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Volumn 47, Issue 4, 2008, Pages 731-734

Structurally defined reactions of sodium TMP-zincate with nitrile compounds: Synthesis of a salt-like sodium sodiumdizincate and other unexpected ion-pair products

Author keywords

Ion pairs; Metalation; Nitriles; Sodium; Zinc

Indexed keywords

AROMATIC COMPOUNDS; NEGATIVE IONS; SODIUM COMPOUNDS; ZINC;

EID: 38349006758     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200704341     Document Type: Article
Times cited : (42)

References (37)
  • 1
    • 33644931614 scopus 로고    scopus 로고
    • For reviews see: a
    • For reviews see: a) R. E. Mulvey, Organometallics 2006, 25, 1060;
    • (2006) Organometallics , vol.25 , pp. 1060
    • Mulvey, R.E.1
  • 3
    • 34250771010 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 3802.
    • (2007) Chem. Int. Ed , vol.46 , pp. 3802
    • Angew1
  • 5
    • 34147172663 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 1105;
    • (2007) Chem. Int. Ed , vol.46 , pp. 1105
    • Angew1
  • 7
    • 34347271684 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 4662.
    • (2007) Chem. Int. Ed , vol.46 , pp. 4662
    • Angew1
  • 12
    • 25144518782 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2005, 44, 6018;
    • (2005) Chem. Int. Ed , vol.44 , pp. 6018
    • Angew1
  • 15
  • 20
    • 33745036379 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 2370:
    • (2006) Chem. Int. Ed , vol.45 , pp. 2370
    • Angew1
  • 22
    • 33745031448 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 2374;
    • (2006) Chem. Int. Ed , vol.45 , pp. 2374
    • Angew1
  • 24
    • 33746265864 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 3775:
    • (2006) Chem. Int. Ed , vol.45 , pp. 3775
    • Angew1
  • 27
    • 33749823856 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2006, 45, 6548;
    • (2006) Chem. Int. Ed , vol.45 , pp. 6548
    • Angew1
  • 31
    • 35048861276 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2007, 46, 7685.
    • (2007) Chem. Int. Ed , vol.46 , pp. 7685
    • Angew1
  • 33
    • 38349059016 scopus 로고    scopus 로고
    • For synthetic details and NMR spectroscopic characterization see the Supporting Information. Crystal data for 1: C28H 46N6Na+C44H80N 6NaZn2, Mr, 1336.6, triclinic, space group P1, a, 10.187(3, b, 12.209(4, c, 17.637(5) Å, a, 73.426(5, β, 87.412(5, γ, 76.154(5)°, V, 2041.0(1) Å3, Z, 1 (both ions on inversion centers, ρcalcd, 1.087 g cm-3 T, 150 K, μ(Mo Kα, 0.64 mm-1 (λ, 0.71073 Å, 14870 reflections measured, 6448 unique, R int, 0.015; R (F, F2 > 2σ, 0.045. wR (F2, all data, 0.128, S F2, 1.026, 493 refined parameters and 433 restraints, constrained H atoms, difference map extremes
    • -3. CCDC 661569 (1), 661570 (2) and 661571 (3) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 34
    • 38349076469 scopus 로고    scopus 로고
    • 2, which led the authors to conclude that complexes of the type RCN·MR′ are probably of general importance in reactions of cyanides with organometallic compounds R′M, see: G. Boche, I. Langlotz, M. Marsch, K. Harms, G. Frenking. Angew. Chem. 1993, 105, 1207;
    • 2, which led the authors to conclude that complexes of the type RCN·MR′ are probably of general importance in reactions of cyanides with organometallic compounds R′M, see: G. Boche, I. Langlotz, M. Marsch, K. Harms, G. Frenking. Angew. Chem. 1993, 105, 1207;


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.