. 76, 1-5 (2001).
2. Kung, H.H., Kung, M.C.: Heterogeneous catalysis: what lies ahead in nanotechnology. Appl. Catal. A: Gen. 246, 193-196 (2003).
3. Schuth, F., Sing K., Weitkamp J. (eds.): Handbook of Porous Solids, vol. I-V. Wiley-VCH, Weinheim (2002) and references therein.
4. Cheetham, A.K., Ferey, G., Loiseau, T.: Open-framework inorganic materials. Angew. Chem. Int. Ed. 38, 3268-3292 (1999).
5. Ganesan, R., Viswanathan, B.: Redox properties of bis(8-hydroxyquinoline) manganese(II) encapsulated in various zeolites. J. Mol. Catal. A: Chem. 223, 21-29 (2004).
6. Tsou, J., Magnoux, P., Guisnet, M., Órfão, J.J.M., Figueiredo, J.L.: Catalytic oxidation of volatile organic compounds: oxidation of methyl-isobutyl-ketone over Pt/zeolite catalysts. Appl. Catal. B: Env. 57, 117-123 (2005).
7. 2 Schiff base ligands derived from acetylacetone in NaX zeolite. Micropor. Mesopor. Mat. 38, 391-401 (2000).
8. Kaucky, D., Vondrova, A., Dedecek, J., Wichterlova, B.: Activity of co ion sites in ZSM-5, ferrierite, and mordenite in selective catalytic reduction of NO with methane. J. Catal. 194, 318-329 (2000).
9. 2+) nanocomposite materials. Inorg. Chem. Commun. 9, 628-633 (2006)
10. Salavati-Niasari, M., Davar, F.: Host (nanodimensional pores of zeolite Y)-guest (3,10-dialkyl-dibenzo-1,3,5,8,10,12-hexaazacyclotetradecane, [Ni(R2Bzo2[14]aneN6)]2+) nanocomposite materials: synthesis, characterization and catalytic oxidation of cyclohexene. Inorg. Chem. Commun. 9, 263-268 (2006)
11. Salavati-Niasari, M., Davar, F.: Synthesis, characterization and catalytic activity of copper(II) complexes of 14-membered macrocyclic ligand; 3,10-dialkyl-dibenzo-1,3,5,8,10,12-hexaazacyclotetradecanel/zeolite encapsulated nanocomposite materials. Inorg. Chem. Commun. 9, 304-309 (2006)
12. Salavati-Niasari, M.: Host (nanocavity of zeolite-Y)-guest (tetraaza[14]annulene copper(II) complexes) nanocomposite materials: synthesis, characterization and liquid phase oxidation of benzyl alcohol. J. Mol. Catal. A: Chem. 245, 192-199 (2006)
13. Salavati-Niasari, M.: Synthesis and characterization of host (nanodimensional pores of zeolite-Y)-guest [Unsaturated 16-membered octaaza-macrocycle manganese(II), cobalt(II), nickel(II), copper(II), and zinc(II) complexes] nanocomposite materials. Chem. Lett. 34, 1444-1445 (2005)
14. Salavati-Niasari, M.: Nanoscale microreactor-encapsulation 14-membered nickel(II) hexamethyl tetraaza: synthesis, characterization and catalytic activity. J. Mol. Catal. A:Chem. 229, 159-164 (2005)
15. Salavati-Niasari, M.: Nanodimensional Microreactor-encapsulation of 18-membered decaaza macrocycle copper(II) complexes. Chem. Lett. 34, 244-245 (2005)
16. Salavati-Niasari, M.: Nanoscale microreactor-encapsulation of 18-membered decaaza macrocycle nickel(II) complexes. Inorg. Chem. Commun. 8, 174-177 (2005)
17. Salavati-Niasari, M.: Zeolite-encapsulated nickel (II) complexes with 14-membered hexaaza macrocycle: synthesis and characterization. Inorg. Chem. Commun. 7, 963-966 (2004);
18. Salavati-Niasari, M: Zeolite-encapsulation copper(II) complexes with 14-membered hexaaza macrocycles: synthesis, characterization and catalytic activity. J. Mol. Catal. A: Chem. 217, 87-92 (2004).
19. Lineares-Solano, A.: Textural characterization of porous carbons by physical adsorption of gases. In: Figueiredo, J.L., Moulijn, J.A. (eds.) Carbon and Coal Gasification, vol. 137. M. Nijhoff and M.A. Dordrecht (1986).
20. Chandra, S., Gupta, L.K.: Spectroscopic approach in characterization of chromium(III), manganese(II), iron(III) and copper(II) complexes with a nitrogen donor tetradentate, 14-membered azamacrocyclic ligand. Spectrochim. Acta A. 61, 2139-2144 (2005).
21. Comba, P., Curtis, N.F., Lawrence, G.A., O'Leary, M.A., Skelton, B. W., White, A.H.: Synthesis of a thirteen-membered tetra-azamacrocycle employing formaldehyde and nitroalkanes directed by metal ions. Crystal structures of (12-methyl-12-nitro-1,4,7,10-tetra-azacyclotridecane)copper(II) perchlorate and μ-chloro-1,1,1-trichloro-2-(12-methyl-12-nitro-1,4,7,10-tetra- azacyclotridecane)dicopper(II). J. Chem. Soc., Dalton Trans. 497-502 (1988)
22. Suh, M.P., Shin, W., Kim, D., Kim, S.: Preparation and molecular structure of the nickel(II) perchlorate complex of a hexadentate macrobicyclic ligand, 1,3,6,8,10,13,16,19-octaazabicyclo[6.6.6]eicosane. Inorg. Chem., 23, 618-620 (1984)
23. Suh, M.P., Kim, D., Kim, S.: Template synthesis and characterization of a nickel(II) complex with tris(((aminoethyl)amino)methyl)amine: (semisepulchrate)nickel(2+). Inorg. Chem. 24, 3712-3714 (1985) (2006);
24. Suh, M.P., Shin, W., Kim, H., Koo, C. H.: Nickel(I1) Complexes of Novel Ligands Containing a Tetraazabicyclononane Ring: Syntheses and Structures of [3,7-Bis(2-aminoethy1)-1,3,5,7-tetraazabicyclo[3.3.l]nonane]nickel(11) Perchlorate and (8-Methyl-1,3,6,8,10,13,15-heptaazatricyclo[13.1.1.1 13∼15]octadecane)nickel(11) Perchlorate. Inorg. Chem. 26, 1846-1852 (1987)
25. Suh, M.P., Kang, S.-G.: Synthesis and properties of nickel(II) and copper(II) complexes of 14-membered hexaaza macrocycles, 1,8-dimethyl- and 1,8-diethyl-1,3,6,8,10,13-hexaazacyclotetradecane. Inorg. Chem. 27, 2544-2546 (1988)
26. Salavati-Niasari, M., Bazarganipour, M: Host (nanodimensional pores of zeolite Y)-guest (tetraaza[14]annulene nickel(II) complexes, [Ni(Me4R2Bzo[14]tetraeneN4)]) nanocomposite materials: Ship-in-a-bottle synthesis, characterization and liquid phase oxidation of phenol with hydrogen peroxide. Catal. Commun. 7, 336-343 (2006)
27. Lever, A.B., Inorganic electronic spectroscopy, 2nd edn. Elsevier, New York (1968)
28. Salavati-Niasari, M., Rezai-Adaryani, M.: Template condensation reactions of formaldehyde with amines and 2,3-butanedihydrazone: preparation and properties of nickel(II) complexes of 18-membered decaaza macrocycles. Polyhedron 23, 1325-1331 (2004)
29. Salavati-Niasari, M., Amiri, A.: Synthesis and characterization of bis(macrocyclic) nickel(II) complexes containing aromatic nitrogen-nitrogen linkers produced by template condensation. Trans. Met. Chem. 31, 157-162
30. Salavati-Niasari, M.: Synthesis, characterization and catalytic oxidation of cyclohexene with molecular oxygen over host (montmorillonite-K10)/guest (nickel(II) complexes of 12- and 13-membered diaza dioxa Schiff-base macrocyclic ligand) nanocatalyst (HGN). J. Mol. Catal. A: Chem. 263, 247-252 (2007).
31. Shakir, M., Nasman, O.S.M., Mohamed, A.K., Varkey, S.P.: N5,17,18-membered pentaazamacrocyclic complexes bearing diamide groups : synthesis and characterization. Ind. J. Chem. 35A, 710-713 (1996).
32. Pandey, U.K., Sengupta, S.K., Tripathi, S.C.: Syntheses and spectroscopic studies on tetraaza macrocyclic complexes of praseodymium(III). Polyhedron 6, 1611-1617 (1987).
33. Balkus, K.J. Jr., Gabrielov, A.G.: Zeolite encapsulated metal complexes. J. Inclusion Phen. Mol. Recognit. Chem. 21, 159-181 (1995).
34. Salavati-Niasari, M.: Nanoscale microreactor-encapsulation of 16-membered hexaaza macrocycle nickel(II) complexes: in situ one-pot template synthesis (IOPTS), characterization and catalytic activity. Micro. Meso. Mat. 92, 173-180 (2006).
35. Salavati-Niasari, M., Bazarganipour, M., Ganjali, M.R., Norouzi, P.: Bis(macrocyclic)dinickel(II) complexes containing phenylene bridges between 13-membered triaza dioxa macrocyclic ligands: in-situ one pot template synthesis, characterization and catalytic oxidation of cyclohexene. Trans. Met. Chem. 32, 9-15 (2007);
36. 2; R=H, Me, Ph) nanocatalyst (HGN). Trans. Met. Chem. 31, 964-696 (2006).