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4Sn and tetraphenylborates have been reported; see refs 12c and 11a. However, in these reactions, no oxidant was used. As suggested, insertion of a Rh(I) complex into a C - H aryl bond (aryl-H activation) leads to a HRh(III)aryl species which undergoes further reaction. Our process is different since an external oxidant is necessary and the C-H-activation probably occurs via electrophilic aromatic substitution. In fact, without oxidant our reactions did not proceed.
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4Sn and tetraphenylborates have been reported; see refs 12c and 11a. However, in these reactions, no oxidant was used. As suggested, insertion of a Rh(I) complex into a C - H aryl bond (aryl-H activation) leads to a HRh(III)aryl species which undergoes further reaction. Our process is different since an external oxidant is necessary and the "C-H-activation" probably occurs via electrophilic aromatic substitution. In fact, without oxidant our reactions did not proceed.
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Rh(I) carboxylates can be oxidized with Cu(OAc)2 to the corresponding Rh(III) complexes, which subsequently undergo directed C - H arylation: Ueura, K.; Satoh, T.; Miura, M. Org. Lett. 2007, 9, 1407.
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