A general route for the synthesis of hydrido-carboxylate complexes of the type MH(CO)(κ3-OCOR)(PPh3)2 [M = Ru, Os; R = CH3, CH2Cl, C6H5, CH(CH3)2] and their use as precatalysts for hydrogenation and hydroformylation reactions

Polyhedron

Volumn 27, Issue 2, 2008, Pages 530-536

  Rosales, Merlín ^a   Alvarado, Beatriz ^a   Arrieta, Federico ^a   De La Cruz, Carlos ^b   González, Ángel ^a   Molina, Karely ^a   Soto, Otto ^a   Salazar, Yslamar ^a  

^a FACULTAD DE CIENCIAS VETERINARIAS   (Venezuela)

^b Laboratorio De Espectroscopia Molecular Y Atómica   (Venezuela)

Author keywords

1 Hexene; Benzothiophene; Carboxylate; Hydroformylation; Hydrogenation; Osmium; Quinoline; Ruthenium

Indexed keywords

CARBOXYLATION; COORDINATION REACTIONS; DICHLOROMETHANE; RUTHENIUM COMPOUNDS; SOLID STATE REACTIONS; SYNTHESIS (CHEMICAL);

1-HEXENE; BENZOTHIOPHENE; CARBOXYLATE; CARBOXYLATE COMPLEXES; CATIONIC COMPLEXES; METHANOL SOLUTION; PRECATALYSTS; QUINOLINE; SODIUM SALT; SPECTROSCOPIC CHARACTERIZATION;

HYDROGENATION;

EID: 38149053595     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2007.10.007     Document Type: Article

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