Esterification of acrylic acid with 1,4-butanediol in a batch distillation column reactor over amberlyst 15 catalyst

Canadian Journal of Chemical Engineering

Volumn 85, Issue 6, 2007, Pages 883-888

  Yang, Jung Il ^a   Cho, Soon Haeng ^a   Park, Jongki ^a   Lee, Kwan Young ^b  

^a Korea Institute of Energy Research (KIER)   (South Korea)

^b Korea University   (South Korea)

Author keywords

4 hydroxybutyl acrylate; Air bubbling; Reaction rate of BD; Reactive distillation

Indexed keywords

ACRYLICS; CATALYST ACTIVITY; DISTILLATION COLUMNS; POLYMERIZATION; REACTION KINETICS;

ACRYLIC ACID (AA); AIR-BUBBLING; REACTION ZONE; REACTIVE DISTILLATION;

ESTERIFICATION;

ACRYLICS; CATALYST ACTIVITY; DISTILLATION COLUMNS; ESTERIFICATION; POLYMERIZATION; REACTION KINETICS;

EID: 38349159604     PISSN: 00084034     EISSN: None     Source Type: Journal    
DOI: 10.1002/cjce.5450850609     Document Type: Article

References (10)

1. BASF Company, "Technical Data Sheet - 1,4-Butanediol," (http://www.basf.com/diols/bcdiolsbdo.html), New Jersey, NJ (1997).
2. BASF Company, "Technical Information - Laromer BDDA," www.performancechemicals.basf.com/ev-wcms-in/internet/en_GB/function/evproducts: /document/30041345/TI, Ludwigshafen, Germany (2004).
3. Chopade, S. P. and M. M. Sharma, "Reaction of Ethanol and Formaldehyde: Use of Versatile Cation-Exchange Resins as Catalyst in Batch Reactors and Reactive Distillation Columns," React. Funct. Polym. 32, 53-64 (1997).
4. Chopade, S. P. and M. M. Sharma, "Acetalization of Ethylene Glycol with Formaldehyde using Cation-Exchange Resins as Catalysts: Batch Versus Reactive Distillation," React. Funct. Polym. 34, 37-45 (1997).
5. Klein, D. H. and W. J. E. Elms, "4-Hydroxybutyl Arylate," Paint Tech. 43, 68 (1971).
6. Nippon Kasei Chemical Company, "Product - 4-Hydroxybutyl Arylate," http://www.nkchemical.co.jp/ver_03/japanese/product_j/ prod_4hba01_j.html), Tokyo (2006).
7. Saha, B. and M. M. Sharma, "Esterification of Formic Acid, Acrylic Acid and Methacrylic Acid with Cyclohexane in Batch and Distillation Column Reactors: Ion-Exchange Resins as Catalysts," React. Funct. Polym. 28, 263-278 (1996).
8. Sato, T. and M. Kobayashi, "Method for Producing 4-Hydroxybutyl (Meth)acrylate," U.S. Patent No. 5,206,421 (1993).
9. Yang, J. I., S. H. Cho, H. J. Kim, H. K. Joo, H. Jung and K. Y. Lee, "Production of 4-Hydroxybutyl Acrylate and Its Reaction Kinetics over Amberlyst 15 Catalyst," Can. J. Chem. Eng. 85(1), 83-91 (2007).
10. Yokoyama, T., Y. Kawaragi and K. Murai, "Process for Producing Hydroxyalkyl Monoacrylate using Stannoxane Catalysts," U.S. Patent No. 6,087,538 (2000).