The distribution coefficient of oil and curing agent in PP/EPDM TPV

Polymers for Advanced Technologies

Volumn 18, Issue 12, 2007, Pages 999-1003

  Lei, Caihong ^a   Huang, Xianbo ^b   Ma, Fangzhong ^b  

^a GUANGDONG UNIVERSITY OF TECHNOLOGY   (China)

^b Kingfa Science and Technology Company   (China)

Author keywords

Dynamic vulcanization; Ethylene propylene diene monomer(EPDM); Polypropylene; Thermoplastic elastomer

Indexed keywords

AGENTS; EXTRACTION; MONOMERS; OILS AND FATS; PEROXIDES; PLASTICS EXTRUDERS; THERMOPLASTIC ELASTOMERS; VULCANIZATION;

CURING AGENT; DISTRIBUTION COEFFICIENT; ETHYLENE-PROPYLENE-DIENE MONOMER; THERMOPLASTIC VULCANIZATE;

POLYPROPYLENES;

AGENTS; EXTRACTION; MONOMERS; OILS AND FATS; PEROXIDES; PLASTICS EXTRUDERS; POLYPROPYLENES; THERMOPLASTIC ELASTOMERS; VULCANIZATION;

CALCULATION; CURING (FINISHING); ELASTOMER; MELTING POINT; MONOMER; POLYPROPYLENE; THERMOPLASTIC POLYMER;

EID: 38349065061     PISSN: 10427147     EISSN: 10991581     Source Type: Journal    
DOI: 10.1002/pat.955     Document Type: Article

References (20)

1. De SK, Bhowmick AK. Thermoplastic Elastomers From Rubber-Plastic Blends. Ellis Horwood: New York, 1990.
2. Coran AY, Patel RP. Thermoplastic elastomers based on dynamically vulcanised elastomer/thermoplastic blends. In Thermoplastic Elastomers (2nd edn), Holden NR et al. (eds). Hanser Publishers: Munich, 1996.
3. Karger-Kocsis J. Thermoplastic rubbers via dynamic vulcanisation. In Polymer Blends and Alloys, Shonaike GO, Simon GP (eds). Marcel Dekker: New York, 1999. p 125-153.
4. Gessler M. Process for preparing a vulcanized blend of crystalline polypropylene and chlorinated butyl rubber, (1962) US Pat: 3,037,954.
5. Fisher K. Thermoplastic blend of partially cured monoolefin copolymer rubber and polyolefin plastic (1973) US Pat: 3,758,643.
6. Coran AY, Patel RP. Rubber-thermoplastic compositions. Part I EPDM-polypropylene thermoplastic vulcanizates. Rubber Chem. Technol. 1980; 53(1): 141-150.
7. Coran AY, Patel RP, Williams D. Rubber-thermoplastic compositions. Part V. Selecting polymers for thermoplastic vulcanizates. Rubber Chem. Technol. 1982; 55(1): 116-136.
8. Abdou-Sabet S, Patel RP. Morphology of elastomeric alloys. Rubber Chem. Technol. 1991; 64(4): 769-779.
9. Coran AY. In Thermoplastic Elastomers Based on Elastomer/ Thermoplastic Blends Dynamically Vulcanized, Al-Malaika S (ed.). Blackie Academic and Professional: London, 1997. p 349-395.
10. Ellul MD. Plasticization of polyolefin elastomers, semicrystalline plastics and blends crosslinked in situ during melt mixing. Rubber Chem. Technol. 1998; 71(2): 244-274.
11. van Duin M. Recent developments for EPDM-based thermoplastic vulcanisates. Macromol. Symp. 2006; 233(1): 11-16.
12. Ohlsson B, Hassander H, Tornell B. Blends and thermoplastic interpenetrating polymer networks of polypropylene and polystyrene-block-poly(ethylene-stat-butylene)-block-poly-styrene triblock copolymer. 1. Morphology and structure-related properties. Polym. Eng. Sci. 1996; 36(4): 501-510.
13. Jayaraman K, Kolli GV, Kang SY, et al. Shear flow behavior and oil distribution between phases in thermoplastic vulcanizates. J. Applied Polym. Sci. 2004; 93(1): 113-121.
14. Sengers WGF, Wubberhorst M, Picken SJ, et al. Distribution of oil in olefinic thermoplastic elastomer blends. Polymer 2005; 46(17): 6391-6401.
15. Gessler AM, Kresge EN. Elastomeric thermoplastics, (1979) US Pat. 4132698.
16. 13C NMR spectroscopy on EPDM/PP/oil thermoplastic vulcanizates in the melt. Polymer 2001; 42(24): 9745-9752.
17. Oikland HG, Hulskotte RJM. The mechanism of EPDM peroxide vulcanization in the presence of trially cyannrate as a coagent. Kantschuk Gummi Kunststoffe 1993; 46(8): 608-673.
18. Dizhen Wang, Xiang Tang, Shan He. Improvement of peroxide-crosslinked EPDM properties with TMPTA. Rubber Ind. 1999; 46(4): 201-203.
19. Danqing Chen, Zhiyong Lin, Yao Qian. The study of PP radical degradation. Fujian Chem. Ind. 2005; (6): 17-19.
20. Wei Wu. Study on the PP- EPDM co-crosslinking structure in dynamically vulcanized PP/EPDM blend by differential scanning calorimetry. China Plastics 1999; 13(7): 18-23.